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    • 1. 发明申请
    • Use of Pyridindione Derivatives for Protecting Organic Material Against Detrimental Effects of Light
    • 使用吡啶并二酮衍生物保护有机材料免受光的有害影响
    • US20070208112A1
    • 2007-09-06
    • US10592666
    • 2005-04-14
    • Simon SchambonyAlban GlaserRudiger Sens
    • Simon SchambonyAlban GlaserRudiger Sens
    • C08K5/34C07D211/78C07D211/72
    • C07D213/85C09K15/30
    • The present invention relates to the use of pyridinedione derivatives of general formula I and if appropriate their tautomers in which R1 is hydrogen, optionally substituted and/or if appropriate heteroatom-comprising alkyl, alkenyl or alkynyl or optionally substituted cycloalkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl, R2 independently of R1 has the definition of R1 or NR4R5, R4, R5 independently of one another and of R1 have the definition of R1 or COR6, A is CN, COR7, COOR7 or CONR7R8, R6, R7, R8 independently of one another and of R1 have the definition of R1, n denotes values of 1, 2, 3 or 4, R3 if n is 1: is hydrogen, optionally substituted and/or if appropriate heteroatom-comprising alkyl, alkenyl or alkynyl or optionally substituted cycloalkyl, cycloalkenyl or heterocycloalkyl, if n is not 1: is an n-valent aliphatic or cycloaliphatic radical which may if appropriate comprise heteroatoms, to protect organic material from the damaging effects of light, to compositions which comprise at least one such pyridinedione derivative of formula I in an amount conferring protection from the damaging effects of light, and at least one organic material, and to pyridinedione derivatives of formula I.
    • 本发明涉及通式I的吡啶二酮衍生物及其合适的互变异构体,其中R 1是氢,任选地被取代和/或如果合适的含杂原子的烷基,烯基或炔基或任选地 取代的环烷基,环烯基,杂环烷基,芳基或杂芳基,独立于R 1的R 2具有R 1或R 4的定义 R 5,R 4,R 5,R 5彼此独立地相互独立地相互独立地具有R 1,R 2, R 1或C 6的定义,A是CN,COR 7,COOR 7或CONR 0, R 8,R 6,R 7,R 8,R 8,R 8,R 8, R 1具有R 1的定义,n表示1,2,3或4的值,如果n是1,则为3以上的R 3为 氢,任选取代的和/或如果合适的含杂原子的烷基,烯基或炔基或任选取代的环 烷基,环烯基或杂环烷基,如果n不为1,则为n价的脂族或脂环族基团,如果合适的话,它可以包含杂原子,以保护有机材料免受光的破坏作用,包括至少一种这样的吡啶二酮衍生物 式I给出了防止光的有害影响的量,以及至少一种有机材料,以及式I的吡啶二酮衍生物。
    • 4. 发明授权
    • Stabilisers for inanimate organic materials
    • 无机有机材料稳定剂
    • US08377192B2
    • 2013-02-19
    • US13060705
    • 2009-08-14
    • Alban GlaserSylke HaremzaSimon Schambony
    • Alban GlaserSylke HaremzaSimon Schambony
    • C09D7/12C08K5/3435C07D401/12C07D211/56
    • C07D211/94
    • The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
    • 本发明涉及包含一个或多个通式(I)的基团的空间位阻胺的用途,用于稳定无生命的有机材料,更特别的是塑料或涂料,其中R 1和R 2各自独立地或不同地是H, C 1 -C 20烷基,C 3 -C 15环烷基,芳基,杂芳基或杂环,R 4,R 5,R 6和R 7各自独立地为不同或不同的是C 1 -C 20烷基,或R 4和R 6或R 5和R 7一起是四亚甲基 或五亚甲基,R 3为芳基或杂芳基。 本发明还涉及稳定无生命的有机材料,特别是塑料或涂料的方法。 本发明另外提供的是包含一个或多个通式(I)的基团的空间位阻胺。 本发明另外提供的是包含选定的空间位阻胺的材料。
