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1. 发明授权

US09375877B2 Method for manufacturing polyimide metal laminate 有权
标题翻译：聚酰亚胺金属层压板的制造方法
公开(公告)号：US09375877B2
公开(公告)日：2016-06-28
申请号：US14238071
申请日：2012-08-10
申请人： Shin-ichiro Kohama , Nobuharu Hisano , Taizou Murakami , Kosuke Oishi , Hiroaki Yamaguchi
发明人： Shin-ichiro Kohama , Nobuharu Hisano , Taizou Murakami , Kosuke Oishi , Hiroaki Yamaguchi
IPC分类号： B29C65/02 , B29C65/00 , B32B15/08 , C08G73/10 , B32B27/28
CPC分类号： B29C66/742 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/281 , B32B2255/10 , B32B2255/26 , B32B2264/10 , B32B2307/20 , B32B2307/306 , B32B2307/50 , B32B2307/714 , B32B2307/734 , B32B2457/00 , B32B2457/08 , B32B2457/14 , C08G73/1085
摘要： A method for manufacturing a polyimide-metal laminate including forming a polyimide film, in which at least surfaces of both sides of the film are formed by thermally fusion-bondable polyimide layers (a), and thermal compression-bonding metal layers on both sides of the polyimide film; in which forming the polyimide film includes reacting a tetracarboxylic dianhydride component with a diamine component containing a diamine compound represented by general formula (1) to give a solution of a polyamic acid (a), forming a self-supporting film from the solution of the polyamic acid (a) and imidizing the self-supporting film by heating at a maximum heating temperature of 440° C. or lower to form the polyimide layer (a); in which R1 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms; and R2 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms.
摘要翻译：一种制造聚酰亚胺 - 金属层压体的方法，包括形成聚酰亚胺膜，其中至少通过可热熔融粘合的聚酰亚胺层（a）形成膜的两侧表面，并且在两侧形成热压接金属层聚酰亚胺膜; 其中形成聚酰亚胺膜包括使四羧酸二酐组分与含有由通式（1）表示的二胺化合物的二胺组分反应，得到聚酰胺酸（a）的溶液，从该溶液中形成自支撑膜聚酰胺酸（a），通过在最高加热温度440℃以下加热而使自支撑膜酰亚胺化以形成聚酰亚胺层（a）; 其中R1表示氢或具有1至12个碳原子的烷基或芳基; 并且R 2表示氢或具有1至12个碳原子的烷基或芳基。

2. 发明申请

US20140290853A1 METHOD FOR MANUFACTURING POLYIMIDE METAL LAMINATE 有权
标题翻译：制备聚酰亚胺金属层压板的方法
公开(公告)号：US20140290853A1
公开(公告)日：2014-10-02
申请号：US14238071
申请日：2012-08-10
申请人： Shin-ichiro Kohama , Nobuharu Hisano , Taizou Murakami , Kosuke Oishi , Hiroaki Yamaguchi
发明人： Shin-ichiro Kohama , Nobuharu Hisano , Taizou Murakami , Kosuke Oishi , Hiroaki Yamaguchi
IPC分类号： B29C65/00
CPC分类号： B29C66/742 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/281 , B32B2255/10 , B32B2255/26 , B32B2264/10 , B32B2307/20 , B32B2307/306 , B32B2307/50 , B32B2307/714 , B32B2307/734 , B32B2457/00 , B32B2457/08 , B32B2457/14 , C08G73/1085
摘要： A method for manufacturing a polyimide-metal laminate including forming a polyimide film, in which at least surfaces of both sides of the film are formed by thermally fusion-bondable polyimide layers (a), and thermal compression-bonding metal layers on both sides of the polyimide film; in which forming the polyimide film includes reacting a tetracarboxylic dianhydride component with a diamine component containing a diamine compound represented by general formula (1) to give a solution of a polyamic acid (a), forming a self-supporting film from the solution of the polyamic acid (a) and imidizing the self-supporting film by heating at a maximum heating temperature of 440° C. or lower to form the polyimide layer (a); in which R1 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms; and R2 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms.
摘要翻译：一种制造聚酰亚胺 - 金属层压体的方法，包括形成聚酰亚胺膜，其中至少通过可热熔融粘合的聚酰亚胺层（a）形成膜的两侧表面，并且在两侧形成热压接金属层聚酰亚胺膜; 其中形成聚酰亚胺膜包括使四羧酸二酐组分与含有由通式（1）表示的二胺化合物的二胺组分反应，得到聚酰胺酸（a）的溶液，从该溶液中形成自支撑膜聚酰胺酸（a），通过在最高加热温度440℃以下加热而使自支撑膜酰亚胺化以形成聚酰亚胺层（a）; 其中R1表示氢或具有1至12个碳原子的烷基或芳基; 并且R 2表示氢或具有1至12个碳原子的烷基或芳基。

