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1. 发明授权

US4264650A Method for applying stress-crack resistant fluoropolymer coating 失效
标题翻译：施加耐应力裂纹的氟聚合物涂层的方法
公开(公告)号：US4264650A
公开(公告)日：1981-04-28
申请号：US8657
申请日：1979-02-01
申请人： Stephen R. Schulze , Elmer C. Lupton , William A. Miller , Robert H. Hutzler
发明人： Stephen R. Schulze , Elmer C. Lupton , William A. Miller , Robert H. Hutzler
IPC分类号： B05D7/14 , C08F259/08 , B05D3/02
CPC分类号： B05D7/14 , C08F259/08
摘要： Disclosed is a method for coating substrates with a stress-crack resistant coating of a fluoropolymer and a polyfunctional compound having two or more allyl groups such as triallylcyanurate or triallylisocyanurate wherein the fluoropolymer is a polymer comprised of ethylene, chlorotrifluoroethylene or tetrafluoroethylene and optionally a termonomer such as 3,3,3-trifluoro-2-trifluoromethyl propene. The ingredients are homogeneously blended and applied to the substrate which is maintained at an elevated temperature to allow flow-out of the coating mixture thereby forming a stress-crack resistant coating.
摘要翻译：公开了一种用含氟聚合物和具有两个或多个烯丙基的多官能化合物如三烯丙氰脲酸酯或三烯丙基异氰尿酸酯的多官能化合物涂覆基材的方法，其中含氟聚合物是由乙烯，三氟氯乙烯或四氟乙烯组成的聚合物，以及任选的三元共聚物为3,3,3-三氟-2-三氟甲基丙烯。将这些成分均匀混合并施加到保持在高温下的基底，以允许涂布混合物流出，从而形成耐应力开裂的涂层。

2. 发明授权

US4302511A Polyamide laminates containing copper salts 失效
标题翻译：含有铜盐的聚酰胺层压板
公开(公告)号：US4302511A
公开(公告)日：1981-11-24
申请号：US221141
申请日：1980-12-29
申请人： Harold W. Tuller , Stephen R. Schulze , Charles D. Mason
发明人： Harold W. Tuller , Stephen R. Schulze , Charles D. Mason
IPC分类号： B32B27/36
CPC分类号： B32B27/36 , Y10T428/31507 , Y10T428/31725 , Y10T428/31736 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31757 , Y10T428/31765 , Y10T428/31786 , Y10T428/31797 , Y10T428/31938
摘要： A laminate structure having at least one layer of a polyamide containing from 0.001 to 1.0 parts, based on the weight of the polyamide, of a copper cation containing material. The polyamide layer is contiguous to at least one opposing layer. The opposing layer contains an effective amount of functional groups selected from the group consisting of acid groups, metal salts of the acid, acid anhydrides, carbonates and mixtures thereof.
摘要翻译：具有至少一层聚酰胺的层压结构体，其含有0.001〜1.0份的聚酰胺重量的含铜阳离子材料。聚酰胺层与至少一个相对的层邻接。相对层含有有效量的选自酸基，酸金属盐，酸酐，碳酸酯及其混合物的官能团。

3. 发明授权

US4322480A Polyamide-polyethylene laminates 失效
标题翻译：聚酰胺 - 聚乙烯层压板
公开(公告)号：US4322480A
公开(公告)日：1982-03-30
申请号：US220884
申请日：1980-12-29
申请人： Harold W. Tuller , Stephen R. Schulze , George S. Wilson
发明人： Harold W. Tuller , Stephen R. Schulze , George S. Wilson
IPC分类号： B32B27/08 , B32B27/34 , B32B27/32
CPC分类号： B32B27/08 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31754 , Y10T428/31757 , Y10T428/31938
摘要： A laminate structure comprising at least one layer of a polyamide and at least one layer of polyethylene containing from 0.1 to 20 percent based on the weight of the polyethylene of oxidized high density polyethylene.
摘要翻译：包含至少一层聚酰胺和至少一层聚乙烯的层压结构，所述聚乙烯层含有基于氧化高密度聚乙烯的聚乙烯重量的0.1-20％。

