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    • 2. 发明授权
    • Expansive material and its preparation process
    • 膨胀材料及其制备工艺
    • US08663383B2
    • 2014-03-04
    • US13261027
    • 2010-05-20
    • Takayuki HiguchiTaiichiro MoriHideaki IshidaRyoetsu YoshinoMinoru Morioka
    • Takayuki HiguchiTaiichiro MoriHideaki IshidaRyoetsu YoshinoMinoru Morioka
    • C04B2/02
    • C04B40/0039C04B38/02Y02P40/18C04B7/02C04B22/064C04B22/143C04B40/0082C04B40/0231
    • The invention provides an expansive material that allows for large expansion of concrete at a material age of 2 to 7 days after pouring and permits concrete to have higher initial compressive strength and makes sure good storage stability, and a process for preparing that expansive material.The invention provides an expansive material and a process for preparing that expansive material, characterized in that clinker or pulverized clinker containing free lime, a hydraulic compound and calcium sulfate anhydrite is heat treated in a carbon dioxide gas atmosphere to form calcium carbonate in it. Preferably, the expansive material contains a particle in which the free lime, hydraulic compound, calcium sulfate anhydrite and calcium carbonate are all present; the content of calcium carbonate is 0.5 to 10% by mass; and the expansive material has a Blaine's specific surface area of 1,500 to 90,000 cm2/g. The expansive material is blended with cement into a cement composition. The preparation conditions are preferably a carbon dioxide gas flow rate of 0.01 to 0.1 L/min. and a temperature of 200 to 800° C., under which conditions there is calcium carbonate formed.
    • 本发明提供了一种膨胀材料,其允许混凝土在浇筑后2至7天的时间内大量膨胀,并允许混凝土具有较高的初始抗压强度并确保良好的储存稳定性,以及制备该膨胀材料的方法。 本发明提供了一种膨胀材料和一种制备膨胀材料的方法,其特征在于,在二氧化碳气氛中对含有游离石灰的熟料或粉碎熟料,水硬性化合物和硫酸钙无水石膏进行热处理,以形成碳酸钙。 优选地,膨胀材料包含其中存在游离石灰,水硬性化合物,硬脂酸钙和碳酸钙的颗粒; 碳酸钙的含量为0.5〜10质量% 膨胀材料的Blaine比表面积为1500〜90,000cm2 / g。 膨胀材料与水泥混合成水泥组合物。 制备条件优选为0.01〜0.1L / min的二氧化碳气体流量。 温度为200〜800℃,在此条件下形成碳酸钙。
    • 7. 发明授权
    • Cement admixture and cement composition
    • 水泥外加剂和水泥组成
    • US08663384B2
    • 2014-03-04
    • US13991524
    • 2011-10-24
    • Takayuki HiguchiTsutomu KidaRyoetsu Yoshino
    • Takayuki HiguchiTsutomu KidaRyoetsu Yoshino
    • C04B22/14C04B28/16
    • C04B7/28C04B28/02C04B28/04C04B40/0039C04B2111/00025Y02W30/92C04B7/02C04B22/008C04B22/064C04B22/142C04B22/143C04B2103/58C04B18/105C04B14/06C04B14/28
    • The invention provides a cement admixture that improves the ability of concrete to bring about high initial strength, works in favor of enhancing the effect on hexavalent chromium reductions, and is less likely to decrease in the effect on hexavalent chromium reductions even upon storage as well as a method for reducing hexavalent chromium. The invention is embodied as (1) A cement admixture, characterized by comprising an expanding material containing free lime, a hydraulic compound and calcium sulfate anhydrite, and a tin sulfate-containing substance; (2) The cement admixture according to (1), characterized in that the tin sulfate-containing substance is contained in an amount of 0.2 to 8 parts by mass—as calculated on a tin sulfate basis—in a total of 100 parts by mass of the expanding material and the tin sulfate-containing substance; (3) The cement admixture according to (1) or (2), characterized in that the expanding material has been treated with carbon dioxide gas to form calcium carbonate therein; (4) The cement admixture according to any one of (1) to (3), characterized in that the expanding material has been surface treated with a shrinkage reducer; (5) A cement composition, characterized by containing cement, and the cement admixture according to any one of (1) to (4); and (6) A method for reducing hexavalent chromium, characterized by use of the cement composition according to (5).
    • 本发明提供了一种提高混凝土产生高初始强度的能力的水泥混合物,有利于增加对六价铬​​还原的影响,并且即使在储存时也不太可能降低对六价铬还原的影响,以及 一种降低六价铬的方法。 本发明体现为:(1)一种水泥混合物,其特征在于包含含有游离石灰的膨胀材料,水硬性化合物和无水硫酸钙,以及含硫酸锡物质; (2)根据(1)所述的水泥混合物,其特征在于,所述含硫酸锡物质的含量为0.2〜8质量份(以硫酸锡为基准),总计为100质量份 的膨胀材料和含硫酸锡物质; (3)根据(1)或(2)所述的水泥外加剂,其特征在于,所述膨胀材料已经用二氧化碳气体处理以在其中形成碳酸钙; (4)如(1)〜(3)中任一项所述的水泥外加剂,其特征在于,所述膨胀材料用减缩剂进行表面处理; (5)一种水泥组合物,其特征在于含有水泥,和(1)〜(4)中任一项所述的水泥混合物; (6)一种减少六价铬的方法,其特征在于使用(5)所述的水泥组合物。
    • 8. 发明授权
    • Alumina fiber aggregate, process for producing the same, and use thereof
    • 氧化铝纤维聚集体,其制造方法及其用途
    • US08273816B2
    • 2012-09-25
    • US12682471
    • 2008-09-29
    • Yasutaka OhshimaIsamu HiranoTakayuki Higuchi
    • Yasutaka OhshimaIsamu HiranoTakayuki Higuchi
    • C08K3/18
    • C08J5/041C04B35/62236C04B35/62245C04B35/6261C04B2235/526C04B2235/5264
    • An object of the invention is to provide an alumina fiber aggregate which, when used as a filler in various materials such as, e.g., resins, coating materials, metals, and ceramics, enables the mixtures to have reduced viscosity and thereby heightens the productivity of products containing alumina fibers, and which enables cured thermosetting resins to have a sufficiently heightened thermal conductivity.This alumina fiber aggregate, when examined by the electron microscope method, gives a frequency distribution regarding number of fibers, wherein the number of fibers having a fiber length of 50-200 μm is 70% or more (including 100%), the number of fibers having a fiber length smaller than 50 μm is 30% or less (including 0), the number of fibers of 50-100 μm is 30-50%, the number of fibers longer than 100 μm but not longer than 200 μm is 30-50%, and the number of fibers longer than 200 μm is 20% or less (including 0). The fibrous mass comprises 70-100% by mass of Al2O3 and 0-30% by mass of SiO2.
    • 本发明的目的是提供一种氧化铝纤维聚集体,当用作诸如树脂,涂料,金属和陶瓷的各种材料中的填料时,使得混合物具有降低的粘度,从而提高生产率 含有氧化铝纤维的产品,并且使固化的热固性树脂具有足够高的导热性。 当通过电子显微镜方法检查时,该氧化铝纤维聚集体给出了关于纤维数量的频率分布,其中纤维长度为50-200μm的纤维的数量为70%以上(包括100%),数量 纤维长度小于50μm的纤维为30%​​以下(包括0),50〜100μm的纤维数为30〜50%,长于100μm且不超过200μm的纤维数为30根 -50%,长于200μm的纤维数为20%以下(包括0)。 纤维质量包含70-100质量%的Al 2 O 3和0〜30质量%的SiO 2。