3. 发明授权

US09511565B2 Polyimide precursor, polyimide, polyimide film, and method for manufacturing triazine compound used for manufacturing same 有权
标题翻译：聚酰亚胺前体，聚酰亚胺，聚酰亚胺膜及其制造用的三嗪化合物的制造方法
公开(公告)号：US09511565B2
公开(公告)日：2016-12-06
申请号：US14237976
申请日：2012-08-10
申请人： Yoshiyuki Oishi , Nobuharu Hisano , Shin-ichiro Kohama , Taizou Murakami , Hiroaki Yamaguchi
发明人： Yoshiyuki Oishi , Nobuharu Hisano , Shin-ichiro Kohama , Taizou Murakami , Hiroaki Yamaguchi
IPC分类号： B32B15/08 , B32B7/12 , C07D251/54 , C07D251/70 , C08G73/10 , B32B27/28 , B32B15/088 , C08G69/26 , B32B15/20 , B32B27/18 , C08G73/06
摘要： A polyimide precursor for obtaining a polyimide film having excellent adhesiveness to metals and improved transmittance in the UV-visible range, a polyimide in which the polyimide precursor is used, a polyimide film in which the polyimide is used, and a method for manufacturing a triazine compound used for manufacturing the polyimide precursor, polyimide film and polyimide.
摘要翻译：一种聚酰亚胺前体，用于获得具有优异的金属密合性和在UV可见范围内提高的透射率的聚酰亚胺膜，使用聚酰亚胺前体的聚酰亚胺，其中使用聚酰亚胺的聚酰亚胺膜，以及三嗪的制造方法用于制造聚酰亚胺前体，聚酰亚胺膜和聚酰亚胺的化合物。

4. 发明申请

US20120244352A1 PROCESS FOR PRODUCING POLYIMIDE FILM, AND POLYIMIDE FILM 审中-公开
标题翻译：生产聚酰亚胺膜的方法和聚酰亚胺膜
公开(公告)号：US20120244352A1
公开(公告)日：2012-09-27
申请号：US13514756
申请日：2010-12-08
申请人： Nobuharu Hisano , Shin-ichiro Kohama , Taizou Murakami , Hiroaki Yamaguchi
发明人： Nobuharu Hisano , Shin-ichiro Kohama , Taizou Murakami , Hiroaki Yamaguchi
IPC分类号： C08G73/10 , B32B37/24 , B29C39/00 , B32B15/08 , C09J7/02
CPC分类号： B32B15/08 , Y10T428/2896 , Y10T428/31681
摘要： A polyimide film having improved adhesiveness is produced by flow-casting a solution of a polyamic acid, which is prepared by reacting a tetracarboxylic acid component and a diamine component, on a support, and drying the solution to form a self-supporting film; applying a solution containing a surface treatment agent to one side or both sides of the self-supporting film, wherein the solvent of the surface treatment agent solution is a water-soluble liquid and has a surface tension of 32 mN/m or less at 20° C. and a boiling point of 125° C. or higher; and heating the self-supporting film to provide a polyimide film.
摘要翻译：通过将通过四羧酸成分和二胺成分反应制备的聚酰胺酸溶液流延在载体上，干燥该溶液以形成自支撑膜，从而制造具有改善粘合性的聚酰亚胺膜; 将含有表面处理剂的溶液涂布在自支撑膜的一侧或两侧，其中表面处理剂溶液的溶剂为水溶性液体，并且在20℃下的表面张力为32mN / m以下 ℃，沸点125℃以上; 并加热自支撑膜以提供聚酰亚胺膜。

