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1. 发明申请

US20070044831A1 Electrolyte composition and dye-sensitized solar cell 审中-公开
标题翻译：电解质组合物和染料敏化太阳能电池
公开(公告)号：US20070044831A1
公开(公告)日：2007-03-01
申请号：US11372350
申请日：2006-03-10
申请人： Shuzi Hayase , Shinichi Kadono
发明人： Shuzi Hayase , Shinichi Kadono
IPC分类号： H01L31/00 , H01M10/40
CPC分类号： H01G9/2004 , H01G9/2031 , Y02E10/542
摘要： The present invention provides an electrolyte composition that can simultaneously realize solidification of the electrolyte layer and alleviation of a reduction in photoelectric conversion rate caused by the solidification of electrolyte layers, and a dye-sensitized solar cell having a solid electrolyte layer comprising the electrolyte composition. The electrolyte composition includes nanoparticles with an ammonium group or a nitrogen-containing heterocyclic group bound thereto; or a porous inorganic film with an ammonium group or a nitrogen-containing heterocyclic group bound thereto. The nanoparticles and the porous inorganic film each are formed of a metal oxide. The nitrogen-containing heterocyclic group is an imidazolium group, a pyridinium group, a triazolium group or a guanidinium group, and the counter anion group is F−, Cl−, Br−, I− or the like. The ammonium group or the nitrogen-containing heterocyclic group chemically modifies the nanoparticles or the porous inorganic film. The electrolyte layer of the dye-sensitized solar cell includes the electrolyte composition.
摘要翻译：本发明提供一种能够同时实现电解质层的固化并且减轻由电解质层固化引起的光电转换率降低的电解质组合物，以及具有包含电解质组合物的固体电解质层的染料敏化太阳能电池。电解质组合物包括与铵基或含氮杂环基结合的纳米颗粒; 或与其结合的铵基或含氮杂环基的多孔无机膜。纳米颗粒和多孔无机膜各自由金属氧化物形成。含氮杂环基是咪唑鎓基，吡啶鎓基，三唑鎓基或胍基，抗衡阴离子基是F - ， - CH ^{- ，I ^{- 等。铵基或含氮杂环基化学改性纳米粒子或多孔无机膜。染料敏化太阳能电池的电解质层包括电解质组合物。}}

2. 发明授权

US08969123B2 Apparatus for manufacturing dye-sensitized solar cell, and method of manufacturing dye-sensitized solar cell 有权
标题翻译：染料敏化太阳能电池的制造装置及染料敏化太阳能电池的制造方法
公开(公告)号：US08969123B2
公开(公告)日：2015-03-03
申请号：US13580782
申请日：2011-02-24
申请人： Hiroaki Hayashi , Ryuichi Shiratsuchi , Suehiro Ohkubo , Shuzi Hayase , Taiichi Mure , Yasuhiro Shishida
发明人： Hiroaki Hayashi , Ryuichi Shiratsuchi , Suehiro Ohkubo , Shuzi Hayase , Taiichi Mure , Yasuhiro Shishida
IPC分类号： H01L31/18 , H01L51/48 , H01G9/20
CPC分类号： H01G9/2068 , H01G9/2031 , H01G9/2059 , Y02E10/542 , Y02P70/521
摘要： In an apparatus for manufacturing a dye-sensitized solar cell, a photosensitization dye solution makes contact with an electrode material layer that functions as a working electrode of a dye-sensitized solar cell so that the photosensitizing dye is adsorbed on the layer. Such an apparatus for manufacturing a dye-sensitized solar cell has a substrate housing section to house a substrate with the electrode material layer formed on its surface, and a circulation mechanism to circulate the photosensitization dye solution in such a way that the solution passes a surface of the substrate housed in the substrate housing section. In such an apparatus, a cross-sectional area of a flow path for the photosensitization dye solution in a portion facing the substrate in the substrate housing section is set smaller than a cross-sectional area of a flow path for the photosensitization dye solution in other portions.
摘要翻译：在染料敏化太阳能电池的制造装置中，光敏染料溶液与作为染料敏化太阳能电池的工作电极的电极材料层接触，使得光敏染料被吸附在该层上。用于制造染料敏化太阳能电池的这种装置具有：基板容纳部，用于容纳其表面上形成有电极材料层的基板;以及循环机构，使光敏染料溶液循环使得溶液通过表面的衬底容纳在衬底容纳部分中。在这样的装置中，在基板容纳部中面向基板的部分中的光敏染料溶液的流路的截面积被设定为小于其他光敏染料溶液的流路的截面面积部分。

