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1. 发明授权

US5663262A Compound containing an oxamic acid group, a process for producing the compound, and a resin composition containing the compound 失效
标题翻译：含有羟基酸基团的化合物，该化合物的制备方法和含有该化合物的树脂组合物
公开(公告)号：US5663262A
公开(公告)日：1997-09-02
申请号：US433097
申请日：1989-11-08
申请人： Shinsuke Shirakawa , Kazunori Kanda , Mitsuo Yamada , Kei Aoki , Satoshi Urano , Nobuaki Tomita
发明人： Shinsuke Shirakawa , Kazunori Kanda , Mitsuo Yamada , Kei Aoki , Satoshi Urano , Nobuaki Tomita
IPC分类号： B01F17/00 , B01F17/54 , C07C233/56 , C07C271/12 , C08C19/22 , C08F8/30 , C08F8/44 , C08F12/26 , C08F20/36 , C08F20/60 , C08G18/64 , C08G59/14 , C08G63/91 , C08G69/48 , C08G73/02 , C08G77/388 , C09D5/44 , C09D201/00 , C08F26/00 , C07C69/52 , C08F126/00 , C08F226/00
CPC分类号： C08G69/48 , B01F17/0035 , B01F17/005 , B01F17/0071 , C07C233/56 , C07C271/12 , C08C19/22 , C08F12/26 , C08F20/36 , C08F20/60 , C08F8/30 , C08F8/44 , C08G18/643 , C08G59/1477 , C08G63/91 , C08G73/0206 , C08G77/388 , C09D5/4434
摘要： The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.
摘要翻译：本发明涉及具有高反应性并且具有水稳定性并用作反应材料或树脂形式的油漆，粘合剂和塑料材料等的含有羟基酸基团的化合物。由于在这些化合物中，在分子的一部分中引入了一个羟基酸基团，而且该酰胺酸基是一个离子官能团，所以该化合物在水中表现出优异的溶解性和分散性，而且由于羟基酸组是消失型加热，化合物在硬化后不会残留在硬化产品中。因此，由这些化合物得到的硬化物的耐水性，耐腐蚀性和耐久性优异。

2. 发明授权

US4829105A Electrodeposition coating composition containing modified epoxy resin having chargeable groups 失效
标题翻译：含有可带电荷基团的改性环氧树脂的电沉积涂料组合物
公开(公告)号：US4829105A
公开(公告)日：1989-05-09
申请号：US149299
申请日：1988-01-28
申请人： Mitsuo Yamada , Kazunori Kanda , Shinsuke Shirakawa , Hirotoshi Umemoto , Ryuzo Mizuguchi
发明人： Mitsuo Yamada , Kazunori Kanda , Shinsuke Shirakawa , Hirotoshi Umemoto , Ryuzo Mizuguchi
IPC分类号： C08G18/08 , C08G18/58 , C08G59/14 , C08G59/40 , C09D5/44
CPC分类号： C08G18/58 , C08G18/0819 , C08G59/1433 , C08G59/40 , C09D5/443
摘要： An anodic electrodeposition composition containing a water-soluble or water-dispersible modified epoxy resin derived from an epoxy resin having two epoxide groups and at least one alcoholic hydroxy group at the terminals and the middle of the resin backbone, respectively. The modified epoxy resin has at least one polymeric side chain block bound to said alcoholic hydroxy group and at least one acid group derived from said terminal epoxide group.

3. 发明授权

US5194655A Polymerizable carbonates having ethylenic and acetylenic functions 失效
标题翻译：具有乙烯和乙酰基官能团的聚合碳酸酯
公开(公告)号：US5194655A
公开(公告)日：1993-03-16
申请号：US699376
申请日：1991-05-14
申请人： Mitsuo Yamada , Kei Aoki , Satoshi Urano , Ryuzo Mizuguchi
发明人： Mitsuo Yamada , Kei Aoki , Satoshi Urano , Ryuzo Mizuguchi
IPC分类号： C07C69/96 , C07C219/16 , C07C233/20
CPC分类号： C07C69/96
摘要： A carbonate compound having ethylenically unsaturated and acetylenically unsaturated functions are disclosed. The compound is represented by the formula: ##STR1## wherein, A is the residue of a hydroxy group-containing, ethylenically unsaturated monomer with removal of the hydroxyl group, R.sup.1 and R.sup.2 are independently a hydrogen atom or a C.sub.1 -C.sub.20 alkyl.

