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1. 发明授权

US07365138B2 Pretreated and prepolymerized polyolefin catalyst, production thereof and method of use 有权
标题翻译：预处理和预聚合的聚烯烃催化剂，其生产方法和使用方法
公开(公告)号：US07365138B2
公开(公告)日：2008-04-29
申请号：US11031587
申请日：2005-01-07
申请人： Steven D. Gray , Tim J Coffy , Edwar S. Shamshoum , Hong Chen
发明人： Steven D. Gray , Tim J Coffy , Edwar S. Shamshoum , Hong Chen
IPC分类号： C08F4/654
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6492 , C08F4/6557
摘要： A method of modifying a Ziegler-Natta type polyolefin catalyst comprises contacting the Ziegler-Natta catalyst with olefin monomer to form a prepolymerized catalyst. The prepolymerized catalyst can comprise a reduced number of catalyst particles having a size of 40 microns or less. The prepolymerized catalyst can be used in a polymerization process to produce polymer fluff particles with a reduced number of polymer fluff fines than the Ziegler-Natta type catalyst.
摘要翻译：修饰齐格勒 - 纳塔型聚烯烃催化剂的方法包括使齐格勒 - 纳塔催化剂与烯烃单体接触以形成预聚合的催化剂。预聚合的催化剂可以包含减少数量的具有40微米或更小尺寸的催化剂颗粒。预聚合的催化剂可用于聚合过程中，以生产具有比齐格勒 - 纳塔型催化剂低的聚合物绒毛数量的聚合物绒毛颗粒。

2. 发明授权

US06846887B2 Polyolefin catalysts, production thereof and method of use 有权
标题翻译：聚烯烃催化剂，其生产方法和使用方法
公开(公告)号：US06846887B2
公开(公告)日：2005-01-25
申请号：US10370365
申请日：2003-02-18
申请人： Steven D. Gray , Tim J. Coffy , Edwar S. Shamshoum , Hong Chen
发明人： Steven D. Gray , Tim J. Coffy , Edwar S. Shamshoum , Hong Chen
IPC分类号： C08F10/00 , C08F110/02 , C08F4/654 , C08F4/655
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6492 , C08F4/6557
摘要： A method of modifying a Ziegler-Natta type polyolefin catalyst comprises contacting the Ziegler-Natta catalyst with olefin monomer to form a prepolymerized catalyst. The prepolymerized catalyst can comprise a reduced number of catalyst particles having a size of 40 microns or less. The prepolymerized catalyst can be used in a polymerization process to produce polymer fluff particles with a reduced number of polymer fluff fines than the Ziegler-Natta type catalyst.
摘要翻译：修饰齐格勒 - 纳塔型聚烯烃催化剂的方法包括使齐格勒 - 纳塔催化剂与烯烃单体接触以形成预聚合的催化剂。预聚合的催化剂可以包含减少数量的具有40微米或更小尺寸的催化剂颗粒。预聚合的催化剂可用于聚合过程中，以生产具有比齐格勒 - 纳塔型催化剂低的聚合物绒毛数量的聚合物绒毛颗粒。

3. 发明授权

US06790804B2 Magnesium-diketonate complex derived polyolefin catalysts, method of making same, method of polymerizing with same 失效
标题翻译：碳酸二乙酯复合衍生的聚烯烃催化剂，其制备方法，聚合方法
公开(公告)号：US06790804B2
公开(公告)日：2004-09-14
申请号：US10186262
申请日：2002-06-27
申请人： Steven D. Gray , Tim J. Coffy , Edwar S. Shamshoum
发明人： Steven D. Gray , Tim J. Coffy , Edwar S. Shamshoum
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/6546 , C08F4/651 , C08F4/657 , C08F4/6548
摘要： A process of forming a polyolefin catalyst component includes contacting a metal compound of the formula MR2 with a diketone to form a metal bis(diketonate) having the formula M(OCRCR′CRO)2, wherein M is a Group IIA or Group VIIB metal, and wherein R and R′ are each hydrocarbyls or substituted hydrocarbyls having from 1 to 20 carbons atoms. Catalyst components, catalysts, polyolefin polymers, catalysts systems, and methods of preparing same are disclosed.
摘要翻译：形成聚烯烃催化剂组分的方法包括使式MR2的金属化合物与二酮接触以形成具有式M（OCRCR'CRO）2的金属双（二酮），其中M为IIA族或VIIB族金属，并且其中R和R'各自为烃基或具有1至20个碳原子的取代烃基。公开了催化剂组分，催化剂，聚烯烃聚合物，催化剂体系及其制备方法。

