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1. 发明授权

US06677412B2 Process for preparing a highly active metallocene catalyst supported on polymer bead for olefin polymerization 失效
标题翻译：制备负载于聚合物珠粒上用于烯烃聚合的高活性金属茂催化剂的方法
公开(公告)号：US06677412B2
公开(公告)日：2004-01-13
申请号：US10118617
申请日：2002-04-02
申请人： Son-Ki Ihm , Ki-Soo Lee , O-Yong Jeong
发明人： Son-Ki Ihm , Ki-Soo Lee , O-Yong Jeong
IPC分类号： C08F444
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/6592 , C08F110/02 , Y10S502/507 , Y10S526/904 , C08F4/65916
摘要： The present invention relates to a process for preparing a highly active metallocene catalyst supported on polymer bead for olefin polymerization, a metallocene catalyst prepared by the said process and a method for alkylene polymerization by employing the said catalyst. The process for preparing a highly active metallocene catalyst supported on polymer bead for olefin polymerization which comprises the steps of: dissolving divinylbenzene, vinylbenzylchloride, and an initiator in an organic solvent, mixing it with a suspension stabilizer of aqueous phase, and carrying out suspension-polymerization at the temperature of 40 to 80° C. to obtain polystyrene; swelling the polystyrene in dialcoholamine dissolved in an organic solvent at ambient temperature for 1 to 3 days, to give a polymer having a functional group of dialcoholamine; and, reacting the polymer with a metallocene compound (CpM*Cl3) dissolved in an organic solvent. The metallocene catalyst of the present invention can be used widely for ethylene polymerization, styrene polymerization and copolymerization, while replacing the conventional homogeneous catalysts.
摘要翻译：本发明涉及一种负载在用于烯烃聚合的聚合物珠上的高活性茂金属催化剂的方法，通过所述方法制备的茂金属催化剂和通过使用所述催化剂进行亚烷基聚合的方法。制备负载在用于烯烃聚合的聚合物珠子上的高活性金属茂催化剂的方法，该方法包括以下步骤：将二乙烯基苯，乙烯基苄基氯和引发剂溶解在有机溶剂中，将其与水相的悬浮稳定剂混合，在40〜80℃的温度下进行聚合，得到聚苯乙烯; 在环境温度下溶解在有机溶剂中的二元醇胺中使聚苯乙烯溶胀1至3天，得到具有二醇胺官能团的聚合物; 并使聚合物与溶解在有机溶剂中的茂金属化合物（CpM * Cl3）反应。本发明的茂金属催化剂可以广泛用于乙烯聚合，苯乙烯聚合和共聚，同时代替常规的均相催化剂。

2. 发明授权

US06376562B1 Hybrid catalyst for hydrocarbon synthesis via hydrogenation of carbon dioxide 失效
标题翻译：用二氧化碳氢化合成碳氢化合物的混合催化剂
公开(公告)号：US06376562B1
公开(公告)日：2002-04-23
申请号：US09409272
申请日：1999-09-30
申请人： Son-Ki Ihm , Young-Kwon Park , Jong-Ki Jeon , Kwang-Eun Jeong
发明人： Son-Ki Ihm , Young-Kwon Park , Jong-Ki Jeon , Kwang-Eun Jeong
IPC分类号： B01J2985
CPC分类号： C10G2/50 , B01J23/26 , B01J23/44 , B01J23/80 , B01J29/85 , B01J35/0006 , C07C29/153 , C07C29/154 , Y02P20/52 , C07C31/04
摘要： The present invention provides a hybrid catalyst which is prepared by mixing a methanol synthesis catalyst with SAPO-type zeolite as a methanol conversion catalyst, and a process for the preparation of hydrocarbons from carbon dioxide by using the hybrid catalyst. The hybrid catalyst of the invention can be used for preparing hydrocarbons having a carbon number of more than 2 from carbon dioxide under a relatively on the hydrocarbons produced. Therefore, the hybrid catalyst may be used for preparing various high-valued hydrocarbons from an ubiquitous carbon source of carbon dioxide.
摘要翻译：本发明提供了通过将甲醇合成催化剂与作为甲醇转化催化剂的SAPO型沸石混合制备的混合催化剂，以及通过使用该混合催化剂从二氧化碳制备烃的方法。本发明的混合催化剂可以在相对于所生产的烃上从二氧化碳制备碳数大于2的碳氢化合物。因此，混合催化剂可用于从普遍存在的二氧化碳碳源制备各种高价烃。

