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    • 1. 发明申请
    • OXYGEN-PERMEABLE MEMBRANE AND METHOD FOR THE PRODUCTION THEREOF
    • 氧渗透膜及其生产方法
    • US20110020192A1
    • 2011-01-27
    • US12736015
    • 2009-02-21
    • Stefan BaumannJose Manuel Serra AlfaroWilhelm Albert MeulenbergHans-Peter BuchkremerDetlev Stoever
    • Stefan BaumannJose Manuel Serra AlfaroWilhelm Albert MeulenbergHans-Peter BuchkremerDetlev Stoever
    • B01J35/02B01D53/22B01D71/02B05D5/00
    • B01D71/024B01D53/228B01D67/0048B01D67/0072B01D69/10B01D69/12B01D69/141B01D2323/46B01D2325/02B01D2325/04B01D2325/10B01D2325/24C01B13/0255
    • The invention relates to a composite membrane for selective gas separation, comprising a layer system having a through-and-through porous, mechanically stable carrier layer, which has an average pore size in the μm range, further having at least one through-and-through porous intermediate layer, which is disposed on the carrier layer and has an average pore size in the range between 2 and 200 nm, and further having a gas-tight functional layer, which is disposed on the intermediate layer and is made of mixed-conductive material having a maximum layer thickness of 1 μm. The carrier layer comprises structural ceramics, a metal or a cermet and has a layer thickness of no more than 1 mm. The intermediate layer is present in a total layer thickness of no more than 100 μm and has an average pore size in the range of 10 and 100 nm. The functional layer comprises a perovskite, a fluorite, or a material having a K2NiF4structure, such as La1-xSrxCo1-yFeyO3-δ(LSCF). The layer thickness of the functional layer is no more than 50 nm, particularly between 25 and 400 nm. In order to produce said composite membrane, at least one porous intermediate layer is applied onto a through-and-through porous, mechanically stable carrier layer, which has an average pore size in the μm range, said intermediate layer having an average pore size in the range between 2 and 200 nm. A further gas-tight, functional layer made of a mixed-conductive material and having a maximum layer thickness of 1 μm is applied onto said intermediate layer.
    • 本发明涉及一种用于选择性气体分离的复合膜,包括具有通孔多孔机械稳定载体层的层系统,其具有μm范围内的平均孔径,还具有至少一个通孔, 通过多孔中间层,其设置在载体层上,平均孔径在2〜200nm的范围内,并且还具有气密功能层,其设置在中间层上, 导电材料的最大层厚度为1μm。 载体层包括结构陶瓷,金属或金属陶瓷,层厚度不大于1mm。 中间层的总层厚不超过100μm,平均孔径在10和100nm的范围内。 功能层包括钙钛矿,萤石或具有K2NiF4结构的材料,例如La1-xSrxCo1-yFeyO3-δ(LSCF)。 功能层的层厚不大于50nm,特别是在25和400nm之间。 为了制造所述复合膜,将至少一个多孔中间层施加到通孔多孔的,机械稳定的载体层上,其平均孔径在μm范围内,所述中间层的平均孔径为 范围在2到200 nm之间。 将由混合导电材料制成并且具有最大层厚度为1μm的另外的气密功能层施加到所述中间层上。
    • 2. 发明授权
    • Oxygen-permeable membrane and method for the production thereof
    • 透氧膜及其制造方法
    • US08486184B2
    • 2013-07-16
    • US12736015
    • 2009-02-21
    • Stefan BaumannJose Manuel Serra AlfaroWilhelm Albert MeulenbergHans-Peter BuchkremerDetlev Stoever
    • Stefan BaumannJose Manuel Serra AlfaroWilhelm Albert MeulenbergHans-Peter BuchkremerDetlev Stoever
    • B01D53/22B01D71/02
    • B01D71/024B01D53/228B01D67/0048B01D67/0072B01D69/10B01D69/12B01D69/141B01D2323/46B01D2325/02B01D2325/04B01D2325/10B01D2325/24C01B13/0255
    • A composite membrane for selective gas separation, comprises a layer system having a continuously porous, mechanically stable carrier layer, which has an average pore size in the μm range, further having at least one continuously porous intermediate layer, which is disposed on the carrier layer and has an average pore size in the range of 2 to 200 nm, and further having a gastight functional layer, which is disposed on the intermediate layer and is made of a mixed-conductive material having a maximum layer thickness of 1 μm. The carrier layer comprises a structural ceramic, a metal, or a cermet and has a layer thickness of no more than 1 mm. The intermediate layer is present with a total layer thickness of no more than 100 μm and has an average pore size in the range of 10 to 100 nm. The functional layer comprises a perovskite, a fluorite, or a material having a K2NiF4 structure, such as La1-xSrxCo1-yFeyO3-8 (LSCF). The layer thickness of the functional layer is no more than 50 nm, and particularly between 25 and 400 nm. In order to produce this composite membrane, at least one porous intermediate layer is applied onto a continuously porous, mechanically stable carrier layer, which has an average pore size in the μm range, wherein the intermediate layer has an average pore size in the range of 2 to 200 nm. A further gastight, functional layer made of a mixed-conductive material and having a maximum layer thickness of 1 μm is applied onto the intermediate layer.
