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    • 8. 发明授权
    • Method for the production of unsaturated nitriles from alkanes
    • 从烷烃生产不饱和腈的方法
    • US07271279B2
    • 2007-09-18
    • US10482326
    • 2002-06-25
    • Frieder BorgmeierFrank RosowskiGoetz-Peter Schindler
    • Frieder BorgmeierFrank RosowskiGoetz-Peter Schindler
    • C07C253/18C07C255/08
    • C07C253/26B01J27/199C07C45/33C07C45/35Y02P20/52C07C47/22C07C255/08
    • The invention relates to a process for preparing unsaturated nitrites from the corresponding alkanes which comprises the steps: a) feeding an alkane into a dehydrogenation zone and catalytically dehydrogenating the alkane to the corresponding alkene to obtain a product gas stream A which comprises the alkene, unconverted alkane and possibly one or more further gas components selected from the group consisting of steam, hydrogen, carbon oxides, hydrocarbons having a lower boiling point than the alkane or the alkene (low-boilers), nitrogen and noble gases, b) at least partially removing further gas components from the product gas stream A to give a feed gas stream B which comprises the alkane and the alkene, c) feeding the feed gas stream B, ammonia, an oxygen-containing gas and, if desired, steam into an oxidation zone and catalytically ammoxidizing the alkene to the corresponding unsaturated nitrile to give a product gas stream C which comprises the unsaturated nitrile, ammoxidation by-products, unconverted alkane and alkene and possibly one or more further gas components selected from the group consisting of steam, oxygen, carbon oxides, ammonia, nitrogen and noble gases, d) optionally removing ammonia from the product gas stream C to give an ammonia-depleted product gas stream D, e) removing the unsaturated nitrile and ammoxidation by-products from the product gas stream C or D by absorption in an aqueous absorbent to give a gas stream E which comprises unconverted alkane and alkene and possibly one or more further gas components selected from the group consisting of oxygen, carbon oxides, ammonia, nitrogen and noble gases, and an aqueous stream which comprises the nitrile and the by-products, and recovery of the unsaturated nitrile from the aqueous stream, f) recycling the gas stream E into the dehydrogenation zone.
    • 本发明涉及从相应的烷烃制备不饱和亚硝酸盐的方法,其包括以下步骤:a)将烷烃进料到脱氢区中,并将烷烃催化脱氢至相应的烯烃,得到产物气流A,其包含未转化的烯烃 烷烃和可能的一种或多种另外的气体组分,其选自蒸汽,氢气,碳氧化物,沸点低于烷烃或烯烃(低沸点)的烃,氮气和惰性气体,b)至少部分 从产物气流A中除去进一步的气体组分,得到包含烷烃和烯烃的进料气流B,c)将进料气流B,氨,含氧气体和如果需要的话进料到氧化物 并将烯烃催化氨基化成相应的不饱和腈,得到包含不饱和腈的产物气流C,通过 - 产物,未转化的烷烃和烯烃以及可能的一种或多种另外的气体组分,其选自蒸汽,氧气,碳氧化物,氨,氮气和惰性气体,d)任选地从产物气流C除去氨,得到氨 分离的产物气流D,e)通过在含水吸收剂中吸收从产物气流C或D中除去不饱和腈和氨氧化副产物,得到包含未转化的烷烃和烯烃的气流E,以及可能一个或多个另外的 选自氧,碳氧化物,氨,氮和惰性气体的气体组分和包含腈和副产物的水流,以及从水流中回收不饱和腈,f)将气体再循环 流E进入脱氢区。