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1. 发明申请

US20060075573A1 Method for producing a leather semi-finished product 失效
标题翻译：皮革半成品的制造方法
公开(公告)号：US20060075573A1
公开(公告)日：2006-04-13
申请号：US10531178
申请日：2003-11-25
申请人： Stephan Huffer , Stefan Schroeder , Jurgen Carle , Thorsten Radler , Volker Bach , Tilman Taeger
发明人： Stephan Huffer , Stefan Schroeder , Jurgen Carle , Thorsten Radler , Volker Bach , Tilman Taeger
IPC分类号： D06M19/00
CPC分类号： C14C3/16 , C14C3/28
摘要： A semifinished leather product is produced from an animal hide by pretanning with the use of a chromium-free tanning agent and of a clay mineral which, after stirring for 30 minutes in water at 50° C. at a circumferential rotor speed of from 5 to 25 m/s, has a number average particle diameter of less than 2 μm or a bimodal particle size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, a proportion of the first, finely divided fraction being from 10 to 90% by weight, and drying of the pretanned animal hide to a water content of from 5 to 45% based on the total weight of the semifinished leather product.
摘要翻译：通过使用无铬鞣剂和粘土矿物预处理从动物皮制造半成品皮革制品，其在50℃的水中搅拌30分钟，周向转子速度为5至 25m / s，数均粒径小于2μm，或双峰粒径分布，其数均粒径小于0.5μm的第一微细分数，第二较粗颗粒的数均粒径通过组合的激光衍射和光散射，通过根据ISO 13320-1的方法在每种情况下确定小于5um，一部分细碎部分的比例为10至90重量％，并干燥基于半成品皮革制品的总重量，预制动物的水分含量为5至45％。

2. 发明申请

US20050210596A1 Use of polyelectrolytes in the production of leather 审中-公开
标题翻译：在生产皮革时使用聚电解质
公开(公告)号：US20050210596A1
公开(公告)日：2005-09-29
申请号：US10505448
申请日：2003-03-12
申请人： Stephan Huffer , Gunther Pabst , Tilman Taeger , Stefan Schroeder , Philippe Lamalle
发明人： Stephan Huffer , Gunther Pabst , Tilman Taeger , Stefan Schroeder , Philippe Lamalle
IPC分类号： C14C1/06 , C14C1/08 , C14C3/22 , C14C1/00
CPC分类号： C14C1/06 , C14C1/08
摘要： A process for the production of semifinished products and intermediates in the production of leather using one or more organic polyelectrolytes comprises at least one of the following steps: (a) Addition of one or more polyelectrolytes and from 0 to 0.7% by weight, based on the salted weight, of lime immediately before or during liming, (b) addition of one or more polyelectrolytes before or during deliming, (c) addition of one or more polyelectrolytes before or during bating, (d) addition of one or more polyelectrolytes and a total of from 0 to 3% by weight, based on the pelt weight, of alkali metal or alkaline earth metal salt immediately before or in the pickle.
摘要翻译：使用一种或多种有机聚电解质在生产皮革中生产半成品和中间体的方法包括以下步骤中的至少一个步骤：（a）加入一种或多种聚电解质和0至0.7重量％，基于（b）在剥离之前或期间添加一种或多种聚电解质，（c）在或之前加入一种或多种聚电解质，（d）加入一种或多种聚电解质和基于皮毛重量的0-3重量％的碱金属或碱土金属盐在紧挨之前或之中。

3. 发明申请

US20070022541A1 Method for producing leather 审中-公开
公开(公告)号：US20070022541A1
公开(公告)日：2007-02-01
申请号：US10529744
申请日：2003-10-14
申请人： Tilman Taeger , Gunther Pabst , Philippe Lamalle , Stephan Huffer , Stefan Schroeder
发明人： Tilman Taeger , Gunther Pabst , Philippe Lamalle , Stephan Huffer , Stefan Schroeder
IPC分类号： C14C1/06
CPC分类号： C14C1/065
摘要： Leather is produced by a process comprising at least two of the following process steps A) to D): A) use of one or more polyelectrolytes in the production of semifinished products or intermediate products, comprising the addition of one or more polyelectrolytes in at least one of the steps (a) to (d) (a) together with from 0 to 1.5% by weight, based on the salted weight, of lime, immediately before or during liming, (b) before or during deliming, (c) before or during bating, (d) together with, altogether, from 0 to 3% by weight, based on the pelt weight, of alkali metal or alkaline earth metal salt, immediately before or during pickling; B) treatment of the hides during liming in an aqueous liquor with one or more compounds of the formula B.1 or the corresponding alkali metal, alkaline earth metal, ammonium or phosphonium salts thereof, R10 and X1 to X4 having the meanings stated in the description, with the proviso that at least two mercapto groups are present in the compound or the compounds B.1; C) use of degreasing agents of the formula C.1 for degreasing pelts, hides or other intermediate stages and semifinished products in leather production, n and R16 to R21 having the meanings stated in the description; D) tanning with the use of a tanning agent which can be prepared by reacting at least one aldehyde of the formula D.1, with at least one further identical or different aldehyde of the formula D.1 in the presence of an acidic catalyst and optionally in the presence of at least one further carbonyl compound of the formula D.2 Z and R22 to R25 having the meanings stated in the description, with the proviso that, when Z corresponds to a single chemical bond or a radical without α-hydrogen atoms, at least one further aldehyde of the formula D.1, in which Z contains α-hydrogen atoms, or at least one further carbonyl compound of the formula D.2 is present.

