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1. 发明申请

US20070259968A1 Macroporous Plastic Bead 审中-公开
标题翻译：大孔塑料珠
公开(公告)号：US20070259968A1
公开(公告)日：2007-11-08
申请号：US11719969
申请日：2005-11-08
申请人： Stefan Menzler , Christian Meier , Roger Recktenwald , Sabine Schwarz-Barac
发明人： Stefan Menzler , Christian Meier , Roger Recktenwald , Sabine Schwarz-Barac
IPC分类号： A61K47/32 , B01D15/08 , C08F110/00
CPC分类号： C08F2/18 , C08F222/385
摘要： (EN) The invention relates to a macroporous plastic bead material with a mean particle diameter of 10 to 1000 pm, radically polymerised from the following monomer types a) 5-40 wt. % vinylic polymerisable monomers with a water-solubility of at least 1% at 20° C. which are not vinylic polymerisable monomers with a quaternary amino group, b) 5-50 wt. % of vinylic polymerisable monomers with an additional functional group which can for covalent bonds on reaction with nucleophilic groups of ligands, c) 20-60 wt. % hydrophilic, cross-linking radically polymerisable monomers with two or more ethylenically-unsaturated polymerisable groups, characterised in that in addition d) 1 to 20 wt. % of a vinylic polymerisable monomer with a quaternary amino group are used for the polymer. The invention further relates to a method for production of the macroporous plastic bead material by inverse suspension polymerisation of monomer phase and uses thereof.
摘要翻译：（EN）本发明涉及一种平均粒径为10-1000μm的大孔塑料珠粒材料，其从以下单体类型自由基聚合a）5-40wt。在20℃下具有至少1％的水溶性的乙烯基可聚合单体，其不是具有季氨基的乙烯基可聚合单体，b）5-50wt。％的具有可与配体的亲核基团反应的共价键的另外的官能团的乙烯基可聚合单体，c）20-60wt。具有两个或更多个烯键式不饱和可聚合基团的亲水性交联自由基可聚合单体，其特征在于另外d）1至20wt。用于聚合物的具有季氨基的乙烯基可聚合单体的％。本发明还涉及通过单体相的反相悬浮聚合及其用途来生产大孔塑料珠粒材料的方法。

2. 发明授权

US07381552B2 Macroporous material in the form of plastic pearls 失效
标题翻译：大孔材料以塑料珠的形式
公开(公告)号：US07381552B2
公开(公告)日：2008-06-03
申请号：US10498971
申请日：2003-08-25
申请人： Stefan Menzler , Hans-Ulrich Petereit , Christian Meier , Thomas Boller , Thomas Suefke , Klaus Schultes , Roger Recktenwald
发明人： Stefan Menzler , Hans-Ulrich Petereit , Christian Meier , Thomas Boller , Thomas Suefke , Klaus Schultes , Roger Recktenwald
IPC分类号： C12N11/08 , G01N33/545 , C07K17/08
CPC分类号： C08F220/28 , C08F246/00 , Y10S530/815
摘要： The invention relates to a macroporous plastics bead material with an average particle diameter from 10 to 1000 μm, containing a copolymer of a) 5-60 wt. % vinylically polymerizable monomers with a water solubility of at least 1% at 20° C., b) 1-40 wt. % vinylically polymerizable monomers with an additional functional group, which can enter into covalent bonds with the nucleophilic groups of the ligands in a polymer-like reaction, c) 10-40 wt. % hydrophilic, crosslinking radical-polymerizable monomers with two or more ethylenically unsaturated polymerizable groups and d) 10-60 wt. % vinylically polymerizable monomers with a water solubility of at most 1% at 20° C. are contained, as a rule with the monomers a) to d) adding up to 100%.
摘要翻译：本发明涉及平均粒径为10-1000μm的大孔塑料珠粒材料，其含有a）5-60wt。％乙烯基聚合性单体，水溶性在20℃下至少为1％，b）1-40wt。具有另外的官能团的具有可与聚合物样反应中的配体的亲核基团共价键的乙烯基聚合性单体的％，c）10-40wt。具有两个或更多个烯属不饱和可聚合基团的亲水性交联自由基聚合单体，和d）10-60wt。在20℃下水溶解度最多为1％的％乙烯基聚合性单体的含量通常与单体a）至d）相加至100％。