    • 一种用于选择性气体分离的复合膜,包括具有连续多孔的,机械稳定的载体层的层系统,其具有在mum范围内的平均孔径,还具有至少一个连续多孔中间层,其设置在载体层 平均孔径在2〜200nm的范围内,进一步具有气密功能层,其设置在中间层上并由最大层厚度为1μm的混合导电材料制成。 载体层包括结构陶瓷,金属或金属陶瓷,并且具有不超过1mm的层厚度。 中间层的总层厚度不超过100μm,平均孔径在10〜100nm的范围内。 功能层包括钙钛矿,萤石或具有K2NiF4结构的材料,例如La1-xSrxCo1-yFeyO3-8(LSCF)。 功能层的层厚不大于50nm,特别是在25和400nm之间。 为了制造这种复合膜,至少一个多孔中间层被施加到连续多孔的,机械稳定的载体层上,该载体层的平均孔径在该范围内,其中中间层的平均孔径在 2〜200nm。 将进一步气密的由混合导电材料制成并具有最大层厚度为1μm的功能层施加到中间层上。
    • 4. 发明申请
    • POWER PLANT THAT USES A MEMBRANE AND METHOD FOR OPERATING THE SAME
    • 使用膜的动力装置及其操作方法
    • US20100263377A1
    • 2010-10-21
    • US12734682
    • 2008-10-29
    • Wilhelm Albert MeulenbergStefan BaumannLudger BlumErnst Riensche
    • Wilhelm Albert MeulenbergStefan BaumannLudger BlumErnst Riensche
    • F01K13/00F01K7/16
    • B01D53/22B01D2256/12F23C9/00F23C2202/30F23L7/007F23L15/00F23L2900/07001Y02E20/322Y02E20/344Y02E20/348
    • Provided is a power plant for generating electrical energy comprising a combustion chamber for producing steam, at least one downstream flue gas purification stage, a separation stage for CO2, a recycling circuit for the flue gas, and a high-temperature O2 membrane, which is connected upstream of the combustion chamber. The high-temperature O2 membrane has an inlet and an outlet on the feed side which are thermally coupled by way of a heat exchanger. On the permeate side, the high-temperature O2 membrane has only an outlet which is connected to the combustion chamber and/or the flue gas recycling circuit and a means for cooling and/or compression which is disposed in this outlet. The power plant, in which coal is burned using substantially pure oxygen, and in which the combustion waste gas is purified and partially recirculated to the combustion process, is operated in such a way that the oxygen that is used is obtained by separation from air using a high-temperature O2 membrane, wherein the membrane is operated with atmospheric air at a pressure of up to 2 bar on the feed side and a negative pressure of between 0.02 and 0.5 bar is applied on the permeate side.
