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1. 发明申请

US20150048314A1 PHOTOACTIVE DEVICES INCLUDING PORPHYRINOIDS WITH COORDINATING ADDITIVES 有权
标题翻译：包括具有协调添加剂的PORPHYRINOID的光学器件
公开(公告)号：US20150048314A1
公开(公告)日：2015-02-19
申请号：US13271993
申请日：2011-10-12
申请人： Stephen R. Forrest , Jeramy Zimmerman , Eric K. Yu , Mark E. Thompson , Cong Trinh , Matthew Whited , Viacheslav Diev
发明人： Stephen R. Forrest , Jeramy Zimmerman , Eric K. Yu , Mark E. Thompson , Cong Trinh , Matthew Whited , Viacheslav Diev
IPC分类号： H01L51/00 , H01L51/50 , H01L51/56 , H01L51/42
CPC分类号： H01L51/0092 , B82Y10/00 , H01L51/0003 , H01L51/001 , H01L51/0046 , H01L51/0047 , H01L51/0077 , H01L51/0078 , H01L51/009 , H01L51/424 , H01L51/4253 , H01L51/5012 , H01L51/5056 , H01L51/5072 , H01L51/56 , Y02E10/549 , Y02P70/521
摘要： Coordinating additives are included in porphyrinoid-based materials to promote intermolecular organization and improve one or more photoelectric characteristics of the materials. The coordinating additives are selected from fullerene compounds and organic compounds having free electron pairs. Combinations of different coordinating additives can be used to tailor the characteristic properties of such porphyrinoid-based materials, including porphyrin oligomers. Bidentate ligands are one type of coordinating additive that can form coordination bonds with a central metal ion of two different porphyrinoid compounds to promote porphyrinoid alignment and/or pi-stacking. The coordinating additives can shift the absorption spectrum of a photoactive material toward higher wavelengths, increase the external quantum efficiency of the material, or both.
摘要翻译：配合添加剂包括在卟啉类材料中，以促进分子间组织，改善材料的一种或多种光电特性。配位添加剂选自具有自由电子对的富勒烯化合物和有机化合物。可以使用不同配位添加剂的组合来定制这种卟啉类物质的特征，包括卟啉低聚物。二齿配体是可以与两种不同卟啉类化合物的中心金属离子形成配位键的一种配位添加剂，以促进卟啉类比对和/或π-叠层。配位添加剂可将光活性材料的吸收光谱向较高波长移动，提高材料的外部量子效率，或两者兼有。

2. 发明授权

US09029837B2 Photoactive devices including porphyrinoids with coordinating additives 有权
标题翻译：光活性器件包括具有配位添加剂的卟啉类
公开(公告)号：US09029837B2
公开(公告)日：2015-05-12
申请号：US13271993
申请日：2011-10-12
申请人： Stephen R. Forrest , Jeramy Zimmerman , Eric K. Yu , Mark E. Thompson , Cong Trinh , Matthew Whited , Vlacheslav Diev
发明人： Stephen R. Forrest , Jeramy Zimmerman , Eric K. Yu , Mark E. Thompson , Cong Trinh , Matthew Whited , Vlacheslav Diev
IPC分类号： H01L51/00 , H01L51/42 , H01L51/50 , H01L51/56
CPC分类号： H01L51/0092 , B82Y10/00 , H01L51/0003 , H01L51/001 , H01L51/0046 , H01L51/0047 , H01L51/0077 , H01L51/0078 , H01L51/009 , H01L51/424 , H01L51/4253 , H01L51/5012 , H01L51/5056 , H01L51/5072 , H01L51/56 , Y02E10/549 , Y02P70/521
摘要： Coordinating additives are included in porphyrinoid-based materials to promote intermolecular organization and improve one or more photoelectric characteristics of the materials. The coordinating additives are selected from fullerene compounds and organic compounds having free electron pairs. Combinations of different coordinating additives can be used to tailor the characteristic properties of such porphyrinoid-based materials, including porphyrin oligomers. Bidentate ligands are one type of coordinating additive that can form coordination bonds with a central metal ion of two different porphyrinoid compounds to promote porphyrinoid alignment and/or pi-stacking. The coordinating additives can shift the absorption spectrum of a photoactive material toward higher wavelengths, increase the external quantum efficiency of the material, or both.
摘要翻译：配合添加剂包括在卟啉类材料中，以促进分子间组织，改善材料的一种或多种光电特性。配位添加剂选自具有自由电子对的富勒烯化合物和有机化合物。可以使用不同配位添加剂的组合来定制这种卟啉类物质的特征，包括卟啉低聚物。二齿配体是可以与两种不同卟啉类化合物的中心金属离子形成配位键的一种配位添加剂，以促进卟啉类比对和/或π-叠层。配位添加剂可将光活性材料的吸收光谱向较高波长移动，提高材料的外部量子效率，或两者兼有。

