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    • 8. 发明授权
    • Catalytic conversion of hydrocarbons to hydrogen and high-value carbon
    • 碳氢化合物催化转化为氢和高碳
    • US06875417B1
    • 2005-04-05
    • US10279489
    • 2002-10-24
    • Naresh ShahDevadas PanjalaGerald P. Huffman
    • Naresh ShahDevadas PanjalaGerald P. Huffman
    • B01J23/755B01J23/80B01J23/84B01J23/881B01J23/89B01J37/00B01J37/03B01J37/18C01B3/26
    • B82Y30/00B01J23/755B01J23/80B01J23/84B01J23/881B01J23/8906B01J37/0009B01J37/03B01J37/18C01B3/26C01B2203/0277C01B2203/1041C01B2203/1047C01B2203/1076C01B2203/1241
    • The present invention provides novel catalysts for accomplishing catalytic decomposition of undiluted light hydrocarbons to a hydrogen product, and methods for preparing such catalysts. In one aspect, a method is provided for preparing a catalyst by admixing an aqueous solution of an iron salt, at least one additional catalyst metal salt, and a suitable oxide substrate support, and precipitating metal oxyhydroxides onto the substrate support. An incipient wetness method, comprising addition of aqueous solutions of metal salts to a dry oxide substrate support, extruding the resulting paste to pellet form, and calcining the pellets in air is also discloses. In yet another aspect, a process is provided for producing hydrogen from an undiluted light hydrocarbon reactant, comprising contacting the hydrocarbon reactant with a catalyst as described above in a reactor, and recovering a substantially carbon monoxide-free hydrogen product stream. In still yet another aspect, a process is provided for catalytic decomposition of an undiluted light hydrocarbon reactant to obtain hydrogen and a valuable multi-walled carbon nanotube coproduct.
    • 本发明提供了用于实现未稀释的轻烃催化分解成氢产物的新催化剂,以及制备这种催化剂的方法。 在一个方面,提供了一种通过混合铁盐水溶液,至少一种另外的催化剂金属盐和合适的氧化物底物载体以及将金属羟基氧化物沉淀到基材载体上来制备催化剂的方法。 初始润湿方法,包括将金属盐水溶液加入到干氧化物基质载体中,将所得糊料挤出成颗粒形式,并在空气中煅烧颗粒。 在另一方面,提供了用于从未稀释的轻烃反应物生产氢的方法,包括如上所述在反应器中使烃反应物与催化剂接触,并回收基本上一氧化碳的氢产物流。 在另一方面,提供了一种用于未稀释的轻烃反应物的催化分解以获得氢气和有价值的多壁碳纳米管副产物的方法。