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1. 发明授权

US08003835B2 Biomass conversion process 有权
标题翻译：生物质转换过程
公开(公告)号：US08003835B2
公开(公告)日：2011-08-23
申请号：US12606804
申请日：2009-10-27
申请人： Steve Yanik , Robert Bartek , Paul O'Connor , Dennis Stamires , Michael Brady
发明人： Steve Yanik , Robert Bartek , Paul O'Connor , Dennis Stamires , Michael Brady
IPC分类号： C07C1/00 , F27B15/08
CPC分类号： C10G1/08 , C10B49/22 , C10B53/02 , C10B57/02 , C10G1/006 , C10G3/42 , C10G3/57 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： A method for converting solid biomass into hydrocarbons includes contacting the solid biomass with a catalyst in a first riser operated at a temperature in the range of from about 50° C. to about 200° C. to thereby produce a first biomass-catalyst mixture and a first product comprising hydrocarbons; a) separating the first product from the first biomass-catalyst mixture; c) charging the first biomass-catalyst mixture to a second riser operated at a temperature in the range of from about 200° C. to about 400° C. to thereby produce a second biomass-catalyst mixture and a second product comprising hydrocarbons; d) separating the second product from the second biomass-catalyst mixture; e) charging the second biomass-catalyst mixture to a third riser operated at a temperature greater than about 450° C. to thereby produce a spent catalyst and a third product comprising hydrocarbons; and f) separating the third effluent from the spent catalyst.
摘要翻译：将固体生物质转化为烃的方法包括使固体生物质与在约50℃至约200℃的温度下操作的第一提升管中的催化剂接触，从而产生第一生物质 - 催化剂混合物，包含烃的第一产物; a）将第一产物与第一生物质 - 催化剂混合物分离; c）将第一生物质 - 催化剂混合物装载到在约200℃至约400℃的温度范围内操作的第二提升管，从而产生第二生物质 - 催化剂混合物和包含烃的第二产物; d）将第二产物与第二生物质 - 催化剂混合物分离; e）将第二生物质 - 催化剂混合物装入在大于约450℃的温度下操作的第三提升管，从而产生废催化剂和包含烃的第三产物; 和f）将第三流出物与废催化剂分离。

2. 发明申请

US20100281759A1 MODULAR BIOMASS TREATMENT UNIT 有权
标题翻译：模块化生物质处理单元
公开(公告)号：US20100281759A1
公开(公告)日：2010-11-11
申请号：US12717744
申请日：2010-03-04
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C10L1/00 , B01J19/00 , B01J35/02 , B01J8/08 , C07C29/88
CPC分类号： C10L9/083 , C10G3/42 , C10G3/49 , C10G2300/1014 , C10G2300/1037 , C10L1/04 , Y02E50/15 , Y02P30/20
摘要： A modular biomass treatment unit includes a first module having a pretreater and a first frame for transportation to and operation at a site adjacent to a solid biomass growth source. The pretreater is operable to process solid biomass to produce a plurality of solid biomass particles for conversion into a fuel or specialty chemical. The first frame supports the pretreater during transportation to and operation at the site adjacent to the solid biomass growth source. The modular biomass treatment unit can also include additional modules each comprising a reactor, a separator, and a frame for transportation to and operation at a site such as the site adjacent to the solid biomass growth source.
摘要翻译：模块化生物质处理单元包括具有预处理器和第一框架的第一模块，用于运输到与固体生物质生长源相邻的位置并在其操作。预处理器可操作地处理固体生物质以产生用于转化成燃料或特种化学品的多个固体生物质颗粒。第一个框架在运输过程中支持预处理器，并在与固体生物质生长生长源相邻的地点操作。模块化生物质处理单元还可以包括附加的模块，每个模块包括反应器，分离器和框架，用于运输到诸如邻近固体生物质生长源的部位的位置和操作。