4. 发明授权

US5194653A Carbonates of acetylenic alcohols 失效
公开(公告)号：US5194653A
公开(公告)日：1993-03-16
申请号：US923435
申请日：1992-08-03
申请人： Mitsuo Yamada , Kei Aoki , Satoshi Urano , Ryuzo Mizuguchi
发明人： Mitsuo Yamada , Kei Aoki , Satoshi Urano , Ryuzo Mizuguchi
IPC分类号： C07C69/96 , C07C245/08 , C07C251/24 , C07C291/08 , C07C317/22 , C07C323/21
CPC分类号： C07C245/08 , C07C251/24 , C07C291/08 , C07C317/22 , C07C323/21 , C07C69/96
摘要： Polymerizable carbonate compounds of the formula: ##STR1## wherein A is an aromatic polycycle, R.sup.1 and R.sup.2 are independently hydrogen atom or alkyl, and n is 1, 2 or 3, are disclosed. They are useful as a component of nonemanating, self-curing and heat resistant resin compositions.

5. 发明授权

US5258542A Carbonates of acetylenic alcohols 失效
标题翻译：炔醇的碳酸盐
公开(公告)号：US5258542A
公开(公告)日：1993-11-02
申请号：US923434
申请日：1992-08-03
申请人： Mitsuo Yamada , Kei Aoki , Satoshi Urano , Ryuzo Mizuguchi
发明人： Mitsuo Yamada , Kei Aoki , Satoshi Urano , Ryuzo Mizuguchi
IPC分类号： C07C69/96 , C07C245/08 , C07C251/24 , C07C291/08 , C07C317/22 , C07C323/20 , C07C323/21
CPC分类号： C07C69/96 , C07C245/08 , C07C251/24 , C07C291/08 , C07C317/22 , C07C323/20 , C07C323/21 , C07C2103/24
摘要： Polymerizable carbonate compounds of the formula: ##STR1## wherein A is an aromatic polycycle, R.sup.1 and R.sup.2 are independently hydrogen atom or alkyl, and n is 1, 2 or 3, are disclosed. They are useful as a component of nonemanating, self-curing and heat resistant resin compositions.
摘要翻译：其中A是芳族多环，R1和R2独立地是氢原子或烷基，并且n是1,2或3，可以是下式的可聚合的碳酸酯化合物。它们可用作非人造，自固化和耐热树脂组合物的组分。

6. 发明授权

US06410146B1 Cationic electrodeposition coating composition 有权
公开(公告)号：US06410146B1
公开(公告)日：2002-06-25
申请号：US09754140
申请日：2001-01-05
申请人： Shinsuke Shirakawa , Keisuke Tsutsui , Mitsuo Yamada
发明人： Shinsuke Shirakawa , Keisuke Tsutsui , Mitsuo Yamada
IPC分类号： B32B1508
摘要： A cationic electrodeposition coating composition is provided which contains blocked isocyanate curing agent which is blocked with a substance not recognized as a HAPs (hazardous atmospheric pollutant). The cationic electrodeposition coating composition of the present invention contains a cationic group-containing epoxy modified base resin and a blocked isocyanate curing agent, wherein said blocked isocyanate curing agent is obtained by reacting a polyisocyanate compound with, as a blocking agent, a terminal primary OH-containing propylene glycol monoalkyl ether and expressed by the formula RO(CH(CH3)CH2O)nH (where R is an alkyl group having 1 to 8 carbons, which may be branched, and n is 1 to 3).

