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    • 8. 发明申请
    • POLYCARBONATE-POLYSILOXANE COPOLYMERS, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM
    • 聚碳酸酯 - 聚硅氧烷共聚物,制备方法和形成的制品
    • US20080081893A1
    • 2008-04-03
    • US11537135
    • 2006-09-29
    • James Franklin HooverJan-Pleun LensBrian Mullen
    • James Franklin HooverJan-Pleun LensBrian Mullen
    • C08G77/12
    • C08G64/186C08G77/448C08L69/00C08L83/04Y10T428/31504Y10T428/31507C08L83/00C08L2666/18
    • A polycarbonate copolymer comprising90 to 100 mol % of units derived from a cyclohexylidene bisphenol of the formula wherein Ra′ and Rb′ are each independently C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4;2 to 35 wt % of units derived from a polysiloxane diol of the formulas or a combination thereof, wherein Ar is a substituted or unsubstituted C6-36 arylene group, each R is the same or different C1-13 monovalent organic group, each R6 is the same or different divalent C1-C30 organic group, and E is an integer from 2 to 100; and0 to 10 mol % of units derived from a dihydroxy aromatic compound of formula (3) wherein Ra and Rb are each independently halogen, p and q are each independently integers of 0 to 4, and the dihydroxy aromatic compound of formula (3) is not the same as the cyclohexylidene bisphenol or the polysiloxane diols.
    • 包含90-100mol%衍生自下式的亚环己基双酚的单元的聚碳酸酯共聚物各自独立地为C 1〜 12烷基,T是C 5-16亚烷基,C 5-16亚烷基亚烷基,C 1-5 - 亚烷基 ,C 1至5个亚烷基,C 6-13亚芳基,C 7-12芳基亚烷基,C 7-12 芳基亚烷基,C 7-12烷基亚芳基或C 7-12亚芳基烷基,r和s各自独立地为1至4; 2至35重量%衍生自下式的聚硅氧烷二醇或其组合的单元,其中Ar为取代或未取代的C 6〜36亚芳基,各R相同或不同, 每个R 6是相同或不同的二价C 1 -C 30 - 有机基团, ,E为2〜100的整数。 和0至10摩尔%的衍生自式(3)的二羟基芳族化合物的单元,其中R a和R b各自独立地为卤素,p和q各自独立地为 0〜4的整数,式(3)的二羟基芳族化合物与亚环己基双酚或聚硅氧烷二醇不同。
    • 9. 发明申请
    • THERMOPLASTIC COMPOSITION HAVING IMPROVED SCRATCH RESISTANCE, AND ARTICLES FORMED THEREFROM
    • 具有改进的耐刮擦性的热塑性组合物及其形成的制品
    • US20080004404A1
    • 2008-01-03
    • US11427102
    • 2006-06-28
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • C08L69/00C08L53/00C08L67/00
    • C08L69/00C08L69/005C08L2666/18
    • A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
    • 热塑性组合物包含A)25至95重量份的第一聚碳酸酯,其基本上由以下组成:i)25至100摩尔%的包含烷基取代的双酚碳酸酯单元的第一碳酸酯单元,ii)0至75摩尔%的第二 碳酸酯单元,其中第一和第二碳酸酯单元不相同,第一和第二碳酸酯单元在第一聚碳酸酯中的摩尔百分比之和为100摩尔%; B)5〜75重量份碳酸酯单元与芳基酯单元的摩尔比为95:5〜10:90的聚酯 - 聚碳酸酯; 和C)0至65重量份的第二聚碳酸酯,其中第一聚碳酸酯和第二聚碳酸酯不相同,并且第一聚碳酸酯,聚酯 - 聚碳酸酯和第二聚碳酸酯的重量份之和为100份 重量。
    • 10. 发明申请
    • METHODS OF POLYMER PREPARATION USING POLYCYCLIC DIHYDROXY COMPOUNDS
    • 使用多环二羟基化合物制备聚合物的方法
    • US20070260033A1
    • 2007-11-08
    • US11693314
    • 2007-03-29
    • Jan KampsJan-Pleun LensJames MahoodArakali RadhakrishnaT. RajRavindra Singh
    • Jan KampsJan-Pleun LensJames MahoodArakali RadhakrishnaT. RajRavindra Singh
    • C08G64/04
    • C07C69/757C07C45/69C07C45/74C07C67/343C07C67/347C07C2601/14C08G64/14C07C49/223
    • Disclosed herein is a process for preparing a polymer comprising structural units derived from polycyclic dihydroxy compound having Formula (I), wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4. The process comprises subjecting a polycyclic dihydroxy compound of Formula (I) to polymerization.
    • 本文公开了一种制备包含衍生自具有式(I)的多环二羟基化合物的结构单元的聚合物的方法,其中R 1选自氰基官能团,硝基官能团,脂族基团 具有1至10个碳的官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团,硝基官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; 并且每次出现时,每个R 3和R 4可以相同或不同,并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团 具有3至10个碳,“n”是0至4的整数,“m”是0至4的整数。该方法包括使式(I)的多环二羟基化合物进行聚合。