    • 7. 发明申请
    • STABILISERS FOR INANIMATE ORGANIC MATERIALS
    • 用于有机材料的稳定剂
    • US20110214590A1
    • 2011-09-08
    • US13060705
    • 2009-08-14
    • Alban GlaserSylke HaremzaSimon Schambony
    • Alban GlaserSylke HaremzaSimon Schambony
    • C09D7/12C08K5/3435C07D401/12C07D401/04C07D211/56
    • C07D211/94
    • The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
    • 本发明涉及包含一个或多个通式(I)的基团的空间位阻胺的用途,用于稳定无生命的有机材料,更特别的是塑料或涂料,其中R 1和R 2各自独立地或不同地是H, C 1 -C 20烷基,C 3 -C 15环烷基,芳基,杂芳基或杂环,R 4,R 5,R 6和R 7各自独立地为不同或不同的是C 1 -C 20烷基,或R 4和R 6或R 5和R 7一起是四亚甲基 或五亚甲基,R 3为芳基或杂芳基。 本发明还涉及稳定无生命的有机材料,特别是塑料或涂料的方法。 本发明另外提供的是包含一个或多个通式(I)的基团的空间位阻胺。 本发明另外提供的是包含选定的空间位阻胺的材料。
    • 9. 发明申请
    • STABILIZER MIXTURE
    • 稳定剂混合物
    • US20100160502A1
    • 2010-06-24
    • US12160724
    • 2007-01-12
    • Simon SchambonyAlban GlaserHubert TrauthManfred AppelSylke Haremza
    • Simon SchambonyAlban GlaserHubert TrauthManfred AppelSylke Haremza
    • C08K5/3435
    • C08K5/3435C07B63/04C07D211/58C08K5/34C08K2201/014C08L23/12C08L2201/08C09D7/48C09K15/20C09K15/30
    • Suitable stabilizers for organic material are a mixture comprising A. at least one oligomeric compound, comprising repeat units of the formula (I), in which the meanings of the symbols are as follows: R1 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5-C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula —CR′═CH—CO—OR″, where R′ is hydrogen, C1-C6-alkyl or a radical of the formula —CO—OR″, and R″ is C1-C18-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl, or tolyl; R2 is a mixture composed of C14-C28-alkyl groups, where two of these alkyl groups whose number of carbon atoms is not permitted to differ by more than two respectively make up at least 30% of this mixture; R3 and R4, independently of one another, are C1-C6-alkyl; and B. at least one compound of the formula (II) or (III) where the meanings of the symbols and indices are as follows: n and m, independently of one another, are a natural number from 2 to 22, and R1, R3 and R4, independently of one another, have the meanings given in formula (I).
    • 用于有机材料的合适的稳定剂是包含A.至少一种低聚化合物的混合物,其包含式(I)的重复单元,其中符号的含义如下:R 1是氢,C 1 -C 6 - 烷基,甲酰基, C 2 -C 6 - 烷酰基,C 1 -C 12 - 烷氧基,C 5 -C 6 - 环烷氧基,氰基甲基,2-羟基乙基,苄基或式-CR'≡CH-CO-OR的基团,其中R'是氢,C1- C6烷基或式-CO-OR基团,R“为C1-C18-烷基,C5-C8-环烷基,C7-C18-芳烷基,苯基或甲苯基; R2是由C14-C28-烷基组成的混合物,其中不允许两个以上碳原子数不同的这些烷基中的两个分别构成该混合物的至少30% R 3和R 4彼此独立地为C 1 -C 6 - 烷基; 和B.至少一种式(II)或(III)的化合物,其中符号和指数的含义如下:n和m彼此独立地是2至22的自然数,并且R 1, R 3和R 4彼此独立地具有式(I)中给出的含义。