7. 发明授权

US06369134B2 Cationic electrodeposition coating composition containing plasticizer 失效
标题翻译：含有增塑剂的阳离子电沉积涂料组合物
公开(公告)号：US06369134B2
公开(公告)日：2002-04-09
申请号：US09754069
申请日：2001-01-05
申请人： Makoto Ando , Masahiro Takegawa , Shinsuke Shirakawa , Mitsuo Yamada
发明人： Makoto Ando , Masahiro Takegawa , Shinsuke Shirakawa , Mitsuo Yamada
IPC分类号： C08L6300
CPC分类号： C09D5/4457 , C08G18/581 , C08G18/584 , C08G18/8064 , C08G18/8074 , C08K5/06 , C08L75/04
摘要： A cationic electrodeposition coating composition which contains a plasticizer is provided, which does not cause poor adhesion with intermediate and top coats, and allows the VOC content to be reduced. The cationic electrodeposition coating composition of the present invention is a cationic electrodeposition coating composition which contains a cationic group-containing epoxy modified base resin, a blocked isocyanate curing agent and a plasticizer, wherein the plasticizer is a propylene oxide oligomer with an average molecular weight of 200 to 1500, contains a primary hydroxyl group on the repeating terminals of the propylene oxide, and contains one or two primary hydroxyl groups and/or primary amino groups in the molecule.
摘要翻译：提供了含有增塑剂的阳离子电沉积涂料组合物，其不会与中间涂层和顶涂层粘附不良，并且允许VOC含量降低。本发明的阳离子电沉积涂料组合物是阳离子电沉积涂料组合物，其含有含阳离子基团的环氧改性基础树脂，封端异氰酸酯固化剂和增塑剂，其中增塑剂是平均分子量为 200至1500，在环氧丙烷的重复端含有伯羟基，并且在分子中含有一个或两个伯羟基和/或伯氨基。

8. 发明授权

US06476101B2 Method for producing pigment dispersing resin for cationic electrodeposition paint 有权
标题翻译：阳离子电沉积涂料用颜料分散树脂的制备方法
公开(公告)号：US06476101B2
公开(公告)日：2002-11-05
申请号：US09725754
申请日：2000-11-30
申请人： Masahiro Takegawa , Makoto Ando , Keisuke Tsutsui , Shinsuke Shirakawa , Mitsuo Yamada
发明人： Masahiro Takegawa , Makoto Ando , Keisuke Tsutsui , Shinsuke Shirakawa , Mitsuo Yamada
IPC分类号： C08K320
CPC分类号： C09D5/4457 , C09D7/45
摘要： To provide a method for producing a pigment dispersing resin varnish for cationic electrodeposition paint, wherein the flow properties and appearance of the resulting electrodeposition coating film are not compromised when using as a solvent a compound that is not volatilized into the atmosphere but remains in the electrodeposition coating film during the onium conversion of a pigment dispersing resin, as well as a cationic electrodeposition resin composition allowing HAPs to be eliminated and volatile organic carbon compounds to be reduced (VOC reduction). A method for producing a pigment dispersing resin varnish for use with cationic electrodeposition paint, wherein a solvent comprising a polyalkylene oxide compound represented by the following formula is used to produce a resin varnish which has been obtained from a cationic epoxy resin composition having amino groups, phosphonium groups, or sulfonium groups. (where R is an ethylene group or propylene group; Ph is a phenylene group; and both n and m are a number of 1 or more).
摘要翻译：为了提供一种阳离子电沉积涂料用颜料分散树脂清漆的制造方法，其特征在于，使用未挥发于大气中而残留在电沉积中的化合物作为溶剂时，不影响所得电沉积涂膜的流动性和外观在颜料分散树脂的鎓转化期间的涂膜以及允许消除HAP的阳离子电沉积树脂组合物和挥发性有机碳化合物的还原（VOC还原）。一种生产用于阳离子电沉积涂料的颜料分散树脂清漆的方法，其中使用包含由下式表示的聚环氧烷化合物的溶剂来制备由具有氨基的阳离子型环氧树脂组合物获得的树脂清漆，鏻基或锍基（其中R是亚乙基或亚丙基; Ph是亚苯基; n和m都是1以上数）。

