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1. 发明授权

US09023977B2 Triazine containing fluoropolyether elastomers having very low glass transition temperatures, compositions containing them and methods of making them 有权
标题翻译：含有玻璃化转变温度非常低的含氟聚醚弹性体的三嗪，含有它们的组合物及其制备方法
公开(公告)号：US09023977B2
公开(公告)日：2015-05-05
申请号：US13500526
申请日：2010-10-05
申请人： Steven G. Corveleyn , Rudolf J. Dams , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
发明人： Steven G. Corveleyn , Rudolf J. Dams , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
IPC分类号： C08G65/00
CPC分类号： C08G65/007
摘要： A method of making a fluoropolyether elastomer containing triazine groups and having a glass transition temperature of less than −40° C., including providing (i) one or more saturated fluoropolyethers containing repeating moieties selected from (—C4F8O—), (—C3F6O—), (—C2F4O—), (—CF2O—) and combinations thereof and further containing at least one functional group at a terminal carbon atom of the backbone chain, or of a side chain if present, wherein the terminal carbon atom may be a primary or secondary carbon atom and wherein the functional group is capable of reacting with a functional group of the fluorinated compound according to (ii) below to form a triazine ring, (ii) one or more fluorinated compound containing at least one perfluorinated alkyl or perfluorinated alkylene moiety wherein the carbon atoms of the perfluorinated alkyl or alkylene moiety may be interrupted by one or more oxygen atoms and wherein the fluorinated compound further contains at least one functional group capable of reacting with the functional group of the one or more fluoropolyethers to form a triazine; curing the components according to (i) and (ii) to form triazines. Further provided are cured compositions, articles comprising the cured compositions and methods of making articles.
摘要翻译：包括制备含有三嗪基并具有小于-40℃的玻璃化转变温度的氟聚醚弹性体的方法，包括提供（i）一种或多种含有重复部分的饱和含氟聚醚，所述重复部分选自（-C 4 F 8 O - ），（-C 3 F 6 O- ），（-C 2 F 4 O-），（-CF 2 O-）及其组合，并且在主链的末端碳原子或侧链（如果存在）中还含有至少一个官能团，其中末端碳原子可以是伯或仲碳原子，其中所述官能团能够与根据下述（ii）的氟化化合物的官能团反应以形成三嗪环，（ii）一种或多种含有至少一种全氟化烷基或全氟化的含氟化合物亚烷基部分，其中全氟烷基或亚烷基部分的碳原子可被一个或多个氧原子间隔，并且其中所述氟化化合物还含有至少一个f 能够与一种或多种含氟聚醚的官能团反应以形成三嗪的官能团; 根据（i）和（ii）固化组分以形成三嗪。还提供了固化组合物，包含固化组合物的制品和制造制品的方法。

2. 发明申请

US20120009438A1 TRIAZINE CONTAINING FLUOROELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 审中-公开
标题翻译：含有低玻璃化转变温度的含荧光物质的TRIAZINE
公开(公告)号：US20120009438A1
公开(公告)日：2012-01-12
申请号：US12833522
申请日：2010-07-09
申请人： Rudolf J. Dams , Steven G. Corveleyn , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
发明人： Rudolf J. Dams , Steven G. Corveleyn , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
IPC分类号： B32B9/00 , C08L27/12 , C08F214/18
CPC分类号： C08G65/007 , C08G2650/48 , C08L71/00 , C08L27/12
摘要： There is provided a curable fluoroelastomer composition comprising i. a first compound which comprising repeating units derived from a fluorinated olefin and further comprising at least one functional group, ii. a second compound comprising repeating units selected from (—C4F8O—), (—C2F4O—) or (—CF2O) or a combination thereof and further containing at least one functional group capable of reacting with the at least one functional group of the first compound either directly or in the presence of a curing compound to form a triazine unit, wherein the composition after curing by forming triazine units has a glass transition temperature of less than −60° C. Also provided are shaped articles comprising the cured compositions, methods of making cured compositions and methods for making shaped articles.
摘要翻译：提供了可固化的含氟弹性体组合物，其包含i。包含衍生自氟化烯烃的重复单元并且还包含至少一个官能团的第一化合物，ii。包含选自（-C 4 F 8 O-），（-C 2 F 4 O-）或（-CF 2 O）的重复单元或其组合的第二化合物，并且还含有至少一个能够与第一化合物的至少一个官能团反应的官能团直接或在固化化合物存在下形成三嗪单元，其中通过形成三嗪单元固化后的组合物具有小于-60℃的玻璃化转变温度。还提供了包含固化组合物的成型制品，制成固化组合物和制造成型制品的方法。