4. 发明授权

US07468339B2 Diketonate complex-derived catalysts useful for preparing polyolefins 失效
标题翻译：用于制备聚烯烃的衍生自二酮衍生物衍生的催化剂
公开(公告)号：US07468339B2
公开(公告)日：2008-12-23
申请号：US11016103
申请日：2004-12-17
申请人： Tim J. Coffy , Steven D. Gray
发明人： Tim J. Coffy , Steven D. Gray
IPC分类号： C08F4/642 , B01J31/02
CPC分类号： C08F10/00 , C07C45/77 , C07C49/92 , C07F3/003 , C08F110/02 , C08F4/651 , C08F4/6557 , C08F4/6548 , C08F2500/18 , C08F2500/12 , C08F2500/24 , C08F2500/07
摘要： An olefin polymerization catalyst may be prepared using a process including contacting a metal compound of the formula M(OR1)2 with a diketone to form a catalyst precursor having the general formula: wherein M is a Group IIA metal; O is oxygen; n=1 or 2; R1, R2, R3, and R4 are the same or different; and are a hydrogen or a substituted or unsubstituted alkyl or aryl moiety having from about 1 to about 20 carbons atoms.
摘要翻译：可以使用包括使式M（OR1）2的金属化合物与二酮接触以形成具有以下通式的催化剂前体的方法来制备烯烃聚合催化剂：其中M是IIA族金属; O是氧; n = 1或2; R1，R2，R3和R4相同或不同; 并且是具有约1至约20个碳原子的氢或取代或未取代的烷基或芳基部分。

5. 发明授权

US06916895B2 Ziegler-Natta catalyst for tuning MWD of polyolefin, method of making, method of using, and polyolefins made therewith 有权
标题翻译：用于调谐聚烯烃的MWD的齐格勒 - 纳塔催化剂，其制备方法，使用方法和由其制备的聚烯烃
公开(公告)号：US06916895B2
公开(公告)日：2005-07-12
申请号：US10687126
申请日：2003-10-16
申请人： Steven D. Gray , Tim J. Coffy
发明人： Steven D. Gray , Tim J. Coffy
IPC分类号： C08F4/654 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6557
摘要： A new synthesis of a Ziegler-Natta catalyst uses a multi-step preparation that includes treating a magnesium dialkoxide compound with halogenating/titanating agents, an organoaluminum preactivating agent, and a heat treatment. The catalyst may be used in the polymerization of olefins, particularly ethylene, to control the molecular weight distribution of the resulting polyolefins.
摘要翻译：齐格勒 - 纳塔催化剂的新合成使用多步骤制备方法，包括用卤化/钛化剂处理二烷氧基镁化合物，有机铝预活化剂和热处理。该催化剂可用于烯烃，特别是乙烯的聚合中，以控制得到的聚烯烃的分子量分布。

6. 发明授权

US06486274B1 Hydrogen response Ziegler-Natta catalyst for narrowing MWD of polyolefin, method of making, method of using, and polyolefins made therewith 有权
标题翻译：用于使聚烯烃的MWD变窄的齐格勒 - 纳塔催化剂，制造方法，使用方法和由此制成的聚烯烃
公开(公告)号：US06486274B1
公开(公告)日：2002-11-26
申请号：US09687688
申请日：2000-10-13
申请人： Steven D. Gray , Tim J. Coffy
发明人： Steven D. Gray , Tim J. Coffy
IPC分类号： C08F4614
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6557
摘要： A Ziegler-Natta type catalyst having an improved hydrogen response provides for narrowing of the MWD of resulting polyolefins polymerized using such catalyst, with such catalyst generally made by a) contacting a soluble magnesium dialkoxide compound of the general formula Mg(OR″)2 with a halogenating agent capable of exchanging one halogen for one alkoxide to form a reaction product A, where R″ is a hydrocarbyl or substituted hydrocarbyl having from 1 to 20 carbon atoms; b) contacting reaction product A with a first halogenating/titanating agent to form reaction product B; and c) contacting reaction product B with a second halogenating/titanating agent to form a catalyst component; wherein in at least one of steps b) and c), the halogenating/titanating agent is a blend of Ti(OPr)4 and TiCl4. Catalyst components, catalysts, catalyst systems, polyolefin polymers, and methods of forming each are disclosed.
摘要翻译：具有改善的氢气响应的齐格勒 - 纳塔型催化剂使得使用这种催化剂聚合的所得聚烯烃的MWD变窄，通常用以下方法制备的催化剂：a）使通式Mg（OR“）2的可溶性二烷氧基镁化合物与一种能够与一个卤素交换一个醇盐形成反应产物A的卤化剂，其中R“是具有1至20个碳原子的烃基或取代的烃基; b）使反应产物A与第一卤化/钛化剂接触以形成反应产物B; 和c）使反应产物B与第二卤化/钛化剂接触以形成催化剂组分; 其中在步骤b）和c）中的至少一个中，卤化/钛化剂是Ti（OPr）4和TiCl 4的共混物。公开了催化剂组分，催化剂，催化剂体系，聚烯烃聚合物和各种形成方法。

