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    • 1. 发明授权
    • Flame-retardant polyvinyl alcohol base fiber
    • 阻燃聚乙烯醇基纤维
    • US6066396A
    • 2000-05-23
    • US319239
    • 1999-06-07
    • Shinya InadaMasahiro SatohHayami YoshimochiAkio OhmoryIsao TokunagaAkira KubotsuMasakazu NishiyamaTomoyuki Sano
    • Shinya InadaMasahiro SatohHayami YoshimochiAkio OhmoryIsao TokunagaAkira KubotsuMasakazu NishiyamaTomoyuki Sano
    • D01F1/07D01F6/50D02G3/00B29C47/06D01F6/14
    • D01F6/50D01F1/07Y10T428/2924Y10T428/2929
    • A vinyl-alcohol-based polymer and vinyl-halide-based polymer are dissolved in a common organic solvent for them, a typical example of which is dimethylsulfoxide, to obtain a dope wherein a solution of the vinyl-halide-based polymer having a particle size of 1-50 .mu.m is present in the solution of the vinyl-alcohol-based polymer. This dope is spun into a low temperature solidifying bath comprising a solidifying solvent such as methanol, and the organic solvent. The resultant is subjected to extraction, drying, dry heat drawing, and optional heat shrinking or acetalization to obtain fiber. In the fiber thus obtained, the vinyl-alcohol-based polymer makes sea phases, and the vinyl-halide-based polymer makes island phases whose size is 0.1-3 .mu.m. The crystallinity degree of the vinyl-alcohol-based polymer is 65-85%.The polyvinyl-alcohol-based flame retardant fiber is useful for clothes, industrial materials, living materials and the like. It can be produced at low costs, and has excellent spinning stability and dimensional stability in hot water.
    • PCT No.PCT / JP98 / 04424 Sec。 371日期1999年6月7日 102(e)日期1999年6月7日PCT提交1998年10月1日PCT公布。 公开号WO99 /​​ 18267 日期1999年04月15日乙烯基醇类聚合物和乙烯基卤化物类聚合物溶解在普通的有机溶剂中,其典型的例子是二甲基亚砜,以获得涂料,其中乙烯基卤化物 - 乙烯醇类聚合物的溶液中存在粒径为1-50μm的聚合物。 将该纺丝液纺成包含固化溶剂如甲醇和有机溶剂的低温固化浴。 将所得物进行萃取,干燥,干热拉伸和任选的热收缩或缩醛化以获得纤维。 在由此获得的纤维中,乙烯醇系聚合物形成海相,卤化乙烯基系聚合物形成尺寸为0.1〜3μm的岛相。 乙烯醇系聚合物的结晶度为65〜85%。 聚乙烯醇类阻燃纤维可用于衣服,工业材料,生活材料等。 可以低成本生产,在热水中具有优异的纺丝稳定性和尺寸稳定性。