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1. 发明授权

US08163860B2 Norbornene copolymer and production method thereof 有权
标题翻译：降冰片烯共聚物及其制备方法
公开(公告)号：US08163860B2
公开(公告)日：2012-04-24
申请号：US13146600
申请日：2010-01-29
申请人： Shojiro Kaita , Nobuyuki Kibino , Kazufumi Kai
发明人： Shojiro Kaita , Nobuyuki Kibino , Kazufumi Kai
IPC分类号： C08F232/04 , C08F4/70
CPC分类号： C08F232/08
摘要： The invention relates to a norbornene copolymer having excellent properties such as transparency, heat resistance, low water absorption and electric insulating property, which copolymer comprises a monomer unit represented by formula (1) and formula (2) and having a number average molecular weight (Mn) of 300,000 to 2,000,000. (In the formulae, R1 represents an alkyl group having 1 to 10 carbon atoms; and R2, R3 and R4 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.)
摘要翻译：本发明涉及具有透明性，耐热性，低吸水性和电绝缘性等优异性能的降冰片烯共聚物，该共聚物包括由式（1）和式（2）表示的单体单元，其数均分子量（ Mn）为30万至2,000,000。（式中，R1表示碳原子数1〜10的烷基，R2，R3，R4分别表示氢原子或碳原子数1〜10的烷基。

2. 发明申请

US20110282014A1 NORBORNENE COPOLYMER AND PRODUCTION METHOD THEREOF 有权
标题翻译：诺贝恩共聚物及其生产方法
公开(公告)号：US20110282014A1
公开(公告)日：2011-11-17
申请号：US13146600
申请日：2010-01-29
申请人： Shojiro Kaita , Nobuyuki Kibino , Kazufumi Kai
发明人： Shojiro Kaita , Nobuyuki Kibino , Kazufumi Kai
IPC分类号： C08F4/82 , C08F232/08
CPC分类号： C08F232/08
摘要： The invention relates to a norbornene copolymer having excellent properties such as transparency, heat resistance, low water absorption and electric insulating property, which copolymer comprises a monomer unit represented by formula (1) and formula (2) and having a number average molecular weight (Mn) of 300,000 to 2,000,000. (In the formulae, R1 represents an alkyl group having 1 to 10 carbon atoms; and R2, R3 and R4 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.)
摘要翻译：本发明涉及具有透明性，耐热性，低吸水性和电绝缘性等优异性能的降冰片烯共聚物，该共聚物包括由式（1）和式（2）表示的单体单元，其数均分子量（ Mn）为30万至2,000,000。（式中，R1表示碳原子数1〜10的烷基，R2，R3，R4分别表示氢原子或碳原子数1〜10的烷基。

3. 发明申请

US20100286354A1 ALLYL ALCOHOL COPOLYMER AND PRODUCTION METHOD THEREOF 审中-公开
标题翻译： ALLYL酒精共聚物及其生产方法
公开(公告)号：US20100286354A1
公开(公告)日：2010-11-11
申请号：US12810444
申请日：2008-12-22
申请人： Nobuyuki Kibino , Yukiharu Hetsugi , Kazufumi Kai
发明人： Nobuyuki Kibino , Yukiharu Hetsugi , Kazufumi Kai
IPC分类号： C08F216/08
CPC分类号： C08F210/14 , C08F8/04 , C08F212/08 , C08F216/08 , C08F2800/10 , C08F2800/20 , C08F222/14 , C08F222/04
摘要： The invention relates to an allyl alcohol copolymer comprising structures represented by formula (1) and (2) as monomer units. (In the formula, R represents an aliphatic hydrocarbon group having 2 to 20 carbon atoms, which may be branched or include a cyclic structure). The copolymer of the invention is excellent in compatibility with various resins, adhesiveness, electric insulation, low water absorption, thermal stability and surface active effect.
摘要翻译：本发明涉及包含由式（1）和（2）表示的结构作为单体单元的烯丙醇共聚物。（式中，R表示碳原子数2〜20的脂肪族烃基，可以是支链状或环状结构）。本发明的共聚物与各种树脂的相容性，粘合性，电绝缘性，低吸水性，热稳定性和表面活性效果优异。