3. 发明授权

US5968228A Process for preparing cobalt metals using nitrogen reductant 失效
标题翻译：使用氮还原剂制备钴金属的方法
公开(公告)号：US5968228A
公开(公告)日：1999-10-19
申请号：US148223
申请日：1998-09-04
申请人： Son-Ki Ihm , Do-Woan Kim , Dong-Keun Lee
发明人： Son-Ki Ihm , Do-Woan Kim , Dong-Keun Lee
IPC分类号： C22B5/12 , C22B23/02 , C22B23/00 , C01G1/00 , C22B15/00
CPC分类号： C22B5/12 , C22B23/021
摘要： The present invention relates to a process for preparing cobalt metals by reducing cobalt oxides with ammonia or nitrogen/hydrogen gas mixtures. In accordance with the present invention, a cobalt metal is economically prepared by reacting a cobalt oxide with a nitrogen reductant at a temperature of 300 to 550.degree. C. for 3 to 7 hours, where the nitrogen reductant is injected into a reactor containing the cobalt oxide at a flow rate of 300 to 700 cc/min, preferably 500 cc/min per 1 g of cobalt oxide, while continuously elevating the temperature of the reactor at a rate of 3 to 7.degree. C./min, most preferably 5.degree. C./min.
摘要翻译：本发明涉及通过用氨或氮/氢气混合物还原钴氧化物制备钴金属的方法。根据本发明，通过在300-550℃的温度下将氧化钴与氮还原剂反应3至7小时来经济地制备钴金属，其中将氮还原剂注入含有钴的反应器氧化物，其流速为300〜700cc / min，优选为500cc / min / 1g氧化钴，同时以3〜7℃/ min，最优选为5℃的速度连续升高反应器的温度 C./min。

4. 发明授权

US5369133A Method for preparing an improved porous polymer bead 失效
标题翻译：制备改进的多孔聚合物珠粒的方法
公开(公告)号：US5369133A
公开(公告)日：1994-11-29
申请号：US998447
申请日：1992-12-29
申请人： Son-Ki Ihm , Young-Do Jo
发明人： Son-Ki Ihm , Young-Do Jo
IPC分类号： C08J9/20 , C08J9/28
CPC分类号： C08J9/20 , C08J2325/00
摘要： A method for preparing an improved porous polymer bead which comprises the following steps: introducing a mixture comprising a purified monomer, initiator and pore-forming agent into a 4-necked reactor with a suspension stabilizer and aqueous solution, suspending the mixture to provide homogeneous organic droplets at a temperature sufficiently low so as not to decompose the initiator, increasing the temperature gradually to a final reaction temperature and maintaining the temperature at the final temperature to react completely by suspension-polymerization the monomers in the individual organic droplet to provide the porous polymer bead, separating the bead, washing the bead with water, acetone and tetrahydrofuran, successively, and drying the bead, precipitating the bead in a solution mixed with monomer nd thinner to fill the pores of the porous bead with the diluted monomers, and introducing in a 4-necked reactor with a suspension stabilizer and aqueous solution, and by suspension-polymerization again, to coat the lightly cross-linked gel-type polymer on the surface of pores in the porous polymer bead, and again washing and drying the beads to provide an improved porous polymer bead.
摘要翻译：一种制备改进的多孔聚合物珠粒的方法，其包括以下步骤：将包含纯化单体，引发剂和成孔剂的混合物引入具有悬浮稳定剂和水溶液的四颈反应器中，将混合物悬浮以提供均匀的有机物液滴在足够低的温度下不会分解引发剂，将温度逐渐升至最终反应温度，并通过将单体悬浮聚合以保持最终温度在完全反应以提供多孔聚合物珠，分离珠，依次用水，丙酮和四氢呋喃洗涤珠粒，并干燥珠粒，将珠子沉淀在与单体和稀释剂混合的溶液中，以稀释的单体填充多孔珠粒的孔隙，并引入具有悬浮稳定剂和水溶液的四颈反应器和悬浮液再次裂解，在多孔聚合物珠粒的孔表面上涂覆轻度交联的凝胶型聚合物，再次洗涤和干燥珠粒以提供改进的多孔聚合物珠粒。

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