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    • 4. 发明授权
      US06559100B1 2-benzoyl-cyclohexane-1,3-diones 失效
    • 2-benzoyl-cyclohexane-1,3-diones
    • US06559100B1
    • 2003-05-06
    • US09485223
    • 2000-02-07
    • Stefan Engel , Joachim Rheinheimer , Ernst Baumann , Wolfgang von Deyn , Regina Luise Hill , Guido Mayer , Ulf Misslitz , Oliver Wagner , Matthias Witschel , Martina Otten , Helmut Walter , Karl-Otto Westphalen
    • Stefan Engel , Joachim Rheinheimer , Ernst Baumann , Wolfgang von Deyn , Regina Luise Hill , Guido Mayer , Ulf Misslitz , Oliver Wagner , Matthias Witschel , Martina Otten , Helmut Walter , Karl-Otto Westphalen
    • C07D2604
    • C07D307/58 , A01N43/80 , C07D261/04
    • Substituted 2-benzoylcyclohexane-1,3-diones of the formula I where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3, —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups: hydroxyl, mercapto, amino, cyano, R3, —OR3, —SR3, —N(R3)2, ═NOR3, —OCOR3, —SCOR3, —NR3COR3, —CO2R3, —COSR3, —CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted; n is 0, 1 or 2; Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2; X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups: —OR4, —OCOR4, —OCONHR4 or —OSO2R4; except for those of the abovementioned alkenylene radicals where the double bond is &agr;,&bgr; to the phenyl ring and where Het is linked to the double bond via the &bgr; position; R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals: hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of: nitrogen, oxygen or sulfur, where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5; R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals: cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 5. 发明授权
      US06500950B1 Benzylidenepyrazolones, their preparation and use 失效
    • Benzylidenepyrazolones, their preparation and use
    • 亚苄基吡唑啉酮，其制备和用途
    • US06500950B1
    • 2002-12-31
    • US09765626
    • 2001-01-22
    • Joachim Rheinheimer , Matthias Witschel , Stefan Engel , Ernst Baumann , Wolfgang von Deyn , Regina Luise Hill , Guido Mayer , Ulf Misslitz , Oliver Wagner , Martina Otten , Karl-Otto Westphalen , Helmut Walter
    • Joachim Rheinheimer , Matthias Witschel , Stefan Engel , Ernst Baumann , Wolfgang von Deyn , Regina Luise Hill , Guido Mayer , Ulf Misslitz , Oliver Wagner , Martina Otten , Karl-Otto Westphalen , Helmut Walter
    • C07D41310
    • C07D413/06 , A01N43/56 , A01N43/78 , A01N43/80 , C07D231/16 , C07D231/20
    • Benzylidenepyrazolones of the formula I, where the substituents and the index n have the following meanings: R1 is unsubstituted or substituted C1-C6-alkyl; R2 is unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, halogen, nitro, cyano; R3 is hydrogen, halogen, nitro, cyano, a group NR5R6, OCOR5, NR5COR6, CO2R5, —COSR5, —CONR5R6, C1-C4-alkoxyiminoalkyl, C1-C6-alkylcarbonyl, unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, unsubstituted or substituted C1-C6-alkylthio, unsubstituted or substituted C2-C6-alkenyl, unsubstituted or substituted C2-C6-alkynyl, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, an unsubstituted or substituted 5- or 6-membered saturated or unsaturated heterocycle which may contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulfur atoms as ring members; R4 is C1-C6-alkyl, C1-C4-haloalkyl; R3 and R4 form an optionally substituted saturated or unsaturated 2- or 3-membered bridge which may contain a sulfur atom which may be oxidized to the sulfoxide or sulfone; R5 is hydrogen or unsubstituted or substituted C1-C6-alkyl; R6 is unsubstituted or substituted C1-C6-alkyl; R7 is hydrogen, C1-C6-alkyl or C1-C4-haloalkyl; n is 0,1 or 2, X is hydrogen, chlorine or bromine; where the compounds claimed may be present both in the trans and in the cis form or as a mixture of these isomers, are described.
    • 式I的亚苄基吡唑酮，其中取代基和指数n具有以下含义：R 1是未取代的或取代的C 1 -C 6 - 烷基; R 2是未取代的或取代的C 1 -C 6 - 烷基，未取代或取代的C 1 -C 6 - 烷氧基，卤素 硝基，氰基; R 3是氢，卤素，硝基，氰基，NR 5 R 6，OCOR 5，NR 5 COR 6，CO 2 R 5，-COSR 5，-CONR 5 R 6，C 1 -C 4烷氧基亚氨基烷基，C 1 -C 6烷基羰基，未取代或取代的C 1 -C 6 - 未取代或取代的C 1 -C 6 - 烷硫基，未取代或取代的C 2 -C 6 - 烯基，未取代或取代的C 2 -C 6 - 炔基，未取代或取代的苯基，未取代或取代的苯氧基，未取代的 或可以含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的取代的5或6元饱和或不饱和杂环; R 4是C 1 -C 6烷基，C 1 -C 4卤代烷基; R 3和 R4形成任选取代的饱和或不饱和的2-或3-元 桥可以含有可被氧化成亚砜或砜的硫原子; R5是氢或未取代或取代的C1-C6-烷基; R6是未取代的或取代的C1-C6-烷基; R7是氢，C1-C6-烷基 或C 1 -C 4卤代烷基; n为0,1或2，X为氢，氯或溴;其中要求保护的化合物可以以反式和顺式形式存在，或以这些异构体的混合物存在。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
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