4. 发明授权

US4033939A Stress-crack resistant ethylene-perhaloethylene terpolymers 失效
标题翻译：耐应力开裂乙烯 - 全卤代乙烯三元共聚物
公开(公告)号：US4033939A
公开(公告)日：1977-07-05
申请号：US649936
申请日：1976-01-19
申请人： Stephen R. Schulze
发明人： Stephen R. Schulze
IPC分类号： C08F210/00 , C08F2/00 , C08F10/00 , C08F14/00 , C08F14/18 , C08F210/02 , C08F214/04 , C08F214/26 , C08L23/08
CPC分类号： C08F210/02 , Y10T428/31699
摘要： Stress-crack resistant terpolymers of from about 40 to 60 mol percent ethylene, about 60 to 40 mol percent of a halogenated comonomer selected from the group consisting of tetrafluoroetylene, chlorotrifluoroethylene and mixtures thereof and about 0.1 to 10 mol percent of a termonomer selected from the group consisting of 3,3,3-trifluoro-2-trifluoromethyl propene, a vinyl monomer which is free of telogenic activity and which provides a side chain having at least two carbon atoms, the side chain being aromatic or having its elements bonded by a single bond only, and mixtures thereof, and containing high and low molecular weight components such that: ##EQU1## WHEREIN X.sub.i represents the weight fraction of each high molecular weight component i;Mw represents the weight-average molecular weight of the terpolymer,Mw.sub.i represents the weight-average molecular weight of each component i, ##EQU2## WHEREIN X.sub.j represents the weight fraction of each low molecular weight component j;Mw.sub.j represents the weight-average molecular weight of each component j, and0.1 .ltoreq.f .ltoreq.0.95.
摘要翻译：约40至60mol％乙烯的抗应力裂纹三元共聚物，约60至40mol％的选自四氟乙烯，三氟氯乙烯及其混合物的卤代共聚单体和约0.1-10mol％的选自以下的三元共聚物：由3,3,3-三氟-2-三氟甲基丙烯组成的基团，没有成熟活性的乙烯基单体，其提供具有至少两个碳原子的侧链，该侧链是芳族的或其元素通过单键和其混合物，并含有高分子量和低分子量组分，使得：

5. 发明授权

US4215176A Polyamide laminates 失效
标题翻译：聚酰胺层压板
公开(公告)号：US4215176A
公开(公告)日：1980-07-29
申请号：US939592
申请日：1978-09-05
申请人： Harold W. Tuller , Stephen R. Schulze
发明人： Harold W. Tuller , Stephen R. Schulze
IPC分类号： B32B27/28 , B32B27/08 , B32B27/34 , B32B27/36
CPC分类号： B32B27/08 , Y10T428/31507
摘要： Improved multi-layered laminates having at least one layer of a polyamide such as polyepsiloncaprolactam containing an excess of terminal amine groups and at least one layer, opposing the polyamide layer, containing a polymer having pendent carboxylic acid groups, their salts, carbonates, or acid anhydrides.
摘要翻译：具有至少一层聚酰胺的改进的多层层压体，例如含有过量的末端胺基的聚己内酰胺和与聚酰胺层相对的至少一层，含有具有侧基羧酸基团的聚合物，其盐，碳酸酯或酸酸酐。

6. 发明授权

US4436872A High impact molding compositions 失效
标题翻译：高冲击成型组合物
公开(公告)号：US4436872A
公开(公告)日：1984-03-13
申请号：US363365
申请日：1982-03-29
申请人： Paul W. Flood , Charles D. Mason , Stephen R. Schulze
发明人： Paul W. Flood , Charles D. Mason , Stephen R. Schulze
IPC分类号： C08L77/02 , C08K3/22 , C08K5/098 , C08L23/00 , C08L33/00 , C08L33/02 , C08L77/00 , C08L101/00
CPC分类号： C08K3/22 , C08K5/098 , C08L77/00
摘要： Certain metal compounds such as antimony oxide and magnesium oxide are used to enhance the notched Izod impact resistance of molded objects made from selected polyamide copolymer compositions comprised of polyepsiloncaprolactam (nylon-6) or polyhexamethyleneadipamide (nylon-66) and preferably ethylene/ethyl acrylate and ethylene/acrylic acid copolymers.
摘要翻译：使用某些金属化合物如氧化锑和氧化镁来提高由选自由聚己内酰胺（尼龙-6）或聚六亚甲基己二酰胺（尼龙-66），优选乙烯/丙烯酸乙酯组成的聚酰胺共聚物组合物制成的模制品的缺口艾佐德冲击强度，乙烯/丙烯酸共聚物。

7. 发明授权

US4335223A High impact molding compositions 失效
标题翻译：高冲击成型组合物
公开(公告)号：US4335223A
公开(公告)日：1982-06-15
申请号：US209182
申请日：1980-11-21
申请人： Paul W. Flood , Charles D. Mason , Stephen R. Schulze
发明人： Paul W. Flood , Charles D. Mason , Stephen R. Schulze
IPC分类号： C08L77/02 , C08K3/22 , C08K5/098 , C08L23/00 , C08L33/00 , C08L33/02 , C08L77/00 , C08L101/00
CPC分类号： C08K3/22 , C08K5/098 , C08L77/00
摘要： Certain metal compounds such as antimony oxide and magnesium oxide are used to enhance the notched Izod impact resistance of molded objects made from selected polyamide copolymer compositions comprised of polyepsiloncaprolactam (nylon-6) or polyhexamethyleneadipamide (nylon-66) and preferably ethylene/ethyl acrylate and ethylene/acrylic acid copolymers.
摘要翻译：使用某些金属化合物如氧化锑和氧化镁来提高由选自由聚己内酰胺（尼龙-6）或聚六亚甲基己二酰胺（尼龙-66），优选乙烯/丙烯酸乙酯组成的聚酰胺共聚物组合物制成的模制品的缺口艾佐德冲击强度，乙烯/丙烯酸共聚物。