7. 发明申请

US20090023875A1 Process for Controlling Morphology of Ziegler-Natta Catalysts 失效
标题翻译：控制齐格勒 - 纳塔催化剂形态的方法
公开(公告)号：US20090023875A1
公开(公告)日：2009-01-22
申请号：US11778262
申请日：2007-07-16
申请人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
发明人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
IPC分类号： B01J37/03 , C08F4/12
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀，其中催化剂组分的平均粒径增加，并且颗粒尺寸分布增加，可溶性含镁催化剂前体的浓度降低; 或沉淀剂，其中催化剂组分的平均粒度增加，并且随着沉淀剂浓度的增加，粒度分布增加。使用本发明能够改善催化剂的一致性，而不管生产规模如何，催化剂形态定制成所需的聚合物形态。新颖的催化剂组分可用于制备聚合物及其最终用途制品，具有期望的性能。要强调的是，该摘要被提供以符合要求摘要的规则，这将允许搜索者或其他读者快速确定技术公开的主题。提交它的理解是，它不会用于解释或限制权利要求的范围或含义。

8. 发明申请

US20080153998A1 MODIFIED CATALYSTS FOR IMPROVED POLYMER PROPERTIES 审中-公开
标题翻译：改进的聚合物性质的改性催化剂
公开(公告)号：US20080153998A1
公开(公告)日：2008-06-26
申请号：US11613766
申请日：2006-12-20
申请人： Ricky McCormick , David W. Knoeppel , Steven D. Gray , Tim J. Coffy
发明人： Ricky McCormick , David W. Knoeppel , Steven D. Gray , Tim J. Coffy
IPC分类号： B01J31/14 , C08F4/22 , B01J21/02 , B01J21/08
CPC分类号： B01J31/143 , B01J23/26 , B01J31/146 , C08F10/00 , C08F210/16 , C08F2410/01 , C08F4/69 , C08F210/06 , C08F2500/12 , C08F2500/19 , C08F2500/04
摘要： Chromium catalysts may be prepared using a process including contacting a chromium catalyst precursor with a treatment agent. This catalyst may be used for polymerization of a variety of monomers, particularly olefins, to form polymers for a wide variety of applications. The catalyst exhibits desirable activity rates and polymers produced therewith may exhibit improved melt flow, polydisperity values, and changes in shear thinning as compared to those prepared under similar conditions but using the same treatment agent as a cocatalyst instead.
摘要翻译：可以使用包括使铬催化剂前体与处理剂接触的方法来制备铬催化剂。该催化剂可用于各种单体，特别是烯烃的聚合，以形成用于各种应用的聚合物。催化剂表现出所需的活性速率，与之相比，使用与助催化剂相同的处理剂，与在相似条件下制备的那些相比，可以显示改善的熔体流动性，多不连续性值和剪切稀化变化。

9. 发明授权

US08063159B2 Process for controlling morphology of Ziegler-Natta catalysts 失效
标题翻译：控制齐格勒 - 纳塔催化剂形态的方法
公开(公告)号：US08063159B2
公开(公告)日：2011-11-22
申请号：US11778262
申请日：2007-07-16
申请人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
发明人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
IPC分类号： C08F4/00
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties.
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀，其中催化剂组分的平均粒径增加，并且颗粒尺寸分布增加，可溶性含镁催化剂前体的浓度降低; 或沉淀剂，其中催化剂组分的平均粒度增加，并且随着沉淀剂浓度的增加，粒度分布增加。使用本发明能够改善催化剂的一致性，而不管生产规模如何，催化剂形态定制成所需的聚合物形态。新颖的催化剂组分可用于制备聚合物及其最终用途制品，具有期望的性能。

10. 发明申请

US20090182100A1 Process for the production of polyethylene resin 审中-公开
标题翻译：聚乙烯树脂生产工艺
公开(公告)号：US20090182100A1
公开(公告)日：2009-07-16
申请号：US12008740
申请日：2008-01-14
申请人： Gerhard K. Guenther , Steven D. Gray , Tim J. Coffy
发明人： Gerhard K. Guenther , Steven D. Gray , Tim J. Coffy
IPC分类号： C08F2/01
CPC分类号： C08F210/16 , C08F110/02 , C08F2/001 , C08F2/00 , C08F2500/02 , C08F210/14 , C08F2500/01
摘要： Process for the polymerization of ethylene to produce a polymer of enhanced long chain branching. Ethylene and hydrogen are introduced into a first reaction zone to produce an ethylene polymer having a first molecular weight distribution. The polymer from the first reaction zone is applied to a second reaction zone along with ethylene and a C3-C8 alpha-olefin monomer. The second reaction zone is operated to produce a copolymer having a second molecular weight distribution different from the first molecular weight distribution. A polymer fluff of bimodal molecular weight distribution is recovered from the second reaction zone and heated to melt the fluff and then extruded. Concomitantly with the heating and or extrusion, the polymer fluff is treated in order to enhance the long chain branching and reduce the melt index MI5 of the polymer product.
摘要翻译：乙烯聚合制备增强长链支化聚合物的方法。将乙烯和氢气引入第一反应区以产生具有第一分子量分布的乙烯聚合物。来自第一反应区的聚合物与乙烯和C 3 -C 8α-烯烃单体一起施加到第二反应区。操作第二反应区以产生具有不同于第一分子量分布的第二分子量分布的共聚物。从第二反应区回收双峰分子量分布的聚合物绒毛，并加热熔化绒毛然后挤出。伴随着加热和/或挤出，处理聚合物绒毛以增强长链支化并降低聚合物产物的熔体指数MI5。

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