3. 发明授权

US08637680B2 Dye-sensitized solar cell, photoelectric conversion element, and dye for use in the solar cell and the element 失效
标题翻译：染料敏化太阳能电池，光电转换元件和用于太阳能电池和元件的染料
公开(公告)号：US08637680B2
公开(公告)日：2014-01-28
申请号：US13255095
申请日：2010-03-10
申请人： Shuzi Hayase , Yoshihiro Yamaguchi , Shyam Sudhir Pandey
发明人： Shuzi Hayase , Yoshihiro Yamaguchi , Shyam Sudhir Pandey
IPC分类号： C07D209/02 , C07D209/04 , H01L31/042
CPC分类号： H01G9/2059 , C09B23/0066 , C09B57/007 , H01G9/2031 , H01L51/0064 , Y02E10/542 , Y02E10/549
摘要： Provided are a squarylium dye having a carboxyindolenine structure and an N-alkyl substituent, and a photoelectric conversion element having high photoelectric conversion efficiency in a near-infrared region and a dye-sensitized solar cell, both of which are produced using the squarylium dye. The photoelectric conversion element or dye-sensitized solar cell uses a compound represented by the formula (1) as the squarylium dye. In the formula (1), R1 and R2 represent a substituted or unsubstituted C5 to C30 alkyl group; X represents C(CH3)2; and A and B represent a carboxy group.
摘要翻译：本发明提供了具有羧基吲哚宁结构和N-烷基取代基的方酸菁染料，以及在近红外区域和染料敏化太阳能电池中具有高光电转换效率的光电转换元件，它们均使用方酸菁染料制备。光电转换元件或染料敏化太阳能电池使用由式（1）表示的化合物作为方酸菁染料。在式（1）中，R 1和R 2表示取代或未取代的C 5至C 30烷基; X表示C（CH 3）2; A和B表示羧基。

4. 发明申请

US20120017974A1 METHOD AND DEVICE FOR DYE ADSORPTION FOR PHOTOSENSITIZING DYE, METHOD AND APPARATUS FOR PRODUCING DYE-SENSITIZED SOLAR CELL, AND DYE-SENSITIZED SOLAR CELL 审中-公开
标题翻译：用于光敏染料的染料吸附的方法和装置，用于生产染料敏化太阳能电池的方法和装置以及透明的太阳能电池
公开(公告)号：US20120017974A1
公开(公告)日：2012-01-26
申请号：US13203456
申请日：2010-02-24
申请人： Hiroaki Hayashi , Ryuichi Shiratsuchi , Suehiro Ohkubo , Masato Takasaki , Shuzi Hayase
发明人： Hiroaki Hayashi , Ryuichi Shiratsuchi , Suehiro Ohkubo , Masato Takasaki , Shuzi Hayase
IPC分类号： H01L31/0216 , B05C5/00 , H01L31/18
CPC分类号： H01G9/2059 , H01G9/2031 , H01G9/2068 , Y02E10/542 , Y02P70/521
摘要： A method for adsorption of a photosensitizing dye includes adsorbing the photosensitizing dye to the layer of an electrode material that functions as the working electrode of a dye-sensitized solar cell, within a reaction vessel containing a solution of the photosensitizing dye, wherein a flow of the photosensitizing dye solution is generated by means of a flow generation part in a direction perpendicular to the electrode material layer, a direction parallel thereto or both, and the flow rate of the photosensitizing dye solution to the electrode material layer is higher than the diffusion velocity of the photosensitizing dye.
摘要翻译：吸附光敏染料的方法包括在含有感光染料溶液的反应容器内将感光染料吸附到作为染料敏化太阳能电池的工作电极的电极材料层上，其中流过光敏染料溶液是通过在垂直于电极材料层的方向上的流动产生部分，与其平行的方向或两者产生的，并且光敏染料溶液对电极材料层的流速高于扩散速度的光敏染料。