5. 发明申请

US20120308816A1 POLYIMIDE FILM, POLYIMIDE LAMINATE COMPRISING SAME, AND POLYIMIDE/METAL LAMINATE COMPRISING SAME 审中-公开
标题翻译：聚酰亚胺膜，包含该聚酰亚胺膜的聚酰亚胺层压体和包含其的聚酰亚胺/金属层压板
公开(公告)号：US20120308816A1
公开(公告)日：2012-12-06
申请号：US13577900
申请日：2011-02-10
申请人： Shin-ichiro Kohama , Nobuharu Hisano , Hiroaki Yamaguchi , Yoshiyuki Oishi , Toru Miura , Tadahiro Yokozawa , Masafumi Kohda , Kosuke Oishi
发明人： Shin-ichiro Kohama , Nobuharu Hisano , Hiroaki Yamaguchi , Yoshiyuki Oishi , Toru Miura , Tadahiro Yokozawa , Masafumi Kohda , Kosuke Oishi
IPC分类号： B32B27/06 , B32B15/08 , B29C39/00 , B32B7/12
CPC分类号： B32B15/08 , B32B7/12 , B32B15/088 , B32B27/06 , B32B27/28 , B32B27/34 , B32B2379/08 , B32B2457/202 , C08G73/0273 , C08G73/0644 , C08G73/1085 , C08J5/128 , C08J2379/08 , C08J2479/08 , C09D179/08 , H05K1/0346 , Y10T428/2848 , Y10T428/31678 , Y10T428/31681 , Y10T428/31721
摘要： Disclosed is a polyimide film having improved adhesiveness to an adhesive and/or adherence to a metal layer. The polyimide film has at least a polyimide layer (b) and a polyimide layer (a) formed contacting the polyimide layer (b), wherein the polyimide layer (a) is a polyimide formed from a tetracarboxylic dianhydride component and a diamine component containing a diamine compound represented by general formula (1): wherein R1 denotes a hydrogen atom, an alkyl group having 1 to 12 carbon atoms or an aryl group, and R2 denotes an alkyl group having 1 to 12 carbon atoms or an aryl group.
摘要翻译：公开了具有改进的粘合剂粘附性和/或与金属层的粘附性的聚酰亚胺膜。聚酰亚胺膜至少具有聚酰亚胺层（b）和与聚酰亚胺层（b）接触形成的聚酰亚胺层（a），其中聚酰亚胺层（a）是由四羧酸二酐组分形成的聚酰亚胺和含有由通式（1）表示的二胺化合物：其中R1表示氢原子，具有1至12个碳原子的烷基或芳基，R2表示具有1至12个碳原子的烷基或芳基。

6. 发明授权

US09393720B2 Polyimide film and process for producing polyimide film 有权
标题翻译：聚酰亚胺膜及其制造方法
公开(公告)号：US09393720B2
公开(公告)日：2016-07-19
申请号：US13391011
申请日：2010-08-18
申请人： Nobuharu Hisano , Taizou Murakami , Masafumi Kohda , Hiroaki Yamaguchi
发明人： Nobuharu Hisano , Taizou Murakami , Masafumi Kohda , Hiroaki Yamaguchi
IPC分类号： B29C39/14 , B29C41/24 , C08G73/10 , C08J7/02 , B29C71/02 , C08L79/08 , H05K3/38 , B29K79/00 , H05K1/03
CPC分类号： B29C41/24 , B29K2079/08 , C08G73/1067 , C08J7/02 , C08J7/08 , C08L79/08 , H05K1/0346 , H05K3/381 , H05K2201/0154 , H05K2203/0793 , Y10T428/28
摘要： A polyimide film, which is produced by the reaction of a tetracarboxylic acid component comprising 3,3′,4,4′-biphenyltetracarboxylic dianhydride as the main component and a diamine component comprising p-phenylenediamine as the main component, is heated at a temperature of from 460° C. to 550° C., and then water or an alkaline aqueous solution is sprayed on a surface of the polyimide film for surface treatment, thereby improving adhesiveness, while maintaining the excellent properties inherent in the polyimide film.
摘要翻译：通过以3,3'，4,4'-联苯四羧酸二酐为主要成分的四羧酸组分与以对苯二胺为主要成分的二胺组分的反应制得的聚酰亚胺薄膜在温度为460℃〜550℃，然后将水或碱性水溶液喷涂在聚酰亚胺膜的表面进行表面处理，从而提高粘合性，同时保持聚酰亚胺膜固有的优异性能。

