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1. 发明授权

US08835578B2 Catalyst components for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US08835578B2
公开(公告)日：2014-09-16
申请号：US13579027
申请日：2011-02-22
申请人： Simona Guidotti , Fabrizio Piemontesi , Joachim T. M. Pater , Giampiero Morini
发明人： Simona Guidotti , Fabrizio Piemontesi , Joachim T. M. Pater , Giampiero Morini
IPC分类号： C08F4/649 , C08F110/06
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/6465 , C08F4/651 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where RI and RII are the same or different and are hydrogen or linear or branched C1-C18 hydrocarbon groups which can also form one or more cyclic structures; RIII groups, equal or different from each other, are hydrogen or C1-C18 hydrocarbon groups; RIV groups equal or different from each other, have the same meaning of RIII except that they cannot be hydrogen; each of RI to RIV groups can contain heteroatoms selected from halogens, N, O, S and Si.
摘要翻译：用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两种电子给体化合物，其中一种选自烷氧基苯，另一种选自那些其中R 1和R II相同或不同，为氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。

2. 发明授权

US08829126B2 Catalyst components for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US08829126B2
公开(公告)日：2014-09-09
申请号：US13579029
申请日：2011-02-22
申请人： Simona Guidotti , Fabrizio Piemontesi , Joachim T. M. Pater , Giampiero Morini
发明人： Simona Guidotti , Fabrizio Piemontesi , Joachim T. M. Pater , Giampiero Morini
IPC分类号： C08F4/649 , C08F210/06
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/651 , C08F4/6465 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) and the other being selected from succinates of formula (II):
摘要翻译：包含Mg，Ti，卤素和两种电子给体化合物的烯烃聚合的催化剂组分，其中一种选自式（I），另一种选自式（II）的琥珀酸盐：

3. 发明授权

US09593171B2 Catalyst components for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US09593171B2
公开(公告)日：2017-03-14
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
IPC分类号： C08F4/16 , C08F10/06
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译：一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于0.60。

4. 发明授权

US09068029B2 Process for the preparation of impact resistant propylene polymer compositions 有权
标题翻译：制备耐冲击丙烯聚合物组合物的方法
公开(公告)号：US09068029B2
公开(公告)日：2015-06-30
申请号：US13509488
申请日：2010-11-15
申请人： Gianni Collina , Marco Ciarafoni , Ofelia Fusco , Benedetta Gaddi , Monica Galvan , Giampiero Morini , Roberto Pantaleoni , Joachim T. M. Pater , Fabrizio Piemontesi , Francesca Verrocchio
发明人： Gianni Collina , Marco Ciarafoni , Ofelia Fusco , Benedetta Gaddi , Monica Galvan , Giampiero Morini , Roberto Pantaleoni , Joachim T. M. Pater , Fabrizio Piemontesi , Francesca Verrocchio
IPC分类号： C08F10/06 , C08F210/06 , C08F110/06 , C08F210/16
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2/001 , C08F4/6494 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F2500/05
摘要： A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90° C.; (ii) polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer. An increased reactivity in the last step is observed.
摘要翻译：一种用于制备丙烯聚合物组合物的方法，其包含50至90重量％的在25℃下不溶于二甲苯的丙烯聚合物部分和10至50重量％在25℃下可溶于二甲苯的乙烯共聚物部分所述方法在特定催化剂体系的存在下进行，其特征还在于以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触一段时间 0.1至120分钟，温度范围为0至90℃; （ii）在乙烯和/或C 4 -C 10α-烯烃任选存在下聚合丙烯，产生丙烯（共）聚合物，其至少85重量％在25℃下不溶于二甲苯，和（iii）连续在（ii）产物存在下，在气相中进行步骤，将乙烯与α-烯烃CH 2 = CHR的混合物聚合，其中R是具有1-10个碳原子的烃基，得到乙烯共聚物。观察到在最后步骤中增加的反应性。

5. 发明申请

US20140046010A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：US20140046010A1
公开(公告)日：2014-02-13
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译：一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于0.60。

6. 发明申请

US20120316300A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：US20120316300A1
公开(公告)日：2012-12-13
申请号：US13579029
申请日：2011-02-22
申请人： Simona Guidotti , Fabrizio Piemontesi , Joachim T.M. Pater , Giampiero Morini
发明人： Simona Guidotti , Fabrizio Piemontesi , Joachim T.M. Pater , Giampiero Morini
IPC分类号： C08F4/649 , C08F210/06
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/651 , C08F4/6465 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) wherein: R2, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements or alkoxy groups of formula —OR1, two or more of the R2 groups can be connected together to form a cycle; R1, equal to or different from each other, are C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements, with the proviso that at least one of R2 is —OR1 and the other being selected from succinates of formula (II): wherein the radicals RI and RII, equal to or different from each other, are a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; the radicals RIII to RVI equal to or different from each other, are hydrogen or a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms, and the radicals RIII to RVI which are joined to the same carbon atom of the succinate chain can be linked together to form a cycle.
摘要翻译：用于烯烃CH 2 = CHR的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一个选自式（I）的那些，其中：R2 彼此相同或不同的是氢原子或任选含有属于式-OR1的元素或烷氧基的周期表第13-17族的杂原子的C1-C20烃基，R2基中的两个或更多个可以连接在一起形成一个循环; R1彼此相同或不同的是C1-C20烃基，其任选地含有属于元素周期表第13-17族的杂原子，条件是R 2中的至少一个为-OR 1且另一个选自来自式（II）的琥珀酸盐：其中基团R 1和R II彼此相同或不同，是任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基; RIII至RVI彼此相同或不同的基团是氢或任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳烷基或烷基芳基，以及RIII至RVI基团连接至琥珀酸酯链的相同碳原子可以连接在一起形成循环。