4. 发明申请

US20050229326A1 Method for removing horn substance from skins, pelts or furs 失效
标题翻译：从皮肤，皮毛或毛皮去除角质物质的方法
公开(公告)号：US20050229326A1
公开(公告)日：2005-10-20
申请号：US10513800
申请日：2003-05-19
申请人： Tilman Taeger , Gunther Pabst , Philippe Lamalle , Stephan Huffer , Stefan Schroeder
发明人： Tilman Taeger , Gunther Pabst , Philippe Lamalle , Stephan Huffer , Stefan Schroeder
IPC分类号： C14C1/06 , C14C3/04 , C14C3/02
CPC分类号： C14C1/06
摘要： Horny substances are removed from hides, pelts or skins of dead animals by treating the hides, pelts or skins in aqueous liquor with one or more compounds of the formula I or their corresponding alkali metal or alkaline earth metal salts or ammonium or phosphonium salts, the variables being defined as follows: R1 is selected from hydrogen and C1-C12-alkyl, unsubstituted or substituted by one or more S—H or O—H groups; X1 to X4 are identical or different and are selected from hydrogen, C1-C4-alkyl, O—H, S—H and N—HR2, R2 is hydrogen or C1-C12-alkyl or a C1-C4-Alkyl-C═O group, at least one radical X1 to X4 being S—H when R1 contains at least one sulfur atom and at least two radicals X1 to X4 being S—H when R1 contains no sulfur atom.
摘要翻译：通过用一种或多种式I化合物或其相应的碱金属或碱土金属盐或铵盐或鏻盐处理含水液体中的皮革，皮毛或皮肤，从死皮的皮革，毛皮或皮肤中去除角质物质，变量定义如下：R 1选自氢和C 1 -C 12 - 烷基，未被取代或被一个或多个SH取代或OH基团; X 1至X 4相同或不同，并且选自氢，C 1 -C 4 - C 4 - 烷基，OH，SH和N-HR 2，R 2是氢或C 1 -C 12 - C 12 - 烷基或C 1 -C 4 - 烷基-CO基团，至少一个X 1至X 4 - 基团，当R 1含有至少一个硫原子时为SH，当R 1为至少两个X X 1至X 4时，SH 4为SH 不含硫原子。

5. 发明申请

US20050020790A1 Use of C4-C6-polymercaptopolyols as regulators in solution or precipitation polymerization 失效
标题翻译：在溶液或沉淀聚合中使用C4-C6聚合物多元醇作为调节剂
公开(公告)号：US20050020790A1
公开(公告)日：2005-01-27
申请号：US10887833
申请日：2004-07-12
申请人： Kathrin Michl , Tilman Taeger , Gunther Pabst , Philippe Lamalle , Stephan Huffer , Stefan Schroeder
发明人： Kathrin Michl , Tilman Taeger , Gunther Pabst , Philippe Lamalle , Stephan Huffer , Stefan Schroeder
IPC分类号： C08F2/00 , C08F2/10 , C08F2/38
CPC分类号： C08F2/38 , C08F2/10
摘要： The present invention relates to C4-C6-polymercaptopolyols as regulators in the free-radically initiated solution and precipitation polymerization of ethylenically unsaturated monomers.
摘要翻译：本发明涉及作为自由基引发溶液中的调节剂和烯属不饱和单体的沉淀聚合的C 4 -C 6 - 聚合物多元醇。