7. 发明申请

US20120156482A1 POLYMIDE FILM AND PROCESS FOR PRODUCING POLYIMIDE FILM 有权
标题翻译：聚酰亚胺薄膜和生产聚酰亚胺薄膜的方法
公开(公告)号：US20120156482A1
公开(公告)日：2012-06-21
申请号：US13391011
申请日：2010-08-18
申请人： Nobuharu Hisano , Taizou Murakami , Masafumi Kohda , Hiroaki Yamaguchi
发明人： Nobuharu Hisano , Taizou Murakami , Masafumi Kohda , Hiroaki Yamaguchi
IPC分类号： B32B7/12 , C08G69/32 , B29D7/00
CPC分类号： B29C41/24 , B29K2079/08 , C08G73/1067 , C08J7/02 , C08J7/08 , C08L79/08 , H05K1/0346 , H05K3/381 , H05K2201/0154 , H05K2203/0793 , Y10T428/28
摘要： A polyimide film, which is produced by the reaction of a tetracarboxylic acid component comprising 3,3′,4,4′-biphenyltetracarboxylic dianhydride as the main component and a diamine component comprising p-phenylenediamine as the main component, is heated at a temperature of from 460° C. to 550° C., and then water or an alkaline aqueous solution is sprayed on a surface of the polyimide film for surface treatment, thereby improving adhesiveness, while maintaining the excellent properties inherent in the polyimide film.
摘要翻译：通过以3,3'，4,4'-联苯四羧酸二酐为主要成分的四羧酸组分与以对苯二胺为主要成分的二胺组分的反应制得的聚酰亚胺薄膜在温度为460℃〜550℃，然后将水或碱性水溶液喷涂在聚酰亚胺膜的表面进行表面处理，从而提高粘合性，同时保持聚酰亚胺膜固有的优异性能。

8. 发明申请

US20100041860A1 POLYIMIDE, DIAMINE COMPOUND AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：聚酰亚胺，DIAMINE化合物及其生产方法
公开(公告)号：US20100041860A1
公开(公告)日：2010-02-18
申请号：US12514437
申请日：2007-11-12
申请人： Hiroaki Yamaguchi , Shuichi Maeda , Nobuharu Hisano , Shinsuke Yabunaka , Kiyotaka Yoshii , Masayoshi Ohue , Akio Matsushita , Yasuhiro Kawachi
发明人： Hiroaki Yamaguchi , Shuichi Maeda , Nobuharu Hisano , Shinsuke Yabunaka , Kiyotaka Yoshii , Masayoshi Ohue , Akio Matsushita , Yasuhiro Kawachi
IPC分类号： C08G69/26 , C07C229/52
CPC分类号： C08G73/16 , C07C219/34 , C07D277/16 , C08G73/1042 , C08G73/1046 , C08G73/1053 , C08G73/1067 , C08G73/1071 , C08L79/08 , H05K1/0346 , H05K1/0393
摘要： A polyimide obtained by reacting a tetracarboxylic acid component with a diamine component containing a diamine compound represented by the following general formula (1): wherein, A represents a biphenylene group which may be substituted with an alkyl group having up to 4 carbon atoms.
摘要翻译：通过使四羧酸成分与含有下述通式（1）表示的二胺化合物的二胺成分反应得到的聚酰亚胺：其中，A表示可被至多具有4个碳原子的烷基取代的亚联苯基。

