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    • 4. 发明授权
    • Heat-developable light-sensitive material
    • 可热成像的感光材料
    • US4030930A
    • 1977-06-21
    • US550503
    • 1975-02-18
    • Kenji SashiharaTakao MasudaYasuhiro NoguchiNobuyoshi SekikawaTadao Shishido
    • Kenji SashiharaTakao MasudaYasuhiro NoguchiNobuyoshi SekikawaTadao Shishido
    • G03C1/498G03C1/02G03C1/76
    • G03C1/49845
    • A heat-developable light-sensitive material comprising a support having thereon at least one layer containing (a) an organic silver salt oxidizing agent; (b) a catalytic amount of a light-sensitive silver halide or a compound capable of forming a light-sensitive silver halide through reaction with the organic silver salt component (a); (c) a reducing agent; and (d) at least one compound represented by the following general formulae (I) to (III) ##STR1## in which A and B each represents different substituents selected from the group consisting of an amino group and a --OX group; X represents a hydrogen atom, an alkali metal atom, a silver atom, a mercury atom or a gold atom; R.sub.1 and R.sub.2 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aralkyl group, an allyl group, an acyl group, an aryl group or an aryloxy group; and R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom or an alkyl group.
    • 一种可热显影的感光材料,其包括其上具有至少一层的载体,所述层包含(a)有机银盐氧化剂; (b)催化量的感光卤化银或能够通过与有机银盐组分(a)反应形成感光卤化银的化合物; (c)还原剂; 其中A和B各自表示选自以下通式(I)至(III)中的至少一种化合物:其中A和B各自表示不同的取代基, 由氨基和-OX基组成的组; X表示氢原子,碱金属原子,银原子,汞原子或金原子; R1和R2各自表示氢原子,卤素原子,烷基,烷氧基,芳烷基,烯丙基,酰基,芳基或芳氧基; 并且R 3,R 4和R 5各自表示氢原子,卤素原子或烷基。
    • 7. 发明授权
    • Thermally developable light-sensitive material
    • 耐热可开发的感光材料
    • US4140532A
    • 1979-02-20
    • US860652
    • 1977-12-14
    • Hideo SatoNobuyoshi SekikawaToshinao UkaiTakao Masuda
    • Hideo SatoNobuyoshi SekikawaToshinao UkaiTakao Masuda
    • G03C1/06G03C1/498G03C1/02
    • G03C1/49845Y10S430/166
    • A thermally developable light-sensitive material comprising a support and containing at least (a) an organic silver salt, (b) a photocatalyst, (c) a reducing agent and (d) a color toning agent in the support or in at least one layer provided on the support, wherein the color toning agent is at least one 2H-1,3-benzothiazin-2,4(3H)-dione, e.g., having the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, a hydroxy group, an acyloxy group, a nitro group, an amino group, an alkyl-substituted amino group, an aryl-substituted amino group, an acylamino group, an acyl group, a hydroxycarbonyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, an alkyl-substituted sulfamoyl group, an aryl-substituted sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group or a sulfo group, further, R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, and/or R.sub.3 and R.sub.4, may combine and represent the atoms necessary to form a condensed aromatic ring; and, further, one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be a monovalent residue of the general formula (I), in which the color toning effect is retained even under conditions of high temperature and/or high humidity.