5. 发明申请

US20100151616A1 DYE-SENSITIZED SOLAR CELL 审中-公开
标题翻译：透明的太阳能电池
公开(公告)号：US20100151616A1
公开(公告)日：2010-06-17
申请号：US12711694
申请日：2010-02-24
申请人： Ryuichi SHIRATSUCHI , Shuzi Hayase
发明人： Ryuichi SHIRATSUCHI , Shuzi Hayase
IPC分类号： H01L31/18 , H01L31/0224 , H01L31/04
CPC分类号： H01L31/022466 , H01G9/2031 , H01L31/1884 , Y02E10/542 , Y02P70/521
摘要： A dye-sensitized solar cell is provided that includes a transparent electrode formed by depositing, in order on a transparent substrate, a transparent conductive film containing tin oxide as a main component, and a compact titanium oxide layer and/or a porous titanium oxide layer, wherein the transparent conductive film, which contains tin oxide as the main component, has a fluorine concentration not exceeding 0.2 wt %, and the transparent conductive film on the transparent substrate has in an X-ray diffraction pattern thereof diffraction peaks attributable to (110), (200), and (211) planes satisfying the conditions that, relative to the sum of the diffraction intensities of the three planes, the ratios of both the (110) and (211) diffraction intensities are larger than 0.25 and smaller than 0.4, and the ratio of the (200) diffraction intensity is larger than 0.25 and smaller than 0.5. The dye-sensitized solar cell has high light conversion efficiency and has an FTO film that are highly heat resistant and does not easily deteriorate during a thermal treatment step when forming a titanium oxide porous film.
摘要翻译：提供一种染料敏化太阳能电池，其包括通过在透明基板上依次沉积含有氧化锡作为主要成分的透明导电膜和紧密的氧化钛层和/或多孔氧化钛层而形成的透明电极其中，含有氧化锡作为主要成分的透明导电膜的氟浓度不超过0.2重量％，透明基板上的透明导电膜的X射线衍射图可归因于（110 ），（200）和（211）面满足相对于三个平面的衍射强度之和的条件，（110）和（211）的衍射强度之比大于0.25且小于（200）衍射强度的比例大于0.25且小于0.5。染料敏化太阳能电池具有高的光转换效率，并且具有高耐热性并且在形成氧化钛多孔膜时在热处理步骤期间不容易劣化的FTO膜。

6. 发明授权

US5811497A Aromatic curing catalyst for epoxy resins 失效
标题翻译：用于环氧树脂的芳香族固化催化剂
公开(公告)号：US5811497A
公开(公告)日：1998-09-22
申请号：US526327
申请日：1995-09-11
申请人： Shuzi Hayase , Yoshihiko Nakano , Shinji Murai , Yukihiro Mikogami
发明人： Shuzi Hayase , Yoshihiko Nakano , Shinji Murai , Yukihiro Mikogami
IPC分类号： C08G59/68 , C08G59/06 , C08G59/24
CPC分类号： C08G59/68 , C08G59/681
摘要： Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.
摘要翻译：本文公开了包含至少一种化合物的固化催化剂，所述化合物是取代或未取代的芳族或杂芳族化合物，并且具有（I）-O-R 1，（II）-O-CY-R 1或（III） - O-CY-X-R1，其直接键合到铠装或杂芳族环上，其数量为1至10，其中R 1可以相同或不同，并且是具有1至20个碳原子的取代或未取代的烃基， X是O或NH，Y是O或S.此外，公开了包含固化催化剂的环氧树脂组合物。

7. 发明授权

US5705540A Inorganic filler, manufacturing method thereof, and resin composition containing an inorganic filler 失效
标题翻译：无机填料及其制造方法，含有无机填料的树脂组合物
公开(公告)号：US5705540A
公开(公告)日：1998-01-06
申请号：US781852
申请日：1997-01-10
申请人： Ken Uchida , Yasuyuki Hotta , Shuzi Hayase
发明人： Ken Uchida , Yasuyuki Hotta , Shuzi Hayase
IPC分类号： B29B15/10 , C08K9/06 , C09C1/30 , C09C3/12 , C08K9/10
CPC分类号： C08K9/06 , C08L63/00 , C09C1/3081 , C09C3/12 , B29K2105/16 , C01P2004/61
摘要： Disclosed is a resin composition excellent in mechanical and electrical properties. The composition contains an inorganic filler such as fused silica or silicon nitride having the surface covered with a substance resulting from decomposition of a polysilane compound and a base resin such as an epoxy resin or a maleimide resin.
摘要翻译：公开了机械和电学性能优异的树脂组合物。该组合物含有表面被聚硅烷化合物分解的物质和环氧树脂或马来酰亚胺树脂等基础树脂所覆盖的物质的熔融二氧化硅或氮化硅等无机填料。