3. 发明授权

US09266999B2 Oligomers and co-oligomers of highly fluorinated sulfinic acid and salts thereof 有权
标题翻译：高度氟化亚磺酸的低聚物和共低聚物及其盐
公开(公告)号：US09266999B2
公开(公告)日：2016-02-23
申请号：US13995037
申请日：2011-12-06
申请人： Miguel A. Guerra , Gregg D. Dahlke , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Zai-Ming Qiu
发明人： Miguel A. Guerra , Gregg D. Dahlke , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Zai-Ming Qiu
IPC分类号： C07C313/02 , C08G61/00 , C08F8/44 , C08F14/18 , C08F214/18
CPC分类号： C08G61/00 , C07C313/02 , C08F8/44 , C08F14/18 , C08F214/184
摘要： There is provided oligomers comprising a highly fluorinated sulfinate oligomers.
摘要翻译：提供了包含高度氟化的亚磺酸盐低聚物的低聚物。

4. 发明授权

US08946465B2 Preparation of oligomers and co-oligomers of highly fluorinated sulfinic acids and salts thereof 有权
标题翻译：制备高度氟化亚磺酸的低聚物和共低聚物及其盐
公开(公告)号：US08946465B2
公开(公告)日：2015-02-03
申请号：US13994819
申请日：2011-12-13
申请人： Miquel A. Guerra , Gregg D. Dahlke , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Zai-Ming Qiu
发明人： Miquel A. Guerra , Gregg D. Dahlke , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Zai-Ming Qiu
IPC分类号： C07C313/04 , C08G75/00 , C07C303/22 , C08F214/18
CPC分类号： C08G75/00 , C07C303/22 , C07C313/04 , C08F214/18 , C07C309/82
摘要： There is provided a method for preparing oligomers and co-oligomers of highly fluorinated sulfuric acids and salts thereof.
摘要翻译：提供了制备高度氟化亚磺酸及其盐的低聚物和共低聚物的方法。

5. 发明授权

US07989552B2 Curing compositions for fluoropolymers 有权
标题翻译：含氟聚合物的固化组合物
公开(公告)号：US07989552B2
公开(公告)日：2011-08-02
申请号：US12139181
申请日：2008-06-13
申请人： Werner M. A. Grootaert , Eric W. Adair , Miguel A. Guerra
发明人： Werner M. A. Grootaert , Eric W. Adair , Miguel A. Guerra
IPC分类号： C08F8/00 , C08F8/42 , C08F8/40 , C08G63/78 , C08L23/28
CPC分类号： C08K5/19 , C08K5/50 , Y10T428/215 , C08L27/12
摘要： A curative composition suitable for fluoroelastomers comprising an anion of Formula III: wherein each Rf independently is R—CF2 or a perfluoroalkyl group having from 1 to 8 carbon atoms, wherein R is H, halo, alkyl, aryl, or cycloalkyl, having up to 8 carbon atoms and which also may be halogenated, fluorinated, or perfluorinated, and which may contain a heteroatom, wherein X is a linking group, and wherein n is a positive integer. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
摘要翻译：适用于含有式III阴离子的含氟弹性体的固化剂组合物：其中每个Rf独立地为R-CF 2或具有1至8个碳原子的全氟烷基，其中R为H，卤素，烷基，芳基或环烷基，具有至多 8个碳原子，并且其也可以被卤化，氟化或全氟化，并且其可以含有杂原子，其中X是连接基团，并且其中n是正整数。还提供了包含该固化剂的含氟聚合物组合物，制备含氟聚合物的方法和含有可固化或固化的含氟聚合物组合物的含氟聚合物制品。

6. 发明授权

US07666949B2 Curing compositions for fluoropolymers 失效
标题翻译：含氟聚合物的固化组合物
公开(公告)号：US07666949B2
公开(公告)日：2010-02-23
申请号：US12138856
申请日：2008-06-13
申请人： Werner M. A. Grootaert , Eric W. Adair , Miguel A. Guerra
发明人： Werner M. A. Grootaert , Eric W. Adair , Miguel A. Guerra
IPC分类号： C08F14/18
CPC分类号： C08K5/19 , C08K5/50 , Y10T428/215 , C08L27/12
摘要： A curative composition comprising a cation and an anion of the formula Anq−Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq− is an anion, provided that at least one Aq− is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R′ groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R′ can be the same as R, with the proviso that R′ cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
摘要翻译：一种包含式Anq-Qpm +的阳离子和阴离子的固化剂组合物，其中m，n，p和q是正整数，其中m * p = n * q，其中Qm +是有机鎓，Aq-是阴离子，条件是至少一个Aq-选自下式：其中每个R独立地为H，卤素，烷基，芳基，芳烷基或环烷基，并且也可以是卤化，氟化或全氟化，其中两个或多个 R和R'基团可以一起形成环，其中每个R基团可独立地含有一个或多个杂原子，其中R'可以与R相同，条件是R'不能为卤素。还提供了包含该固化剂的含氟聚合物组合物，制备含氟聚合物的方法和含有可固化或固化的含氟聚合物组合物的含氟聚合物制品。