3. 发明申请

US20110186910A1 METHODS OF PREPARING FLEXIBLE PHOTOVOLTAIC DEVICES USING EPITAXIAL LIFTOFF, AND PRESERVING THE INTEGRITY OF GROWTH SUBSTRATES USED IN EPITAXIAL GROWTH 有权
标题翻译：使用外延起绒制备柔性光伏器件的方法，并保持外延生长中使用的生长基质的一致性
公开(公告)号：US20110186910A1
公开(公告)日：2011-08-04
申请号：US12878261
申请日：2010-09-09
申请人： Stephen R. Forrest , Jeramy Zimmerman , Kyusang Lee , Kuen-Ting Shiu
发明人： Stephen R. Forrest , Jeramy Zimmerman , Kyusang Lee , Kuen-Ting Shiu
IPC分类号： H01L29/06 , H01L21/302 , H01L31/0352
CPC分类号： H01L31/1892 , H01L21/7813 , H01L31/0735 , H01L31/1852 , H01L31/1896 , Y02E10/544
摘要： There is disclosed methods of making photosensitive devices, such as flexible photovoltaic (PV) devices, through the use of epitaxial liftoff. Also described herein are methods of preparing flexible PV devices comprising a structure having a growth substrate, wherein the selective etching of protective layers yields a smooth growth substrate that us suitable for reuse.
摘要翻译：公开了通过使用外延剥离来制造诸如柔性光伏（PV）器件的光敏器件的方法。本文还描述了制备包含具有生长衬底的结构的柔性PV器件的方法，其中保护层的选择性蚀刻产生了适合于再利用的平滑生长衬底。

4. 发明授权

US08378385B2 Methods of preparing flexible photovoltaic devices using epitaxial liftoff, and preserving the integrity of growth substrates used in epitaxial growth 有权
公开(公告)号：US08378385B2
公开(公告)日：2013-02-19
申请号：US12878261
申请日：2010-09-09
申请人： Stephen R. Forrest , Jeramy Zimmerman , Kyusang Lee , Kuen-Ting Shiu
发明人： Stephen R. Forrest , Jeramy Zimmerman , Kyusang Lee , Kuen-Ting Shiu
IPC分类号： H01L29/06 , H01L21/302 , H01L31/0352
CPC分类号： H01L31/1892 , H01L21/7813 , H01L31/0735 , H01L31/1852 , H01L31/1896 , Y02E10/544
摘要： There is disclosed methods of making photosensitive devices, such as flexible photovoltaic (PV) devices, through the use of epitaxial liftoff. Also described herein are methods of preparing flexible PV devices comprising a structure having a growth substrate, wherein the selective etching of protective layers yields a smooth growth substrate that us suitable for reuse.