3. 发明申请

US20050065224A1 Macroporous material in the form of plastic pearls 失效
标题翻译：大孔材料以塑料珍珠的形式
公开(公告)号：US20050065224A1
公开(公告)日：2005-03-24
申请号：US10498971
申请日：2003-08-25
申请人： Stefan Menzler , Hans-Ulrich Petereit , Christian Meier , Thomas Boller , Thomas Suefke , Klaus Schultes , Roger Recktenwald
发明人： Stefan Menzler , Hans-Ulrich Petereit , Christian Meier , Thomas Boller , Thomas Suefke , Klaus Schultes , Roger Recktenwald
IPC分类号： C08F220/28 , C08F246/00 , C08J9/00 , C08F118/02
CPC分类号： C08F220/28 , C08F246/00 , Y10S530/815
摘要： The invention relates to a macroporous plastics bead material with an average particle diameter from 10 to 1000 μm, containing a copolymer of a) 5-60 wt. % vinylically polymerizable monomers with a water solubility of at least 1% at 20° C., b) 1-40 wt. % vinylically polymerizable monomers with an additional functional group, which can enter into covalent bonds with the nucleophilic groups of the ligands in a polymer-like reaction, c) 10-40 wt. % hydrophilic, crosslinking radical-polymerizable monomers with two or more ethylenically unsaturated polymerizable groups and d) 10-60 wt. % vinylically polymerizable monomers with a water solubility of at most 1% at 20° C. are contained, as a rule with the monomers a) to d) adding up to 100%.
摘要翻译：本发明涉及平均粒径为10-1000μm的大孔塑料珠粒材料，其含有a）5-60wt。％乙烯基聚合性单体，水溶性在20℃下至少为1％，b）1-40wt。具有另外的官能团的具有可与聚合物样反应中的配体的亲核基团共价键的乙烯基聚合性单体的％，c）10-40wt。具有两个或更多个烯属不饱和可聚合基团的亲水性交联自由基聚合单体，和d）10-60wt。在20℃下水溶解度最多为1％的％乙烯基聚合性单体的含量通常与单体a）至d）相加至100％。

4. 发明申请

US20050084925A1 Method for producing cephalexin 失效
标题翻译：生产头孢氨苄的方法
公开(公告)号：US20050084925A1
公开(公告)日：2005-04-21
申请号：US10501140
申请日：2003-10-16
申请人： Stefan Menzler , Thomas Boller , Hans-Ulrich Petereit , Christian Meier
发明人： Stefan Menzler , Thomas Boller , Hans-Ulrich Petereit , Christian Meier
IPC分类号： C12P35/04 , C12P35/00 , C07D501/14
CPC分类号： C12P35/04
摘要： The invention relates to a process for the preparation of cephalexin with the aid of a penicillin amidase immobilized on a crosslinked hydrophilic copolymer which has binding activity for ligands having nucleophilic groups and is in bead form.
摘要翻译：本发明涉及一种借助于固定在交联的亲水共聚物上的青霉素酰胺酶来制备头孢氨苄的方法，所述交联的亲水共聚物对具有亲核基团的配体具有结合活性且呈珠粒形式。

5. 发明授权

US07264943B2 Method for producing cephalexin 失效
标题翻译：生产头孢氨苄的方法
公开(公告)号：US07264943B2
公开(公告)日：2007-09-04
申请号：US10501140
申请日：2003-10-16
申请人： Stefan Menzler , Thomas Boller , Hans-Ulrich Petereit , Christian Meier
发明人： Stefan Menzler , Thomas Boller , Hans-Ulrich Petereit , Christian Meier
IPC分类号： C07D501/22 , C12P35/04
CPC分类号： C12P35/04
摘要： The invention relates to a process for the preparation of cephalexin with the aid of a penicillin amidase immobilized on a crosslinked hydrophilic copolymer which has binding activity for ligands having nucleophilic groups and is in bead form.
摘要翻译：本发明涉及一种借助于固定在交联的亲水共聚物上的青霉素酰胺酶来制备头孢氨苄的方法，所述交联的亲水共聚物对具有亲核基团的配体具有结合活性且呈珠粒形式。

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