7. 发明授权

US07294677B2 Catalyst for making fluoroelastomer compositions and methods of using the same 失效
标题翻译：制备含氟弹性体组合物的催化剂及其使用方法
公开(公告)号：US07294677B2
公开(公告)日：2007-11-13
申请号：US11211884
申请日：2005-08-25
申请人： Werner M. A. Grootaert , Miguel A. Guerra
发明人： Werner M. A. Grootaert , Miguel A. Guerra
IPC分类号： C08F8/18
CPC分类号： C07C257/06 , C08K5/29 , C08L27/12
摘要： A catalyst is preparable from a first component represented by R′C(CF2R)O−Q+ and a second component (NCCFR″)bZ. The catalyst may be combined with a fluoropolymer having nitrogen-containing cure-sites to form a curable composition that is useful for preparing fluoroelastomer compositions.
摘要翻译：一种催化剂可由来自由R'C（CF 2 R 2）-O - O - Q + / O 2表示的第一组分和第二组分（NCCFR' '）_{b Z。催化剂可与具有含氮固化位点的含氟聚合物组合以形成可用于制备含氟弹性体组合物的可固化组合物。}

8. 发明授权

US07655591B2 Catalyst for making fluoroelastomer compositions and methods of using the same 失效
标题翻译：制备含氟弹性体组合物的催化剂及其使用方法
公开(公告)号：US07655591B2
公开(公告)日：2010-02-02
申请号：US11867969
申请日：2007-10-05
申请人： Werner M. A. Grootaert , Miguel A. Guerra
发明人： Werner M. A. Grootaert , Miguel A. Guerra
IPC分类号： B01J31/04
CPC分类号： C07C257/06 , C08K5/29 , C08L27/12
摘要： A catalyst is preparable from a first component represented by R′C(CF2R)O− Q+ and a second component (NCCFR″)bZ. The catalyst may be combined with a fluoropolymer having nitrogen-containing cure-sites to form a curable composition that is useful for preparing fluoroelastomer compositions.
摘要翻译：催化剂可由由R'C（CF2R）O-Q +和第二组分（NCCFR“）bZ表示的第一组分制备。催化剂可与具有含氮固化位点的含氟聚合物组合以形成可用于制备含氟弹性体组合物的可固化组合物。

9. 发明授权

US5882466A Aqueous bonding composition 失效
标题翻译：水性粘合组合物
公开(公告)号：US5882466A
公开(公告)日：1999-03-16
申请号：US695141
申请日：1996-08-08
申请人： Werner M. A. Grootaert , Dirk H. C. Arren , Rudolf J. Dams
发明人： Werner M. A. Grootaert , Dirk H. C. Arren , Rudolf J. Dams
IPC分类号： C08J5/12 , C09D4/00 , C09D183/08 , C09J11/06 , C09J183/04 , C09J4/00
CPC分类号： C08J5/124 , C09D183/08 , C09D4/00 , C09J11/06 , C08J2327/12
摘要： An aqueous bonding composition comprising a silane compound, a water-soluble surface tension-reducing compound, water, and substantially no organic solvent, and a method of using said aqueous bonding composition. The aqueous bonding composition can be used to produce a bonded article comprising a fluoropolymer bonded to a substrate.
摘要翻译：包含硅烷化合物，水溶性表面张力降低化合物，水和基本上不含有机溶剂的水性粘合组合物以及使用所述水性粘合组合物的方法。水性粘合组合物可以用于制备包含结合到基底的含氟聚合物的粘合制品。

10. 发明授权

US07402630B2 Curing compositions for fluoropolymers 有权
标题翻译：含氟聚合物的固化组合物
公开(公告)号：US07402630B2
公开(公告)日：2008-07-22
申请号：US11014042
申请日：2004-12-16
申请人： Werner M. A. Grootaert , Eric W. Adair , Miguel A. Guerra
发明人： Werner M. A. Grootaert , Eric W. Adair , Miguel A. Guerra
IPC分类号： C08F8/00 , C08F8/42 , C08F8/40 , C08G63/78 , C08L23/28
CPC分类号： C08K5/19 , C08K5/50 , Y10T428/215 , C08L27/12
摘要： A curative composition comprising a cation and an anion of the formula Anq−Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq− is an anion, provided that at least one Aq− is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R′ groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R′ can be the same as R, with the proviso that R′ cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
摘要翻译：包含阳离子和式A的阴离子的固化剂组合物，其中m ，n，p和q是正整数，其中m * p = n * q，其中Q m +是有机鎓，A q - 是阴离子，条件是从下式中选择至少一个A q - ：其中每个R独立地是H，卤素，烷基，芳基，芳烷基或环烷基，并且也可以是卤化的，氟化的或全氟化的其中R和R'基团中的两个或多个可以一起形成环，其中每个R基团可独立地含有一个或多个杂原子，其中R'可以与R相同，条件是R'不能为光环。还提供了包含该固化剂的含氟聚合物组合物，制备含氟聚合物的方法和含有可固化或固化的含氟聚合物组合物的含氟聚合物制品。

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