9. 发明申请

US20090197068A1 POLYIMIDE FILM, AND METHOD FOR PRODUCTION THEREOF 审中-公开
标题翻译：聚酰亚胺膜及其生产方法
公开(公告)号：US20090197068A1
公开(公告)日：2009-08-06
申请号：US12363546
申请日：2009-01-30
申请人： Hiroaki Yamaguchi , Masafumi Kohda , Nobuharu Hisano , Shinsuke Yabunaka
发明人： Hiroaki Yamaguchi , Masafumi Kohda , Nobuharu Hisano , Shinsuke Yabunaka
IPC分类号： C08G69/26 , B32B15/08 , B28B1/14
CPC分类号： H05K1/0346 , B32B7/12 , B32B15/08 , B32B15/20 , B32B27/16 , B32B27/281 , B32B2307/20 , B32B2307/306 , B32B2307/50 , B32B2307/54 , B32B2307/714 , B32B2307/724 , B32B2307/734 , B32B2457/00 , B32B2457/04 , B32B2457/08 , B32B2457/12 , C08G73/1042 , C08G73/1067 , C08L79/08 , H05K2201/0154 , Y10T428/31681
摘要： Disclosed is a polyimide film prepared from an aromatic tetracarboxylic acid component consisting essentially of 3,3′,4,4′-biphenyltetracarboxylic dianhydride and an aromatic diamine component consisting essentially of not less than 65 mol phenylenediamine % but less than 97 mol % of p-phenylenediamine and not less than 3 mol % but less than 35 mol % of 2,4-toluenediamine.
摘要翻译：公开了由基本上由3,3'，4,4'-联苯四羧酸二酐组成的芳族四羧酸组分和基本上由不低于65mol的苯二胺％但小于97mol％的p组成的芳族二胺组分制备的聚酰亚胺膜苯二胺，不小于3摩尔％但小于35摩尔％的2,4-甲苯二胺。

10. 发明授权

US09090355B2 Composite tank, wing, and method for manufacturing composite tank 有权
标题翻译：复合罐，翼，及复合罐制造方法
公开(公告)号：US09090355B2
公开(公告)日：2015-07-28
申请号：US13258179
申请日：2010-03-17
申请人： Hiroaki Yamaguchi , Yuichiro Kamino , Koichi Nakamura , Tooru Hashigami
发明人： Hiroaki Yamaguchi , Yuichiro Kamino , Koichi Nakamura , Tooru Hashigami
IPC分类号： B64D15/04 , B64D37/06 , B64C3/34 , B64D37/32
CPC分类号： B64D37/06 , B64C3/34 , B64D37/32 , Y02T50/44
摘要： A composite tank that can suppress electrification, corrosion and strength degradation, a wing comprising the composite tank, and a method for manufacturing the composite tank. The composite tank comprises: a tank body inside which a combustible material is stored, having a first resin portion (11, 12) formed from a fiber reinforced resin and a metal portion formed from a metal material, a second resin portion (22) formed from a fiber reinforced resin, which covers at least those regions on the inner surface of the tank body where the first resin portion (11, 12) adjoins the metal portion, and a plurality of conductive portions (23) that enable charge transfer through the second resin portion (22), from the surface that contacts the combustible material to the first resin portion (11, 12), wherein the fiber in the second resin portion (22) has a higher electrical resistivity than fiber in the first resin portion (11, 12), and the second resin portion (22) forms a layer that isolates the first resin portion (11, 12) from the metal portion.
摘要翻译：可抑制带电，腐蚀和强度降低的复合罐，包括复合罐的翼，以及制造复合罐的方法。复合罐包括：储存有可燃材料的罐体，具有由纤维增强树脂形成的第一树脂部分（11,12）和由金属材料形成的金属部分，形成第二树脂部分（22）至少覆盖在第一树脂部分（11,12）与金属部分相邻的罐体内表面上的那些区域的多个导电部分（23），所述多个导电部分（23）能够通过第二树脂部分（22）从与可燃材料接触的表面到第一树脂部分（11,12），其中第二树脂部分（22）中的纤维具有比第一树脂部分中的纤维更高的电阻率 11,12），第二树脂部（22）形成使第一树脂部（11,12）与金属部分隔离的层。

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