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    • 1. 发明授权
    • Photographic element with pyrazole electron donors
    • 具有吡唑电子给体的摄影元件
    • US4407941A
    • 1983-10-04
    • US355464
    • 1982-03-08
    • Shunji SuginakaRyuichiro KobayashiSatoru IkeuchiNoboru MizukuraNoriko Fujita
    • Shunji SuginakaRyuichiro KobayashiSatoru IkeuchiNoboru MizukuraNoriko Fujita
    • C07D231/52C07D491/056G03C1/06G03C5/30G03C8/02G03C8/08G03C8/36G03C1/40G03C5/54
    • C07D231/52G03C5/30G03C8/02G03C8/08G03C8/36Y10S430/16
    • A photographic element comprising a support provided thereon with at least one light-sensitive silver halide emulsion layer containing a nondiffusible compound which receives at least one electron in an alkaline condition to release a photographically useful material and a nondiffusible electron donor or a precursor thereof having the following formula (I) or (II): ##STR1## wherein R.sup.1 represents hydrogen, an alkyl, an aryl or a heterocyclic group, R.sup.2 represents hydrogen, an alkyl, an aryl, a heterocyclic, an amino, a carbamide, a sulfonamide, a sulfamoyl, a carbamoyl or a ureido group, R.sup.3 and R.sup.4 each is hydrogen, --COR.sup.5, --SO.sub.2 R.sup.6 or --CSR.sup.7 wherein R.sup.5 and R.sup.6 each is a substituted or unsubstituted, respectively, alkyl, alkenyl, aryl, heterocyclic, alkylamino, alkyloxy, aryloxy, alkylthio, arylthio, alkyloxycarbonyl or aryloxycarbonyl group, and R.sup.7 is a substituted or unsubstituted alkyllamino or arylamino group, said R.sup.4 being allowed to form a ring together with said R.sup.1.
    • 一种照相元件,包括其上提供有至少一种感光卤化银乳剂层的载体,所述至少一种感光卤化银乳剂层含有不可扩散的化合物,其在碱性条件下接收至少一种电子以释放具有照相作用的材料,以及不可溶的电子给体或其前体, 下式(I)或(II):其中R 1表示氢,烷基,芳基或杂环基,R 2表示氢,烷基,芳基,杂环,氨基,脲,磺酰胺, 氨基甲酰基或脲基,R 3和R 4各自为氢,-COR 5,-SO 2 R 6或-CSR 7,其中R 5和R 6各自为取代或未取代的烷基,烯基,芳基,杂环,烷基氨基,烷氧基, 芳氧基,烷硫基,芳硫基,烷氧基羰基或芳氧基羰基,R7是取代或未取代的烷基氨基或芳基氨基,所述R4与所述R 1一起形成环。
    • 7. 发明授权
    • Dye image forming process
    • 染料成像工艺
    • US4209328A
    • 1980-06-24
    • US808867
    • 1977-06-22
    • Yuzuru SatoRyuichiro KobayashiNaoshi KuniedaKazumasa WatanabeNoboru MizukuraKenji YoshidaTadanori Oya
    • Yuzuru SatoRyuichiro KobayashiNaoshi KuniedaKazumasa WatanabeNoboru MizukuraKenji YoshidaTadanori Oya
    • D06P5/00C09B29/06G03C8/10G03C8/18G03C5/54G03C1/10G03C1/40G03C9/00
    • C09B29/06G03C8/18
    • In a dye image forming process in color photography comprising imagewise exposing a photographic element comprising a support and a light sensitive silver halide emulsion layer, and processing the exposed photographic element with an alkaline processing solution in the presence of a dye developer whereby a dye image corresponding to the imagewise exposure is formed by oxidation of said developer as a function of development of silver halide, the improvement which comprises the dye developer being a mono azo dye developer represented by the following formula:X--N.dbd.N--Y--NH--Zwherein X represents a monovalent group selected from an aromatic group, a non-aromatic-heterocyclic active-methylene-containing group, a non-aromatic-heterocyclic active-methyne-containing group, an aliphatic active-methylene-containing group, and an aliphatic active-methyne-containing group; and Y and Z respectively represent divalent and monovalent groups of an aromatic group, at least one of the X, Y and Z has therein at least one of the developer groups which are either capable of developing silver halide or changeable to a group capable of developing silver halide, the azo radical (--N=N--) and the secondary amino radical (--NH--) are respectively attached to the adjacent carbon atoms in Y, the azo radical being attached to an aromatic ring of the aromatic group of X or to the active methylene or methyne of X and is attached to an aromatic ring of the aromatic group of Y, and the amino radical is attached to aromatic rings of Y and Z.