4. 发明申请

US20110124815A1 POLYURETHANE AND PRODUCTION METHOD THEREOF 审中-公开
标题翻译：聚氨酯及其生产方法
公开(公告)号：US20110124815A1
公开(公告)日：2011-05-26
申请号：US13003261
申请日：2009-08-04
申请人： Nobuyuki Kibino , Kazufumi Kai
发明人： Nobuyuki Kibino , Kazufumi Kai
IPC分类号： C08G71/04
CPC分类号： C08G18/6212 , C08G18/69 , C08G18/73 , C08G18/755 , C08J5/18 , C08J2375/04 , C09D175/04 , H01B3/302
摘要： The invention relates to polyurethane having s excellent electric insulating property and thermal stability, obtained by a polyaddition reaction between a polyol copolymer which is a copolymer comprising as monomer units the structures represented by formulae (1) and (2) and a polyisocyanate compound: wherein R represents aliphatic hydrocarbon group having 2 to 20 carbon atoms, which may be branched and may contain a cyclic structure; and a production method thereof.
摘要翻译：本发明涉及具有优异的电绝缘性和热稳定性的聚氨酯，其通过多元醇共聚物之间的加聚反应获得，所述多元醇共聚物是包含作为单体单元的由式（1）和（2）表示的结构的共聚物和多异氰酸酯化合物：其中 R表示碳原子数2〜20的脂肪族烃基，可以是支链状，也可以含有环状结构。及其制造方法。

5. 发明授权

US5770664A Catalyst component for producing polyolefin, catalyst for producing polyolefin comprising the catalyst component, and process for producing polyolefin in the presence of the catalyst 失效
标题翻译：用于生产聚烯烃的催化剂组分，用于生产包含催化剂组分的聚烯烃的催化剂，以及在催化剂存在下制备聚烯烃的方法
公开(公告)号：US5770664A
公开(公告)日：1998-06-23
申请号：US855510
申请日：1997-05-13
申请人： Yoshikuni Okumura , Nobuyuki Kibino , Tetsuya Maki , Akihiro Hori , Kiyotaka Ishida , Shigenobu Miyake , Shintaro Inazawa
发明人： Yoshikuni Okumura , Nobuyuki Kibino , Tetsuya Maki , Akihiro Hori , Kiyotaka Ishida , Shigenobu Miyake , Shintaro Inazawa
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16
CPC分类号： C08F210/16 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/943
摘要： A catalyst component for producing polyolefin, a catalyst for producing polyolefin using the catalyst component, and a process for producing polyolefin in the presence of the catalyst. The catalyst component comprises a metallocene compound represented by formula (1): ##STR1## All the symbols in formula (1) are defined in the description.
摘要翻译：用于生产聚烯烃的催化剂组分，使用催化剂组分制备聚烯烃的催化剂，以及在催化剂存在下制备聚烯烃的方法。催化剂组分包括由式（1）表示的茂金属化合物：（1）式（1）中的所有符号在说明书中定义。

6. 发明授权

US06303714B1 Catalyst component for olefin polymerization catalyst for olefin polymerization, and process for preparing polyolefin 失效
标题翻译：用于烯烃聚合的烯烃聚合催化剂的催化剂组分和制备聚烯烃的方法
公开(公告)号：US06303714B1
公开(公告)日：2001-10-16
申请号：US09242664
申请日：1999-02-22
申请人： Nobuyuki Kibino , Kiyotaka Ishida , Tsugihiko Hakozaki , Tsutomu Sakuragi , Shigenobu Miyake , Shintaro Inazawa
发明人： Nobuyuki Kibino , Kiyotaka Ishida , Tsugihiko Hakozaki , Tsutomu Sakuragi , Shigenobu Miyake , Shintaro Inazawa
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F110/02 , C08F2420/04 , Y10S526/943 , C08F4/64044 , C08F2500/12 , C08F2500/04 , C08F2500/11
摘要： The present invention provides an olefin polymerization catalyst component comprising a transition metal compound represented by general formula (1) LmCpnMX1X2 (1) an olefin polymerization catalyst containing the catalyst component as a transition metal component, and a method of producing a polyolefin using the catalyst. According to the present invention, polyolefins having a wide molecular weight distribution and excellent moldability and containing small amounts of low molecular weight components can be produced with high activity.
摘要翻译：本发明提供一种烯烃聚合催化剂组分，其包含由通式（1）表示的过渡金属化合物，含有催化剂组分作为过渡金属组分的烯烃聚合催化剂，以及使用该催化剂制备聚烯烃的方法。根据本发明，可以高活性地制备分子量分布宽，成型性优异且含有少量低分子量成分的聚烯烃。

7. 发明授权

US5329031A Metallocene and process for producing polyolefin using the same 失效
公开(公告)号：US5329031A
公开(公告)日：1994-07-12
申请号：US982894
申请日：1992-11-30
申请人： Shigenobu Miyake , Nobuyuki Kibino , Takashi Monoi , Hiroyuki Ohira , Shintaro Inazawa
发明人： Shigenobu Miyake , Nobuyuki Kibino , Takashi Monoi , Hiroyuki Ohira , Shintaro Inazawa
IPC分类号： C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/02
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/943
摘要： A metallocene having an asymmetric ligand which is represented by the formula below and its enantiomer: ##STR1## and a process for producing a polyolefin using the same as a catalyst component. The metallocene and its enantiomer are particularly effective in the production of highly stereospecific polyolefins.