7. 发明申请

US20120302709A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：US20120302709A1
公开(公告)日：2012-11-29
申请号：US13579027
申请日：2011-02-22
申请人： Simona Guidotti , Fabrizio Piemontesi , Joachim T.M. Pater , Giampiero Morini
发明人： Simona Guidotti , Fabrizio Piemontesi , Joachim T.M. Pater , Giampiero Morini
IPC分类号： C08F4/649
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/6465 , C08F4/651 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where RI and RII are the same or different and are hydrogen or linear or branched C1-C18 hydrocarbon groups which can also form one or more cyclic structures; RIII groups, equal or different from each other, are hydrogen or C1-C18 hydrocarbon groups; RIV groups equal or different from each other, have the same meaning of RIII except that they cannot be hydrogen; each of RI to RIV groups can contain heteroatoms selected from halogens, N, O, S and Si.
摘要翻译：用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两种电子给体化合物，其中一种选自烷氧基苯，另一种选自那些其中R 1和R II相同或不同，为氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。

8. 发明授权

US07943717B2 Butene-1 copolymers and process for their preparation 有权
标题翻译：丁烯-1共聚物及其制备方法
公开(公告)号：US07943717B2
公开(公告)日：2011-05-17
申请号：US10532686
申请日：2003-11-03
申请人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
发明人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
IPC分类号： C08F10/04 , C08F10/14 , C08F110/04 , C08F110/14 , C08F4/44 , C08L23/00 , C08L23/04
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2≦2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译：本发明涉及含有至多40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比r1·r2＆nlE; 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。

9. 发明授权

US07482413B2 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 有权
标题翻译：二氯化镁 - 醇加合物和由其获得的催化剂组分
公开(公告)号：US07482413B2
公开(公告)日：2009-01-27
申请号：US10550986
申请日：2004-03-09
申请人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
发明人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F4/65
摘要： The present invention relates to MgCl2.(EtOH),m(ROH)n(H2O)p adduct in which R is a C1-C15 hydrocarbon group different from ethyl, n and m are indexes, higher than 0, satisfying the equations (n+m)≧0.7 and 0.05≦n/(n+m)≦0.95 and p is a number ranging from 0 to 0.7 with the proviso that when R is methyl and (n+m) is in the range of 0.7 to 1, the value of n/(n+m) ranges from 0.05 to 0.45. The catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译：本发明涉及MgCl 2（EtOH），m（ROH）n（H 2 O）p加合物，其中R是不同于乙基的C 1 -C 15烃基，n和m是指数，高于0，满足等式（n + m）> = 0.7和0.05 <= n /（n + m）<= 0.95，p为0至0.7的数，条件是当R为甲基且（n + m）为0.7 为1，n /（n + m）的值为0.05〜0.45。从本发明的加合物得到的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。

10. 发明申请

US20080004409A1 Butene-1 (Co)Polymers Having Low Isotacticity 有权
标题翻译：具有低全同立构规整度的丁烯-1（Co）聚合物
公开(公告)号：US20080004409A1
公开(公告)日：2008-01-03
申请号：US11665630
申请日：2005-10-12
申请人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
发明人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
IPC分类号： C08L23/18 , C08F10/08 , C08F4/42
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/15 , C08F210/14 , C08F210/16 , C08F210/06
摘要： Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [η] measured in tetraline at 135° C. from 1 to 3 dL/g; content of xylene insoluble fraction at 0° C. from 3 to 60%; and a ratio ES2/ES1>1, where ES1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.
摘要翻译：丁烯-1（共）聚合物，其特征在于以下性质：全同立构五单元形式的丁烯-1单元的含量（mmmm）为25至55％; 在135℃的四氢化萘中测量的特性粘度η为1至3dL / g; 0℃下二甲苯不溶级分含量为3〜60％; 和ES ES 2 / ES 1比1，其中ES 1是在聚合物上测定的沸腾二乙醚可溶级分，ES为ES 沸点二乙醚可溶级分是在研磨聚合物之后测定的。丁烯-1（共）聚合物在加工性和弹性体性能之间显示出良好的平衡。

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