6. 发明申请

US20060101583A1 Adducts based on cyclic compounds and the use thereof as tanning agents and curing agents 失效
公开(公告)号：US20060101583A1
公开(公告)日：2006-05-18
申请号：US10543495
申请日：2004-01-21
申请人： Stephan Huffer , Oliver Reese , Wlater Gramlich , Stefan Schroeder , Gunter Scherr , Volker Bach
发明人： Stephan Huffer , Oliver Reese , Wlater Gramlich , Stefan Schroeder , Gunter Scherr , Volker Bach
IPC分类号： C14C1/00
CPC分类号： C07D307/32 , C07D309/30 , C14C3/18 , C14C9/02
摘要： The invention relates to adducts that can be obtained by reacting carbonyl compounds of general formula (I) in which the variables are defined as follows: R1 and R2 are selected among hydrogen, C1-C12 alkyl, C3-C12 cycloalkyl, substituted or unsubstituted, C7-C13 aralkyl, C6-C14 aryl, substituted or unsubstituted, whereby R1 and R2 can be bounds to one another while forming a ring. These carbonyl compounds are reacted with cyclic compounds of general formula (II) in which the variables are defined as follows: X is selected among oxygen, sulfur and N—R8; R3 and R8 are the same or different and are selected among hydrogen, C1-C12 alkyl, C3-C12 cycloalkyl, substituted or unsubstituted, C7-C13 aralkyl, C6-C14 aryl, substituted or unsubstituted, formyl, CO—C1-C12 alkyl, CO—C3-C12 cycloalkyl, substituted or unsubstituted, CO—C7-C13 aralkyl, CO—C6-C14 aryl, whereby in the event X═N—R8, R3 and R8 can be bound to one another while forming a ring; R4, R5 and R6 are the same or different and are selected among hydrogen, C1-C12 alkyl, C3-C12 cycloalkyl, substituted or unsubstituted, C7-C13 aralkyl, C6-C14 aryl, substituted or unsubstituted, whereby two adjacent radicals at time can be bound to one another while forming a ring; n represents a integer ranging from 1 to 4, and; R7 is the same or different and is selected among hydrogen, C1-C12 alkyl, C3-C12 cycloalkyl, substituted or unsubstituted, C7-C13 aralkyl, C6-C14 aryl, substituted or unsubstituted, whereby two adjacent radicals R7 at time can be bound to one another or R6 or R4 can be bound to adjacent R7 while forming a ring.

7. 发明申请

US20090172890A1 Method for Producing Leather 审中-公开
标题翻译：生产皮革的方法
公开(公告)号：US20090172890A1
公开(公告)日：2009-07-09
申请号：US11995511
申请日：2006-07-06
申请人： Stephan Huffer , Stefan Schroeder , Philippe Lamalle , Volker Bach
发明人： Stephan Huffer , Stefan Schroeder , Philippe Lamalle , Volker Bach
IPC分类号： C14C1/08
CPC分类号： C14C3/16
摘要： Process for the production of leather, wherein, after liming, deliming and, if appropriate, pickling, animal hides are pretanned or tanned with a mixture of compounds comprising(a) at least one organic tanning agent and (b) a mixture of (b1) at least one C3-C12-dicarboxylic acid (b2) and at least one further acidic compound selected from C1-C3-mono- or C3-C12-dicarboxylic acids, or salts thereof.
摘要翻译：用于生产皮革的方法，其中，在石灰化，分层，如果适用的酸洗后，用包含（a）至少一种有机鞣剂和（b）（b1）的混合物的混合物混合物将动物皮革预先或鞣制）至少一种C 3 -C 12二羧酸（b2）和至少一种选自C 1 -C 3 - 单 - 或C 3 -C 12 - 二羧酸的其它酸性化合物或其盐。