    • 一种可热显影的感光材料,其包括载体并且至少包含(a)有机银盐,(b)光催化剂,(c)还原剂和(d)载体中的至少一种颜色调色剂 层,其中色调剂是至少一种2H-1,3-苯并噻嗪-2,4(3H) - 二酮,例如具有以下通式(I):其中 R 1,R 2,R 3和R 4可以相同或不同,表示氢原子,卤素原子,烷基,环烷基,芳基,烷氧基,芳氧基,烷硫基, 羟基,酰氧基,硝基,氨基,烷基取代的氨基,芳基取代的氨基,酰氨基,酰基,羟基羰基,烷氧基羰基,芳氧基羰基, 氨磺酰基,烷基取代的氨磺酰基,芳基取代的氨磺酰基,烷基磺酰基,芳基磺酰基 p或磺基,此外,R 1和R 2,R 2和R 3和/或R 3和R 4可以组合并表示形成稠合芳环所必需的原子; 此外,R 1,R 2,R 3和R 4中的一个可以是通式(I)的一价残基,即使在高温和/或高湿度的条件下也保持着色调色效果。
    • 9. 发明授权
    • Heat-developable light-sensitive materials using the reaction product of
a organic silver salt an a N-halo-oxazolidinone
    • 使用有机银盐和N-卤代恶唑烷酮的反应产物的热显影光敏材料
    • US4003749A
    • 1977-01-18
    • US596130
    • 1975-07-15
    • Takao MasudaNobuyoshi Sekikawa
    • Takao MasudaNobuyoshi Sekikawa
    • G03C1/498G03C1/02G03C1/34
    • G03C1/49818
    • A heat-developable light-sensitive material comprising a support having therein or in one or more layers thereon an organic silver (b) a light-sensitive silver halide, and (c) a reducing agent, with the light-sensitive silver halide comprising the reaction product of a part of the organic silver salt and an N-halo compound represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each is a hydrogen atom; an alkyl group having 1 to 22 carbon atoms; a haloalkyl group having 1 to 22 carbon atoms; an amino group; a hydroxyalkyl group having 1 to 22 carbon atoms; an allyl group; a naphthyl group; a benzyl group; a ##STR2## group in which R.sub.5 is a hydrogen atom, a halogen atom, an alkyl group, an alkylthio group, an amino group or an alkylamino group; a benzyloxy group; an aryl group; a haloaryl group; an alkylaryl group; and alkoxyaryl group; an --OR.sub.6 group in which R.sub.6 is a hydrogen atom, an alkyl group, an allyl group, an aryl group or an alkoxyaryl group; a ##STR3## group in which R.sub.7 and R.sub.8 each is a hydrogen atom, an alkyl group, an aryl group or an allyl group; a cyclohexyl group; a --CH.sub.2 OR.sub.9 group in which R.sub.9 is a naphthyl group; or a --CH.sub.2 R.sub.10 in which R.sub.10 is a morpholino group, a piperadino group or an alkylthio group; and X is a chlorine atom or a bromine atom.
    • 一种可热显影的感光材料,其包含其中具有支撑体或其一个或多个层上的有机银(b)感光卤化银,和(c)还原剂,所述感光卤化银包含 有机银盐的一部分的反应产物和由下式(I)表示的N-卤素化合物:其中R1,R2,R3和R4各自为氢原子; 具有1至22个碳原子的烷基; 具有1至22个碳原子的卤代烷基; 氨基; 具有1至22个碳原子的羟烷基; 烯丙基; 萘基; 苄基; R5是氢原子,卤素原子,烷基,烷硫基,氨基或烷基氨基的基团; 苄氧基; 芳基; 卤代芳基; 烷基芳基; 和烷氧基芳基; 其中R6为氢原子,烷基,烯丙基,芳基或烷氧基芳基的-OR6基团; R7和R8各自为氢原子,烷基,芳基或烯丙基的基团; 环己基; 其中R9为萘基的-CH2OR9基团; 或其中R 10为吗啉代基,哌嗪基或烷硫基的-CH 2 R 10; X为氯原子或溴原子。
    • 10. 发明授权
    • Thermally developable light-sensitive material with a benzoic acid
    • 具有苯甲酸的可热显影的感光材料
    • US4152160A
    • 1979-05-01
    • US893747
    • 1978-04-05
    • Shinpei IkienoueTakao MasudaNobuyoshi Sekikawa
    • Shinpei IkienoueTakao MasudaNobuyoshi Sekikawa
    • G03C1/498G03C1/92G03C1/00G03C1/34G03C1/72
    • G03C1/49854
    • A thermally developable light-sensitive material with improved storage stability and a minimized thermal fog without an increase in both light discoloration and dark discoloration which comprises a support and having therein or in at least one layer thereon at least (a) an organic carboxylic acid silver salt comprising about 50 mol% or more of silver behenate, (b) a photocatalyst and (c) a reducing agent, and with the material containing (d) at least one compound (1) represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents a hydrogen atom or a substituent selected from the group consisting of a nitro group, a cyano group and a halogen atom, with the proviso that R.sub.1, R.sub.2 and R.sub.3 are not all simultaneously a hydrogen atom, and (2) having a half-neutralization point of from about 40 mV to about 140 mV above the half-neutralization point of benzoic acid in isopropanol.
    • 具有改善的储存稳定性和最小化的热雾的热可显影的感光材料,而不增加光的变色和暗色变色,其包括载体并且在其中或至少一层中至少包含一种有机羧酸银 包含约50mol%或更多的山嵛酸银的盐,(b)光催化剂和(c)还原剂,以及含有(d)至少一种由以下通式(I)表示的化合物(1)的材料: (I)其中可以相同或不同的R 1,R 2和R 3各自表示氢原子或选自硝基,氰基和卤素原子的取代基,条件是 R1,R2和R3不全部同时为氢原子,和(2)在异丙醇中苯甲酸的半中和点以上的半中和点为约40mV至约140mV。