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    • 1. 发明授权
    • Production of dielectric ceramic material powder
    • 电介质陶瓷材料粉末的生产
    • US5554571A
    • 1996-09-10
    • US538335
    • 1995-10-03
    • Shinsei OkabeSakiko IwamotoHarunobu Sano
    • Shinsei OkabeSakiko IwamotoHarunobu Sano
    • C01G25/00C01G27/00C04B35/49C04B35/626
    • C01G27/006C01G25/006C04B35/49C04B35/626C01P2002/34
    • Powder of dielectric ceramic materials is produced by preparing a main component Ba(Ti.sub.1-x-y Zr.sub.x Hf.sub.y)O.sub.3 allowing barium hydroxide, at least one titanium compound, at least one zirconium compound and at least one hafnium compound to react with one another by condensation by catalytic actions of a base selected from the group consisting of alkali and amines; preparing a complex hydroxide of at least one rare earth element and manganese by allowing at least one rare earth element compound and a manganese compound to react with a base selected from the group consisting of alkali and amines in an aqueous solution; preparing at least one carbonate of calcium and magnesium by allowing at least one compound of calcium compounds and magnesium compounds to react with carbonate ions in an aqueous solution; mixing all the precipitates, and drying and thermally treating the resultant mixture.
    • 电介质陶瓷材料的粉末是通过制备主要成分Ba(Ti1-x-yZrxHfy)O3来制备的,所述主要组分Ba(Ti1-x-yZrxHfy)O3允许氢氧化钡,至少一种钛化合物,至少一种锆化合物和至少一种铪化合物彼此反应, 选自碱和胺的碱的催化作用; 通过在水溶液中使至少一种稀土元素化合物和锰化合物与选自碱和胺的碱反应来制备至少一种稀土元素和锰的复合氢氧化物; 通过使至少一种化合物的钙化合物和镁化合物与水溶液中的碳酸根离子反应来制备至少一种钙和镁的碳酸盐; 混合所有沉淀物,并干燥并热处理所得混合物。
    • 2. 发明授权
    • Dielectric ceramic composition
    • 介电陶瓷组合物
    • US5439857A
    • 1995-08-08
    • US268819
    • 1994-06-30
    • Sakiko IwamotoHarunobu SanoYukio HamajiKunisaburo Tomono
    • Sakiko IwamotoHarunobu SanoYukio HamajiKunisaburo Tomono
    • C04B35/499H01G4/12C04B35/26
    • C04B35/499H01G4/1254
    • A dielectric ceramic composition consists essentially of a main component of a four component system, Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3 --PbTiO.sub.3 --Pb(Ni.sub.1/3 Nb.sub.2/3)O.sub.3 --Pb(Zn.sub.1/2 W.sub.1/2)O.sub.3, of which a part of Pb is replaced with at least one substituent selected from the group consisting of Ba, Ca and Sr; and a secondary component selected from the group consisting of w, Zn and Mg. The secondary component is incorporated in the main component in an amount of 0.05 to 10.0 parts by weight per 100 parts by weight of the main component in terms of each oxide, WO.sub.3, ZnO or MgO. The main component consists essentially of 4.0 to 93.0 mol % of Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3, 1.5 to 35.0 mol % of PbTiO.sub.3, 1.5 to 51.0 mol % of Pb(Ni.sub.1/3 Nb.sub.2/3)O.sub.3, and 1.0 to 34.0 mol % of Pb(Zn.sub.1/2 W.sub.1/2)O.sub.3, the amount of at least one substituent for Pb being 0.1 to 10 mol %.
    • 电介质陶瓷组合物主要由四组分Pb(Mg1 / 3Nb2 / 3)O3-PbTiO3-Pb(Ni1 / 3Nb2 / 3)O3-Pb(Zn1 / 2W1 / 2)O3的主要成分组成,其中 一部分Pb被选自Ba,Ca和Sr中的至少一种取代基取代; 和选自由w,Zn和Mg组成的组的次要组分。 相对于每种氧化物WO 3,ZnO或MgO而言,以每100重量份主成分为0.05〜10.0重量份的次要成分。 主要成分基本上由Pb(Mg1 / 3Nb2 / 3)O3的4.0〜93.0mol%,PbTiO3的1.5〜35.0mol%,Pb(Ni1 / 3Nb2 / 3)O3的1.5〜51.0mol%,以及1.0〜34.0 Pb(Zn1 / 2W1 / 2)O3的摩尔%,Pb的至少一个取代基的量为0.1〜10摩尔%。