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    • 8. 发明授权
    • Polyimide and high-temperature adhesive thereof
    • 聚酰亚胺及其高温粘合剂
    • US4931531A
    • 1990-06-05
    • US210789
    • 1988-06-24
    • Shoji TamaiMasahiro OhtaSaburo KawashimaKatsuaki IiyamaHideaki OikawaAkihiro Yamaguchi
    • Shoji TamaiMasahiro OhtaSaburo KawashimaKatsuaki IiyamaHideaki OikawaAkihiro Yamaguchi
    • H01L21/265C08G73/10C08L79/08H01J37/317
    • C08G73/1064C08G73/1071
    • This invention relates to a novel polyimide which is high-temperature resistant and capable of being molded in a fused state. This invention also relates to a high-temperature adhesive using the polyimide.The polyimide consists essentially of recurring units of the formula: ##STR1## where R is a tetra-valent radical selected from the group consisting of an aliphatic radical having 2 or more carbon atoms, alicyclic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are linked to one another directly or via a bridge member.The polyimide can be prepared by reacting bis[4-(4-aminophenoxy)phenoxy)phenyl] sulfone with a tetracarboxylic dianhydride in an organic solvent and imidizing the resultant polyamic acid.Various tetracarboxylic dianhydrides can be used and preferred dianhydride are pyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride, bis(3,4-diarboxyphenyl) ether dianhydride, 3,3',4,4'-biphenyltetracarboxylic dianhydride, and 4,4'-(p-phenylenedioxy)diphthalic dianhydride.
    • 本发明涉及一种耐高温且能够熔融融合的新型聚酰亚胺。 本发明还涉及使用该聚酰亚胺的高温粘合剂。 聚酰亚胺基本上由下式的重复单元组成:其中R是选自具有2个或更多个碳原子的脂族基团,脂环族基团,单芳族基团,稠合多芳族基团和非芳族基团的四价基团, 其中芳族基团直接或通过桥连构件彼此连接。 聚酰亚胺可以通过使双[4-(4-(4-(4-氨基苯氧基)苯氧基)苯基]砜与四羧酸二酐在有机溶剂中反应制备,并酰亚胺化得到的聚酰胺酸。 可以使用各种四羧酸二酐,优选二酐是均苯四酸二酐,3,3分钟,4,4分钟 - 二苯甲酮四羧酸二酐,双(3,4-二羧基苯基)醚二酐,3,3分钟,4,4分钟 - 联苯四羧酸二酐, 和4,4分钟 - (对亚苯基二氧基)二邻苯二甲酸二酐。