3. 发明授权

US08558043B2 Modular biomass treatment unit 有权
标题翻译：模块化生物质处理装置
公开(公告)号：US08558043B2
公开(公告)日：2013-10-15
申请号：US12717744
申请日：2010-03-04
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C07C1/00 , C10G1/10
CPC分类号： C10L9/083 , C10G3/42 , C10G3/49 , C10G2300/1014 , C10G2300/1037 , C10L1/04 , Y02E50/15 , Y02P30/20
摘要： A modular biomass treatment unit includes a first module having a pretreater and a first frame for transportation to and operation at a site adjacent to a solid biomass growth source. The pretreater is operable to process solid biomass to produce a plurality of solid biomass particles for conversion into a fuel or specialty chemical. The first frame supports the pretreater during transportation to and operation at the site adjacent to the solid biomass growth source. The modular biomass treatment unit can also include additional modules each comprising a reactor, a separator, and a frame for transportation to and operation at a site such as the site adjacent to the solid biomass growth source.
摘要翻译：模块化生物质处理单元包括具有预处理器和第一框架的第一模块，用于运输到与固体生物质生长源相邻的位置并在其操作。预处理器可操作地处理固体生物质以产生用于转化成燃料或特种化学品的多个固体生物质颗粒。第一个框架在运输过程中支持预处理器，并在与固体生物质生长生长源相邻的地点操作。模块化生物质处理单元还可以包括附加的模块，每个模块包括反应器，分离器和框架，用于运输到诸如邻近固体生物质生长源的部位的位置和操作。

4. 发明授权

US08288600B2 Methods for co-processing of biomass and petroleum feed 有权
标题翻译：生物质和石油饲料的共处理方法
公开(公告)号：US08288600B2
公开(公告)日：2012-10-16
申请号：US12917988
申请日：2010-11-02
申请人： Robert Bartek , Michael Brady , Dennis Stamires , Steve Yanik , Paul O'Connor , Jacobus Cornelius Rasser
发明人： Robert Bartek , Michael Brady , Dennis Stamires , Steve Yanik , Paul O'Connor , Jacobus Cornelius Rasser
IPC分类号： C10L1/00
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. to 400° C. to form particulated biomass having a mean average particle size between 1 μm and 1000 μm. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes from 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit, and then at least a portion of the particulated biomass of the suspension is converted into fuel.
摘要翻译：本文公开了一种从生物质生产燃料的方法。该方法包括在80℃至400℃的温度下焙烧生物质材料，以形成平均粒度为1μm至1000μm的颗粒状生物质。将颗粒状生物质与液体烃混合以形成悬浮液，其中悬浮液包括1重量％至40重量％的颗粒生物质。将悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置中的单元中，然后将至少一部分颗粒生物质的悬浮液转化为燃料。

5. 发明申请

US20120137572A1 PROCESSING BIOMASS WITH A HYDROGEN SOURCE 审中-公开
标题翻译：用氢源处理生物量
公开(公告)号：US20120137572A1
公开(公告)日：2012-06-07
申请号：US13321702
申请日：2010-05-24
申请人： Robert Bartek , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Steve Yanik , Paul O'Connor
IPC分类号： C10L1/00 , C07C51/00 , B01J8/00 , C07C29/00 , C07C37/50 , C07D307/34 , C07C1/20 , C07C45/00
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A method is disclosed including co-processing a biomass feedstock and a refinery feedstock in a refinery unit. The method can include producing a liquid product by catalytically cracking or hyrocracking or hydrotreating a biomass feedstock and a refinery feedstock in a refinery unit having a fluidized reactor. Catalytically cracking can include transferring hydrogen from the refinery feedstock to carbon and oxygen from the biomass feedstock. Hydrocracking or hydrotreating can include transferring hydrogen from a hydrogen source to carbon and oxygen from the biomass feedstock, and to carbon from the refinery feedstock.
摘要翻译：公开了一种方法，包括在炼油厂中共同处理生物质原料和炼油原料。该方法可以包括通过在具有流化反应器的精炼厂单元中催化裂化或热裂解或加氢处理生物质原料和炼油原料来生产液体产物。催化裂化可以包括将氢气从炼油原料转移到来自生物质原料的碳和氧。加氢裂化或加氢处理可以包括从氢源将氢气从生物质原料转移到碳和氧，以及从炼油原料转移到碳。