9. 发明授权

US06462106B2 Amino-polyether-modified epoxy and cationic electrodeposition paint composition containing the same 有权
标题翻译：氨基聚醚改性的环氧和阳离子电沉积涂料组合物含有
公开(公告)号：US06462106B2
公开(公告)日：2002-10-08
申请号：US09768245
申请日：2001-01-25
申请人： Shinsuke Shirakawa , Mitsuo Yamada
发明人： Shinsuke Shirakawa , Mitsuo Yamada
IPC分类号： C08K320
CPC分类号： C09D5/4434 , C08G18/581 , C08G18/8012 , C08G18/8064 , C08G18/8077 , C08G59/10 , C09D163/00 , C08L71/00
摘要： Disclosed is a novel amino-polyether-modified epoxy for an electrodeposition paint. The amin-polyether-modified epoxy compound is obtained by reacting amino polyether represented by a formula as follow: wherein m is an integer of 5 or more, R is hydrogen, methyl group or ethyl group, and n is 2 or 3, with polyglycidyl ether having a molecular weight of 1,000 to 7,000 and an epoxy equivalent of 500 to 3,500, wherein an equivalent ratio of a primary amino group of the amino polyether to an epoxy group of the polyglycidyl ether is controlled within the range of 0.52 to 1.0.
摘要翻译：公开了用于电沉积涂料的新型氨基 - 聚醚改性环氧树脂。氨基 - 聚醚改性的环氧化合物是通过使由下式表示的氨基聚醚反应得到：其中m为5以上的整数，R为氢，甲基或乙基，n为2或3，与聚缩水甘油基醚，其分子量为1,000〜7000，环氧当量为500〜3,500，其中氨基聚醚的伯氨基与聚缩水甘油醚的环氧基的当量比控制在0.52〜1.0的范围内。

10. 发明授权

US5340931A Aromatic allene compounds of the formula (CH.sub.2 .dbd.CH--O).sub.n --R--(A.sub.m in which R is an aromatic group and preparation thereof 失效
标题翻译：其中R为芳族基团的式（CH2 = CH-O）n-R-（A）m的芳香族烯化合物及其制备方法
公开(公告)号：US5340931A
公开(公告)日：1994-08-23
申请号：US323786
申请日：1989-03-15
申请人： Mitsuo Yamada , Hiromichi Kayano , Kei Aoki , Keizou Ishii
发明人： Mitsuo Yamada , Hiromichi Kayano , Kei Aoki , Keizou Ishii
IPC分类号： C07C43/215 , C07C43/225 , C07C59/68 , C07C65/28 , C07C245/08 , C07C309/42 , C07C309/43 , C07C41/18 , C07C41/32
CPC分类号： C07C43/215 , C07C245/08 , C07C309/42 , C07C309/43 , C07C43/225 , C07C59/68 , C07C65/28 , C07C2101/14 , C07C2103/24
摘要： Allene compounds have the formula:(CH.sub.2 .dbd.C.dbd.CH--O).sub.n --R--(A).sub.m (I)in which R is a substituted or unsubstituted mono- or polyvalent benzene, naphthalene, anthracene, azobenzene, bisphenol or polyphenyl (containing 2 to 10 benzene rings connected in line) nucleus, or a group--Ph--R.sup.1 --Ph-- (II)(in which each group Ph is a phenylene, halophenylene, alkylphenylene, cyanophenylene or alkoxyphenylene group, and the chain R.sup.1 linking the two group Ph is a C.sub.1 -C.sub.6 aliphatic hydrocarbon or an alicyclic hydrocarbon group, the chain optionally being interrupted by one or more oxygen atoms); A is a carboxyl or sulphonyl group or a group --CH.dbd.C.dbd.CH.sub.2 ; n is an integer of from 1 to 10; m is 0, 1, 2 or 3; and the sum of m and n is equal to the valence of the group R.They may be prepared by isomerization of corresponding propargyloxy compounds.
摘要翻译：烯化合物具有下式：（CH 2 = C = CH-O）nR-（A）m（I）其中R是取代或未取代的单或多价苯，萘，蒽，偶氮苯，双酚或多苯基（含2 至10个苯环），或基团-Ph-R1-Ph-（Ⅱ）（其中各基团Ph为亚苯基，卤代亚苯基，烷基亚苯基，氰基亚苯基或烷氧基亚苯基，连接两个基团的链R1 Ph是C1-C6脂族烃或脂环烃基，任选被一个或多个氧原子间隔的链）; A是羧基或磺酰基或基团-CH = C = CH 2; n为1〜10的整数， m为0,1,2或3; 并且m和n的总和等于基团R的化合价。它们可以通过相应的炔丙氧基化合物的异构化来制备。

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