8. 发明申请

US20050125906A1 Tanning agent and curing agent based on dialdehydes 失效
标题翻译：鞣剂和基于二醛的固化剂
公开(公告)号：US20050125906A1
公开(公告)日：2005-06-16
申请号：US10511279
申请日：2003-05-02
申请人： Stephan Hüffer , Gunther Pabst , Tilman Taeger , Stefan Schroeder , Gerhard Wolf
发明人： Stephan Hüffer , Gunther Pabst , Tilman Taeger , Stefan Schroeder , Gerhard Wolf
IPC分类号： C07C45/72 , C14C3/16 , C14C3/00
CPC分类号： C07C45/72 , C14C3/16
摘要： The invention relates to a tanning agent that is produced by reacting at least one aldehyde of general formula (I) with at least another identical or different aldehyde of formula (I), wherein the variables are defined as follows: Z is a single chemical bond, an optionally substituted C1-C12-alkyl, an optionally substituted C5-C12-cycloalkyl or an optionally substituted C6-C14-aryl, wherein the reaction is carried out in the presence of an acid catalyst and optionally in the presence of at least another carbonyl compound of formula (II), R1 to R4 represent, independent of one another, hydrogen, optionally substituted C1-C12-allyl, optionally substituted C3-C12-cycloalkyl, optionally substituted C7-C13-aralkyl or optionally substituted C6-C14-aryl, provided that at least another aldehyde of formula (I) in which the radical of Z contains α hydrogen atoms or at least another carbonyl compound of formula (I) is present when Z is a single chemical bond or a radical without any hydrogen atoms. The invention also relates to a method for the production of said tanning agent, to the utilization thereof as curing agent, particularly for pretannage, tannage or retannage of animal skins using the inventive tanning agents. The invention further relates to a powder active agent containing one or more of said inventive tanning agents, to a method for the production of said powder active agents and to the use thereof as curing agent and to leather produced using the inventive tanning agents or the inventive method.
摘要翻译：本发明涉及通过使至少一种通式（I）的醛与至少另一相同或不同的式（I）的醛反应制备的鞣制剂，其中变量定义如下：Z是单一化学键，任选取代的C 1 -C 12 - 烷基，任选取代的C 5 -C 12 - 环烷基或任选取代的C 6 -C 14 - 芳基，其中反应在酸催化剂的存在下进行，并且任选地在至少另外一种羰基化合物存在下进行式（II）中，R 1至R 4彼此独立地表示氢，任选取代的C 1 -C 4烷基， 12-烯丙基，任选取代的C 3 -C 12 - 环烷基，任选取代的C 7 -C 13 - 或其任选取代的C 6 -C 14 - 芳基，条件是至少另一种式（I）的醛，其中th 当Z是单个化学键或没有任何氢原子的基团时，Z的基团含有α氢原子或至少另外一个式（I）的羰基化合物。本发明还涉及一种用于生产所述鞣剂的方法，其用作固化剂，特别是使用本发明的鞣剂对动物皮肤进行预处理，鞣制或回火处理。本发明还涉及含有一种或多种所述本发明的鞣剂的粉末活性剂，用于制备所述粉末活性剂的方法及其作为固化剂的用途，以及使用本发明的鞣剂或本发明制备的皮革方法。

9. 发明申请

US20060101584A1 Formulation for use in chrome or chrome-free tannage 失效
标题翻译：用于铬或无铬鞣革的配方
公开(公告)号：US20060101584A1
公开(公告)日：2006-05-18
申请号：US10524047
申请日：2003-08-14
申请人： Stephan Hueffer , Stefan Schroeder , Einhard Wagner , Thorsten Radler , Karl Vill
发明人： Stephan Hueffer , Stefan Schroeder , Einhard Wagner , Thorsten Radler , Karl Vill
IPC分类号： C14C3/00
CPC分类号： C14C3/16 , C14C3/28
摘要： A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 μm or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.
摘要翻译：提出了用于无铬或铬鞣制剂的制剂，其包含粘土矿物，其在50℃下在水中剧烈搅拌30分钟后具有小于2μm的数均粒径或双峰尺寸分布具有数均粒径小于0.5μm的第一细碎部分和数均粒径小于5μm的第二粗纱部分，通过组合的方法按照ISO 13320-1的方法确定激光衍射和光散射，第一细分的份数为10至90重量％，以及一种或多种下列一种或多种物质：有机聚合物，醛鞣剂，砜鞣剂，树脂鞣剂，苯酚鞣剂，加脂剂，植物鞣剂，染料和颜料。

10. 发明申请

US20070266501A1 Superficial Use of Cationic or Amphoteric Polymers on Semifinished Leather Products 审中-公开
标题翻译：在半成品皮革制品上表面使用阳离子或两性聚合物
公开(公告)号：US20070266501A1
公开(公告)日：2007-11-22
申请号：US10566967
申请日：2004-07-30
申请人： Gerhard Wolf , Stephan Huffer , Oliver Reese , Jurgen Decker , Georg Igl , Stefan Schroeder , Gunter Scherr
发明人： Gerhard Wolf , Stephan Huffer , Oliver Reese , Jurgen Decker , Georg Igl , Stefan Schroeder , Gunter Scherr
IPC分类号： C14C11/00 , D06P1/607
CPC分类号： C14C11/003 , D06P1/6076 , D06P3/32
摘要： A process for the treatment of leather comprises the following process steps: (a) Application of at least one cationic or amphoteric aqueous treatment composition to leather by roll coating and/or roll application and/or spray application, and subsequently (b) treatment of the leather with an anionic leather treatment composition in a drum.
摘要翻译：用于处理皮革的方法包括以下工艺步骤：（a）通过辊涂和/或辊施加和/或喷雾施用将至少一种阳离子或两性水处理组合物施用于皮革，随后（b）处理在皮革中用阴离子皮革处理组合物在鼓中。

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