6. 发明申请

US20120090977A1 CATALYST/BIOMASS MIXING IN TRANSPORT REACTOR 有权
标题翻译：催化剂/生物质混合在运输反应堆
公开(公告)号：US20120090977A1
公开(公告)日：2012-04-19
申请号：US13264925
申请日：2010-05-05
申请人： Robert Bartek , Ronald Lee Cordle , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Ronald Lee Cordle , Steve Yanik , Paul O'Connor
IPC分类号： C10B53/02 , C10B7/10
CPC分类号： C10G1/08 , B01J8/0025 , B01J8/1845 , B01J2208/0038 , B01J2208/00752 , C10B49/22 , C10B53/02 , C10B57/06 , C10G1/02 , C10G11/18 , C10G2300/1014 , Y02E50/14 , Y02P30/20
摘要： A reactor and/or process is disclosed for fluidized cracking of solid particulate biomass material, including a first mixing zone where a particulate stream comprising solid particulate biomass is mixed with a lift gas and becomes fluidized, and including a second mixing zone where a heat carrier material is mixed with the fluidized solid particulate biomass material.
摘要翻译：公开了用于固体颗粒生物质材料的流化裂化的反应器和/或方法，包括第一混合区，其中包含固体颗粒生物质的颗粒物流与提升气体混合并变成流化的，并且包括第二混合区，其中热载体材料与流化固体颗粒生物质材料混合。

7. 发明授权

US09944837B2 Co-processing solid biomass in a conventional petroleum refining process unit 有权
公开(公告)号：US09944837B2
公开(公告)日：2018-04-17
申请号：US13617289
申请日：2012-09-14
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C09K3/00 , C10G1/08 , C10G11/00 , C10G11/18 , C10G1/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.

8. 发明授权

US09120980B2 Catalyst/biomass mixing in transport reactor 有权
标题翻译：运输反应器中的催化剂/生物质混合
公开(公告)号：US09120980B2
公开(公告)日：2015-09-01
申请号：US13264925
申请日：2010-05-05
申请人： Robert Bartek , Ronald Cordle , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Ronald Cordle , Steve Yanik , Paul O'Connor
IPC分类号： C10B49/22 , C10G1/08 , C10G1/02 , C10B53/02 , C10B57/06 , C10G11/18 , B01J8/18 , B01J8/00
CPC分类号： C10G1/08 , B01J8/0025 , B01J8/1845 , B01J2208/0038 , B01J2208/00752 , C10B49/22 , C10B53/02 , C10B57/06 , C10G1/02 , C10G11/18 , C10G2300/1014 , Y02E50/14 , Y02P30/20
摘要： A reactor and/or process is disclosed for fluidized cracking of solid particulate biomass material, including a first mixing zone where a particulate stream comprising solid particulate biomass is mixed with a lift gas and becomes fluidized, and including a second mixing zone where a heat carrier material is mixed with the fluidized solid particulate biomass material.
摘要翻译：公开了用于固体颗粒生物质材料的流化裂化的反应器和/或方法，包括第一混合区，其中包含固体颗粒生物质的颗粒物流与提升气体混合并变成流化的，并且包括第二混合区，其中热载体材料与流化固体颗粒生物质材料混合。

9. 发明授权

US08524959B1 Biomass catalytic conversion process and apparatus for use therein 有权
标题翻译：生物质催化转化方法及其中使用的装置
公开(公告)号：US08524959B1
公开(公告)日：2013-09-03
申请号：US12708241
申请日：2010-02-18
申请人： Paul O'Connor , Henrique Soares Cerqueira , Robert Bartek , Steve Yanik
发明人： Paul O'Connor , Henrique Soares Cerqueira , Robert Bartek , Steve Yanik
IPC分类号： C07C1/00
CPC分类号： C10G1/08 , C10G2300/1011 , Y02P30/20
摘要： Disclosed is a process for small-scale operation of biomass catalytic cracking. The process is suitable for lab scale and pilot plant operation, as well as for small-scale commercial operation. The process is suitable for simulating a continuous biomass catalytic cracking (BCC) process. The process comprises a biomass conversion cycle and a catalyst regeneration cycle.A fluid bed reactor and a reaction feed fluidizer suitable for use in the process are also disclosed.
摘要翻译：公开了一种生物质催化裂化小规模运行的方法。该过程适用于实验室规模和试点工厂运行，适用于小规模商业运行。该方法适用于模拟连续生物质催化裂化（BCC）工艺。该方法包括生物质转化循环和催化剂再生循环。还公开了适用于该方法的流化床反应器和反应进料流化器。

10. 发明授权

US08288599B2 Co-processing solid biomass in a conventional petroleum refining process unit 有权
标题翻译：在常规石油炼制过程单元中共同处理固体生物质
公开(公告)号：US08288599B2
公开(公告)日：2012-10-16
申请号：US12867214
申请日：2009-06-29
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C07C1/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

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