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    • 1. 发明授权
    • Purification of hydrogen peroxide solution
    • 纯化过氧化氢溶液
    • US5200166A
    • 1993-04-06
    • US815182
    • 1991-12-31
    • Shujiro ShigaYasuyoshi SawaguriKoji KabasawaTatsuya Momobayashi
    • Shujiro ShigaYasuyoshi SawaguriKoji KabasawaTatsuya Momobayashi
    • B01J41/04C01B15/013
    • C01B15/0135
    • A process for purifying a hydrogen peroxide solution is disclosed, comprising treating a 10 to 60% by weight hydrogen peroxide solution having a pH between 1.5 and 5.0 and containing anionic impurities with a hydrogencarbonate type or carbonate type anion exchange resin while adding an acid or a salt thereof having an acid dissociation constant pKa in water of not more than 5 to the hydrogen peroxide solution to be treated continuously or semi-continuously in an amount of from 0.5 to 5 milli-equivalents per liter of hydrogen peroxide solution. The hydrogen peroxide decomposing activity of the anion exchange resin can be inhibited without decreasing a rate of removal of strong acid radicals in the anionic impurities thereby minimizing oxygen evolution due to decomposition of hydrogen peroxide.
    • 公开了一种用于纯化过氧化氢溶液的方法,其包括在加入酸或酸的情况下,将pH为1.5-5.0的10至60重量%的过氧化氢溶液和含有阴离子杂质的碳酸氢盐型或碳酸盐型阴离子交换树脂 其在水中的酸解离常数pKa为不超过5的连续或半连续的过氧化氢溶液,其量为0.5-5毫当量/升过氧化氢溶液。 可以抑制阴离子交换树脂的过氧化氢分解活性,而不会降低阴离子杂质中强酸性基团的除去速率,从而最小化由于过氧化氢分解引起的氧析出。
    • 2. 发明授权
    • Treatment of aqueous waste solution
    • 废水处理
    • US3966594A
    • 1976-06-29
    • US527151
    • 1974-11-25
    • Masaaki OhkawaYasuyoshi Sawaguri
    • Masaaki OhkawaYasuyoshi Sawaguri
    • C02F1/26G04G17/00B01D11/04
    • G04G17/00C02F1/26
    • Organic waste water containing water-soluble organic anionic substances is treated by1. contacting an acidic waste water with a water-insoluble organic solvent solution of at least one amine represented by the formula, ##EQU1## wherein R.sub.1 and R.sub. 2 are each a hydrogen or halogen atom or a C.sub.1 - C.sub.4 alkyl group, and R is a C.sub.8 - C.sub.18 alkyl or alkenyl group,2. separating the aqueous layer from the organic layer, and3. contacting said organic layer with an aqueous alkali solution whereby said substances are transferred to said aqueous alkali layer and said amine is recovered as the organic solution thereof.
    • 含有水溶性有机阴离子物质的有机废水通过以下方式进行处理:1,用至少一种由式2表示的胺的无水无机溶剂溶液接触酸性废水:-CH 2 -N-CH 2 - R 2各自为氢或卤素原子或C1-C4烷基,R为C8-C18烷基或烯基,2.分离有机层中的水性层,以及3.用有机物接触有机有机层 ALKALI解决方案,其中称为物质转移为标示水性碱性层和酸性胺作为其有机溶液被回收。