8. 发明授权

US5063134A Photosensitive composition 失效
标题翻译：感光组合物
公开(公告)号：US5063134A
公开(公告)日：1991-11-05
申请号：US455783
申请日：1990-01-02
申请人： Rumiko Horiguchi , Shuzi Hayase , Yasunobu Onishi
发明人： Rumiko Horiguchi , Shuzi Hayase , Yasunobu Onishi
IPC分类号： C08G8/06 , C08G8/28 , C09D161/04 , G03F7/075
CPC分类号： G03F7/0758 , C08G8/06 , C08G8/28 , C09D161/04
摘要： A photosensitive composition contains a polymer having a unit represented by formula I, and a photosensitive agent: ##STR1## wherein each of R.sub.1 to R.sub.4 represents a hydrogen atom, an alkyl group, an alkoxyl group, or a substituted or non-substituted allyl group, at least one of R.sub.1 to R.sub.4 being an alkyl groups having 1 to 10 carbon atoms and containing silicon, l represents a positive integer, and each of a and b represents an integer from 1 to 3, and c represents an integer from 0 to 2, a+b+c not exceeding 4.
摘要翻译：感光性组合物含有具有式I表示的单元的聚合物和光敏剂：其中R 1〜R 4各自表示氢原子，烷基，烷氧基或取代或未取代的光敏剂，取代的烯丙基，R 1至R 4中的至少一个为具有1至10个碳原子且含有硅的烷基，l表示正整数，a和b各自表示1至3的整数，c表示整数从0到2，a + b + c不超过4。

9. 发明授权

US08754323B2 Dye-sensitized solar cell and process for producing the same 失效
标题翻译：染料敏化太阳能电池及其制造方法
公开(公告)号：US08754323B2
公开(公告)日：2014-06-17
申请号：US12304038
申请日：2007-06-21
申请人： Shuzi Hayase , Ryuichi Shiratsuchi , Suehiro Ohkubo , Yoshihiro Yamaguchi
发明人： Shuzi Hayase , Ryuichi Shiratsuchi , Suehiro Ohkubo , Yoshihiro Yamaguchi
IPC分类号： H01G9/20
CPC分类号： H01G9/2022 , H01G9/2031 , H01G9/2059 , Y02E10/542 , Y02P70/521
摘要： A dye-sensitized solar cell is provided, wherein it can be produced by a relatively easy and simple process and ensures high conversion efficiency even in cases where the thickness of the porous semiconductor layer is increased. The dye-sensitized solar cell 10 includes, in the interior of or on the conductive-substrate-side surface of the porous semiconductor layer 16, conductive metal film 20, such as a film of tungsten, having a large number of randomly located penetrations 24. Penetrations 24 of the conductive metal film 20 are formed by forming a fine-particle layer on the surface of the porous semiconductor layer, forming a conductive metal film on the surface of the fine-particle layer, and making the fine-particle layer disappear by heating or solvent-cleaning.
摘要翻译：提供了一种染料敏化太阳能电池，其中其可以通过相对简单和简单的方法制造，并且即使在多孔半导体层的厚度增加的情况下也确保高转换效率。染料敏化太阳能电池10在多孔半导体层16的内部或导电性基板侧表面上包括具有大量随机定位的穿透件24的导电金属膜20（例如钨膜）通过在多孔半导体层的表面形成微粒层，在微粒层的表面形成导电性金属膜，使微粒层消失，形成导电性金属膜20的穿透部24 通过加热或溶剂清洗。

10. 发明申请

US20120029206A1 DYE-SENSITIZED SOLAR CELL, PHOTOELECTRIC CONVERSION ELEMENT, AND DYE FOR USE IN THE SOLAR CELL AND THE ELEMENT 失效
标题翻译：透明太阳能电池，光电转换元件和用于太阳能电池和元件的眼镜
公开(公告)号：US20120029206A1
公开(公告)日：2012-02-02
申请号：US13255095
申请日：2010-03-10
申请人： Shuzi Hayase , Yoshihiro Yamaguchi , Shyam Sudhir Pandey
发明人： Shuzi Hayase , Yoshihiro Yamaguchi , Shyam Sudhir Pandey
IPC分类号： C07D407/08 , C07D209/12
CPC分类号： H01G9/2059 , C09B23/0066 , C09B57/007 , H01G9/2031 , H01L51/0064 , Y02E10/542 , Y02E10/549
摘要： Provided are a squarylium dye having a carboxyindolenine structure and an N-alkyl substituent, and a photoelectric conversion element having high photoelectric conversion efficiency in a near-infrared region and a dye-sensitized solar cell, both of which are produced using the squarylium dye. The photoelectric conversion element or dye-sensitized solar cell uses a compound represented by the formula (1) as the squarylium dye. In the formula (1), R1 and R2 represent a substituted or unsubstituted C5 to C30 alkyl group; X represents C(CH3)2; and A and B represent a carboxy group.
摘要翻译：本发明提供了具有羧基吲哚宁结构和N-烷基取代基的方酸菁染料，以及在近红外区域和染料敏化太阳能电池中具有高光电转换效率的光电转换元件，它们均使用方酸菁染料制备。光电转换元件或染料敏化太阳能电池使用由式（1）表示的化合物作为方酸菁染料。在式（1）中，R 1和R 2表示取代或未取代的C 5至C 30烷基; X表示C（CH 3）2; A和B表示羧基。

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