8. 发明申请

US20130261271A1 CATALYST FOR NORBORNENE MONOMER POLYMERIZATION AND METHOD FOR PRODUCING NORBORNENE POLYMER 有权
标题翻译：用于NORBENNENE单体聚合的催化剂和用于生产NORBENNENE聚合物的方法
公开(公告)号：US20130261271A1
公开(公告)日：2013-10-03
申请号：US13824221
申请日：2011-10-25
申请人： Satoshi Fujibe , Nobuyuki Kibino
发明人： Satoshi Fujibe , Nobuyuki Kibino
IPC分类号： C08F32/08
CPC分类号： C08F32/08 , C07C251/12 , C07F15/006 , C08F4/619 , C08F4/61908 , C08F4/7022 , C08F32/04 , C08F232/08
摘要： The invention relates to a catalyst for the polymerization of norbornene monomers comprising transition metal complex (A) represented by formula (1); and a method for producing a norbornene (co)polymer, especially a norbornene copolymer containing a monomer unit represented by formulae (2) and (3), wherein a norbornen monomer is homopolyzed or copolymerized in the presence of the polymerization catalyst. Preferable examples of the transition metal complex (A) include (π-allyl){4-(2,6-diisopropylphenylimino)-2-penten-2-olato-κ2N,O}palladium and (π-allyl){4-(1-naphthylimino)-2-penten-2-olato-κ2N,O}palladium. In the formulae, the symbols are as defined in the description. A norbornene (co)polymer which has excellent transparency, excellent heat resistance, excellently low water absorption and excellent electrical insulation characteristics can be efficiently produced by the present invention.
摘要翻译：本发明涉及包含由式（1）表示的过渡金属络合物（A）的降冰片烯单体的聚合催化剂; 和降冰片烯（共）聚合物的制造方法，特别是含有式（2）和（3）所示的单体单元的降冰片烯共聚物的制造方法，其中降冰片烯单体在聚合催化剂存在下被均聚或共聚。过渡金属络合物（A）的优选实例包括（β-烯丙基）{4-（2,6-二异丙基苯基亚氨基）-2-戊烯-2-醇 - 卡巴N，O}钯和（β-烯丙基）{4-（ 1-萘基亚氨基）-2-戊烯-2-醇 - 卡巴N，O}钯。在公式中，符号如说明书中所定义。通过本发明可以有效地制造具有优异的透明性，优异的耐热性，优异的低吸水性和优异的电绝缘性的降冰片烯（共）聚合物。

9. 发明申请

US20070161828A1 Production process of 3-alkoxy-1-propanols, and 3-alkoxy-1-propanols obtained by the production process 失效
标题翻译：通过制备方法得到的3-烷氧基-1-丙醇和3-烷氧基-1-丙醇的制备方法
公开(公告)号：US20070161828A1
公开(公告)日：2007-07-12
申请号：US10588085
申请日：2005-02-04
申请人： Nobuyuki Kibino , Yasushi Kadowaki , Masaaki Sakai , Yukiharu Hetsugi
发明人： Nobuyuki Kibino , Yasushi Kadowaki , Masaaki Sakai , Yukiharu Hetsugi
IPC分类号： C07C29/128
CPC分类号： C07C41/06 , C07C29/10 , C07C31/205 , C07C43/13 , C07C43/178
摘要： In the presence of a catalyst containing at least one element selected from the group consisting of elements of the group III, lanthanoid elements and actinoid elements of the Periodic Table, an allyl alcohol is reacted with an alcohol compound. A method for efficiently producing 3-alkoxy-1-propanol in a single step using an alcohol as a starting material is provided.
摘要翻译：在含有选自元素周期表第III族元素，镧系元素和锕系元素中的至少一种元素的催化剂的存在下，烯丙醇与醇化合物反应。提供了使用醇作为原料在一个步骤中有效生产3-烷氧基-1-丙醇的方法。

10. 发明授权

US5349032A Metallocene and process for producing polyolefin using the same 失效
标题翻译：茂金属及使用其制备聚烯烃的方法
公开(公告)号：US5349032A
公开(公告)日：1994-09-20
申请号：US212931
申请日：1994-03-15
申请人： Shigenobu Miyake , Nobuyuki Kibino , Takashi Monoi , Hiroyuki Ohira , Shintaro Inazawa
发明人： Shigenobu Miyake , Nobuyuki Kibino , Takashi Monoi , Hiroyuki Ohira , Shintaro Inazawa
IPC分类号： C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/943
摘要： A metallocene having an asymmetric ligand which is represented by the formula below and its enantiomer: ##STR1## and a process for producing a polyolefin using the same as a catalyst component. The metallocene and its enantiomer are particularly effective in the production of highly stereospecific polyolefins.
摘要翻译：具有由下式表示的不对称配位体及其对映异构体的金属茂：使用该催化剂组分制备聚烯烃的方法。茂金属及其对映体在高立体定向聚烯烃的生产中特别有效。

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