    • 提供一种用于产生电能的发电厂,其包括用于产生蒸汽的燃烧室,至少一个下游烟道气净化级,用于CO 2的分离级,用于烟道气的回收回路和高温O 2膜,其是 连接在燃烧室的上游。 高温O 2膜在进料侧具有通过热交换器热耦合的入口和出口。 在渗透侧,高温O 2膜仅具有连接到燃烧室和/或烟道气回收回路的出口以及设置在该出口中的用于冷却和/或压缩的装置。 使用基本纯净的氧燃烧煤并且其中燃烧废气被净化并部分地再循环到燃烧过程的发电厂以这样的方式运行,使得使用的氧气通过使用 高温O2膜,其中膜在进料侧的压力为2巴的大气中进行操作,并且在渗透侧施加0.02至0.5巴的负压。
    • 5. 发明申请
    • Power station and method for operating the same
    • 电站及其运行方法
    • US20120060728A1
    • 2012-03-15
    • US13138977
    • 2010-04-03
    • Jewgeni NazarkoErnst RienscheReinhard MenzerWilhelm Albert MeulenbergStefan Baumann
    • Jewgeni NazarkoErnst RienscheReinhard MenzerWilhelm Albert MeulenbergStefan Baumann
    • F23C9/00F23L15/00F23L7/00F23J15/00
    • F23L7/007F23C9/00F23C2202/30F23J15/06F23J15/08F23J2215/50F23L2900/07001Y02E20/322Y02E20/344Y02E20/363
    • A combustion system comprising a burner and a combustion chamber, is connected by way of a line to a membrane unit having a high-temperature membrane for extracting the combustion oxygen from the air, the membrane unit having a feed line for a flushing gas on the permeate side. The combustion system further comprises a circulation element for recirculated flue gas, a heat exchanger being disposed upstream of the membrane unit inside the flue gas line. Disclosed is a method for operating this combustion system, in which carbon-containing fuel is burned in an oxygen-flue gas atmosphere, and in which the oxygen for combustion is produced from air by means of a membrane unit comprising a high-temperature membrane, and in which the flue gas is in part recirculated. Disclosed are the steps of first cooling the recirculated flue gas, optionally for a flue gas scrubbing process, subsequently reheating the cooled flue gas to ensure the necessary operating temperature of the membrane, the heating energy being extracted by way of a heat exchange with the flue gas having the corresponding temperature level of the combustion process, and feeding the flue gas heated in this manner to the membrane unit as a flushing gas.
    • 包括燃烧器和燃烧室的燃烧系统通过管线连接到具有用于从空气中提取燃烧氧的高温膜的膜单元,所述膜单元具有用于冲洗气体的进料管线 渗透面 燃烧系统还包括用于再循环烟道气的循环元件,热交换器设置在烟道气管线内部的膜单元的上游。 公开了一种操作该燃烧系统的方法,其中含碳燃料在氧 - 烟气气氛中燃烧,其中通过包含高温膜的膜单元由空气产生用于燃烧的氧, 并且其中烟道气部分地再循环。 公开了首先冷却再循环烟道气的步骤,任选地用于烟道气洗涤过程,随后重新加热冷却的烟道气以确保膜的必要操作温度,加热能量通过与烟道的热交换提取 气体具有相应的燃烧过程的温度水平,并将以这种方式加热的烟道气供给到膜单元作为冲洗气体。
    • 6. 发明授权
    • Power plant that uses a membrane and method for operating the same
    • 使用膜的发电厂及其操作方法
    • US08506678B2
    • 2013-08-13
    • US12734682
    • 2008-10-29
    • Wilhelm Albert MeulenbergStefan BaumannLudger BlumErnst Riensche
    • Wilhelm Albert MeulenbergStefan BaumannLudger BlumErnst Riensche
    • B01D53/22
    • B01D53/22B01D2256/12F23C9/00F23C2202/30F23L7/007F23L15/00F23L2900/07001Y02E20/322Y02E20/344Y02E20/348
    • Provided is a power plant for generating electrical energy comprising a combustion chamber for producing steam, at least one downstream flue gas purification stage, a separation stage for CO2, a recycling circuit for the flue gas, and a high-temperature O2 membrane, which is connected upstream of the combustion chamber. The high-temperature O2 membrane has an inlet and an outlet on the feed side which are thermally coupled by way of a heat exchanger. On the permeate side, the high-temperature O2 membrane has only an outlet which is connected to the combustion chamber and/or the flue gas recycling circuit and a means for cooling and/or compression which is disposed in this outlet. The power plant, in which coal is burned using substantially pure oxygen, and in which the combustion waste gas is purified and partially recirculated to the combustion process, is operated in such a way that the oxygen that is used is obtained by separation from air using a high-temperature O2 membrane, wherein the membrane is operated with atmospheric air at a pressure of up to 2 bar on the feed side and a negative pressure of between 0.02 and 0.5 bar is applied on the permeate side.
    • 提供一种用于产生电能的发电厂,其包括用于产生蒸汽的燃烧室,至少一个下游烟道气净化级,用于CO 2的分离级,用于烟道气的回收回路和高温O 2膜,其是 连接在燃烧室的上游。 高温O 2膜在进料侧具有通过热交换器热耦合的入口和出口。 在渗透侧,高温O 2膜仅具有连接到燃烧室和/或烟道气回收回路的出口以及设置在该出口中的用于冷却和/或压缩的装置。 使用基本纯净的氧燃烧煤并且其中燃烧废气被净化并部分地再循环到燃烧过程的发电厂以这样的方式运行,使得使用的氧气通过使用 高温O2膜,其中膜在进料侧的压力为2巴的大气中进行操作,并且在渗透侧施加0.02至0.5巴的负压。