8. 发明授权

US4070341A Stabilized ethylene-chlorotrifluoroethylene polymers exhibiting reduced metal corrosion 失效
标题翻译：表现出减少的金属腐蚀的稳定的乙烯 - 氯三氟乙烯聚合物
公开(公告)号：US4070341A
公开(公告)日：1978-01-24
申请号：US751001
申请日：1976-12-15
申请人： Stephen R. Schulze
发明人： Stephen R. Schulze
IPC分类号： C08L23/00 , C08K3/00 , C08K3/22 , C08K3/24 , C08K3/30 , C08K5/04 , C08K5/13 , C08L1/00 , C08L23/08 , C08L27/00 , C08L27/12 , C08L27/20 , C08L63/00 , C08L63/02 , C08L101/00 , H01B3/44
CPC分类号： C08K3/30 , C08K5/13 , C08L23/0892 , C08L2203/202 , C08L63/00 , Y10T428/269 , Y10T428/31699
摘要： Stabilized fluoropolymer compositions comprising a polymer from about 40 to 60 mol percent ethylene, about 60 to 40 mol percent chlorotrifluoroethylene and optionally about 0.1 to 10 mol percent of a fluorinated termonomer selected from the group consisting of 3,3,3-trifluoro-2-trifluoromethyl propene, a vinyl monomer which is free of telogenic activity and which provides a side chain having at least two carbon atoms, the side chain being aromatic or having its elements bonded by a single bond only, and mixtures thereof, and as a stabilizing agent, a member selected from the group consisting of epoxy resins, mixtures of tribasic lead sulfate and bisphenol A, and mixtures of the epoxy resin, tribasic lead sulfate and bisphenol A.
摘要翻译：稳定的含氟聚合物组合物包含约40至60mol％的乙烯，约60至40mol％的三氟氯乙烯和约0.1-10mol％的选自3,3,3-三氟-2- 三氟甲基丙烯，一种不具有游离性活性的乙烯基单体，其提供具有至少两个碳原子的侧链，所述侧链是芳族的或仅通过单键键合其元素，以及它们的混合物，以及作为稳定剂，选自环氧树脂，三硫酸铅和双酚A的混合物的组分，以及环氧树脂，三元硫酸铅和双酚A的混合物。

9. 发明授权

US4357268A Nucleation agents for crystalline polymers 失效
标题翻译：结晶聚合物成核剂
公开(公告)号：US4357268A
公开(公告)日：1982-11-02
申请号：US220878
申请日：1980-12-29
申请人： Nicholas Vanderkooi, Jr. , John C. Haylock , Stephen R. Schulze , Harold W. Tuller
发明人： Nicholas Vanderkooi, Jr. , John C. Haylock , Stephen R. Schulze , Harold W. Tuller
IPC分类号： C08L67/00 , C08K5/09 , C08K5/098 , C08L67/02 , C08L91/00
CPC分类号： C08K5/098 , C08K5/09
摘要： A polyethylene terephthalate composition comprising the salt of a dimer acid, trimer acid or the salt of a mixture of dimer and trimer acid. The dimer and/or trimer acids are neutralized with a Group IA metal cation, preferably sodium. The composition can contain a filler, plasticizer, impact modifier and/or a polyepoxide.
摘要翻译：一种聚对苯二甲酸乙二醇酯组合物，其包含二聚酸，三聚酸或二聚体和三聚酸的混合物的盐的盐。二聚体和/或三聚酸用IA族金属阳离子，优选钠中和。组合物可以含有填料，增塑剂，抗冲改性剂和/或聚环氧化物。

10. 发明授权

US4053445A Solutions of ethylene-chlorotrifluoroethylene copolymers 失效
标题翻译：乙烯 - 氯代三氟乙烯共聚物的溶液
公开(公告)号：US4053445A
公开(公告)日：1977-10-11
申请号：US737231
申请日：1976-11-01
申请人： Stephen R. Schulze
发明人： Stephen R. Schulze
IPC分类号： C08L27/12 , C08F14/00 , C08F14/24 , C08J3/09 , C08L1/00 , C08L27/00 , C08K5/02 , C08K5/10 , C08K5/15 , C08K5/20
CPC分类号： C08J3/091 , C08K5/0016 , C08K5/54 , C08J2327/12
摘要： Solutions of a copolymer of about 55 to 95 mol percent chlorotrifluoroethylene and about 45 to 5 mol percent ethylene in an organic solvent. The solutions may optionally contain an organic silane, preferably an aminosilane.

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