    • 在彩色摄影中的染料成像过程中,包括将包含载体和感光卤化银乳剂层的照相元件成像曝光,并在染料显影剂存在下用碱性处理溶液处理曝光的照相元件,由此染料图像对应 通过作为卤化银显影的函数的所述显影剂的氧化形成图像曝光,其改进包括染料显影剂是由下式表示的单偶氮染料显影剂:XN = NY-NH-Z其中X表示 选自芳族基团,非芳香族 - 杂环类活性亚甲基基团,非芳香族 - 含杂环式含活性甲基的基团,含脂肪族活性亚甲基基团和脂肪族活性甲基 - 含有组; Y和Z分别表示芳族基团的二价和一价基团,X,Y和Z中的至少一个在其中具有能够显影卤化银或能够显影的基团中的至少一种显影剂组 卤化银,偶氮基(-N = N-)和仲氨基(-NH-)分别连接到Y中的相邻碳原子上,偶氮基连接到X的芳族基团的芳环上或 与X的活性亚甲基或次炔连接并连接到Y的芳族基团的芳环上,并且氨基连接到Y和Z的芳环上。
    • 9. 发明授权
    • Photographic element with lactone polymer
    • 摄影元素与内酯聚合物
    • US4407938A
    • 1983-10-04
    • US369362
    • 1982-04-19
    • Noboru MizukuraMikio Koyama
    • Noboru MizukuraMikio Koyama
    • G03C7/26C08F8/00C08F8/16C08F16/18C08F20/00C08F20/02C08F20/10C08F22/06C08F22/10C08L33/04G03C8/52G03C8/54G03C1/40G03C1/48G03C1/78
    • G03C8/52
    • A photographic element comprising a support having thereof at least one silver halide emulsion layer and at least one temporary barrier layer, said temporary barrier layer comprising a mixture of a lactone polymer with repetitive units represented by the formula (I): ##STR1## and a vinylidene chloride terpolymer represented by the formula (II): ##STR2## wherein R is a hydrogen atom, an alkyl or an aralkyl group; R.sup.1, R.sup.2 and R.sup.3 each is a hydrogen atom or a methyl group; n.sup.1 is an integer of from 1 to 5, while n.sup.2 is an integer of 1 or 2; A is a monomer unit of a copolymerizable ethylenically unsaturated acid or of the salt thereof, while B is a copolymerizable ethylenically unsaturated monomer unit; x represents from 50 to 99.5% by weight, y represents from 0.5 to 44.5% by weight, and z represents from 0 to 49.5% by weight.
    • 一种照相元件,包括其中具有至少一个卤化银乳剂层和至少一个暂时阻挡层的载体,所述临时阻隔层包含内酯聚合物与由式(I)表示的重复单元的混合物: I)和由式(II)表示的偏二氯乙烯三元共聚物:其中R是氢原子,烷基或芳烷基的式(II) R1,R2和R3各自为氢原子或甲基; n1为1〜5的整数,n2为1或2的整数, A是可共聚的烯属不饱和酸或其盐的单体单元,而B是可共聚的烯属不饱和单体单元; x表示50〜99.5重量%,y表示0.5〜44.5重量%,z表示0〜49.5重量%。