5. 发明申请

US20130043214A1 SACRIFICIAL ETCH PROTECTION LAYERS FOR REUSE OF WAFERS AFTER EPITAXIAL LIFT OFF 审中-公开
标题翻译：外部提升关闭后的重复使用的防腐蚀层
公开(公告)号：US20130043214A1
公开(公告)日：2013-02-21
申请号：US13536267
申请日：2012-06-28
申请人： Stephen R. Forrest , Jeramy Zimmerman , Kyusang Lee
发明人： Stephen R. Forrest , Jeramy Zimmerman , Kyusang Lee
IPC分类号： B32B15/04 , B44C1/22
CPC分类号： H01L31/1896 , Y02E10/50 , Y10T428/31678
摘要： There is disclosed a growth structure comprising a growth substrate, a sacrificial layer, a buffer layer, at least three substrate protective layers, at least one epilayer, at least one contact, and a metal or alloy-coated host substrate. In one embodiment, the device further comprises at least three device structure protecting layers. The sacrificial layer may be positioned between the growth substrate and the at least one epilayer, wherein the at least three substrate protective layers are positioned between the growth substrate and the sacrificial layer, and the at least three device structure protecting layers are positioned between the sacrificial layer and the epilayer. There is also disclosed a method of preserving the integrity of a growth substrate by releasing the cell structure by etching the sacrificial layer and the protective layers.
摘要翻译：公开了一种生长结构，其包括生长衬底，牺牲层，缓冲层，至少三个衬底保护层，至少一个外延层，至少一个接触层，以及涂覆有金属或合金的主体衬底。在一个实施例中，该装置还包括至少三个装置结构保护层。牺牲层可以位于生长衬底和至少一个外延层之间，其中至少三个衬底保护层位于生长衬底和牺牲层之间，并且至少三个器件结构保护层位于牺牲层之间层和外延层。还公开了通过蚀刻牺牲层和保护层来释放细胞结构来保持生长基质的完整性的方法。

6. 发明申请

US20070227588A1 ENHANCED TUNNEL JUNCTION FOR IMPROVED PERFORMANCE IN CASCADED SOLAR CELLS 审中-公开
标题翻译：增强隧道结，改善了在太阳能电池中的性能
公开(公告)号：US20070227588A1
公开(公告)日：2007-10-04
申请号：US11675269
申请日：2007-02-15
申请人： Arthur Gossard , Joshua Zide , Jeramy Zimmerman
发明人： Arthur Gossard , Joshua Zide , Jeramy Zimmerman
IPC分类号： H01L31/00
CPC分类号： H01L31/0687 , H01L31/0352 , H01L31/18 , Y02E10/544 , Y02P70/521
摘要： A method and device that incorporates metallic nanoparticles at the p+-n+ tunnel junction in a cascaded photovoltaic solar cell. The use of the nanoparticles enhances the tunneling current density through the tunnel junction. As such, the efficiency of the solar cell is increased. A method in accordance with the present invention comprises making a first solar cell having a first bandgap, making a tunnel junction coupled to the first solar cell, and making a second solar cell having a second bandgap, coupled to the tunnel junction opposite the first solar cell, wherein the tunnel junction comprises nanoparticles. Such a method further optionally includes the nanoparticles being a metal or a semi metal, specifically a semi-metal of erbium arsenide, the nanoparticles being deposited in an island structure within the tunnel junction, and the first solar cell being deposited on a flexible substrate. A device in accordance with the present invention comprises a tunnel junction, wherein the tunnel junction comprises nanoparticles between the n+ layer and the p+ layer of the tunnel junction. Such a device further optionally includes the device being a cascaded solar cell, the nanoparticles are a metal or semi-metal, specifically a semi-metal of erbium arsenide, and the device is fabricated on a flexible substrate.
摘要翻译：在级联的光伏太阳能电池中在p + + + + + + / - 隧道结处掺入金属纳米粒子的方法和装置。纳米颗粒的使用通过隧道结增强隧穿电流密度。因此，提高了太阳能电池的效率。根据本发明的方法包括制造具有第一带隙的第一太阳能电池，使得耦合到第一太阳能电池的隧道结，以及制造具有第二带隙的第二太阳能电池，其耦合到与第一太阳能电池相对的隧道结电池，其中所述隧道结包括纳米颗粒。这种方法进一步可选地包括纳米颗粒是金属或半金属，特别是铒砷化物的半金属，纳米颗粒以隧道结内的岛结构沉积，第一太阳能电池沉积在柔性基底上。根据本发明的装置包括隧道结，其中隧道结包括在隧道结的n +层和p +层之间的纳米颗粒。这种装置进一步可选地包括该装置是级联的太阳能电池，纳米颗粒是金属或半金属，特别是砷化砷的半金属，并且该装置制造在柔性基板上。

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