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    • 2. 发明申请
    • Retardation film and polyester resin for optical use
    • 用于光学用途的延迟膜和聚酯树脂
    • US20090207490A1
    • 2009-08-20
    • US11920777
    • 2006-05-23
    • Hideki MoriyamaShigetoshi MaekawaJun SakamotoAkimitsu TsukudaMasahiro KimuraRisa Taniguchi
    • Hideki MoriyamaShigetoshi MaekawaJun SakamotoAkimitsu TsukudaMasahiro KimuraRisa Taniguchi
    • G02B1/08G02B5/30C08K5/5317
    • C08J5/18C08G63/199C08G63/553C08G63/672C08J2367/00G02B5/3025
    • The present invention relates to a retardation film using polyester having a photoelastic coefficient of −40×10−12 Pa−1 to 40×10−12 Pa−1. The present invention also relates to a polyester resin for optical use which contains a phosphorus compound, and an alicyclic component and a fluorene derivative component as constituents, and satisfies the following equations (6) and (7): 100° C.≦glass transition temperature≦150° C.  (6) and 1.0≦(Ma/2+Mb+Mc)/P≦5.0  (7), wherein Ma is the number of moles of an alkali metal element contained in 1 ton of the polyester resin, Mb is the number of moles of an alkaline earth metal element contained in 1 ton of the polyester resin, Mc is the sum of the number of moles of a zinc element (Zn), a cobalt element (Co) and a manganese element (Mn) contained in 1 ton of the polyester resin, and P is the number of moles of a phosphorus element contained in 1 ton of the polyester resin.
    • 本发明涉及使用光弹性系数为-40×10-12Pa-1〜40×10-12Pa-1的聚酯的延迟膜。 本发明还涉及含有磷化合物,脂环族成分和芴衍生物成分作为成分的光学用聚酯树脂,并且满足下列等式(6)和(7):<?在线式 描述=“在线公式”end =“lead”?> 100°C <=玻璃化转变温度<= 150°C(6)<?in-line-formula description =“In-line Formulas”end = “tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?>和<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?> 1.0 <=(Ma / 2 + Mb + Mc)/ P <= 5.0(7) description =“In-line Formulas”end =“tail”?>其中Ma是1吨聚酯树脂中含有的碱金属元素的摩尔数,Mb是包含在碱性金属元素中的碱金属元素的摩尔数 1吨聚酯树脂,Mc是锌元素(Zn),钴元素(Co)和人的摩尔数之和 1吨聚酯树脂中含有的甘油元素(Mn),P是1吨聚酯树脂中含有的磷元素的摩尔数。
    • 8. 发明授权
    • Biaxially oriented thermoplastic resin film
    • 双轴取向热塑性树脂薄膜
    • US07384690B2
    • 2008-06-10
    • US10501041
    • 2003-01-08
    • Tetsuya MachidaShigetoshi MaekawaTakuji HigashiojiTetsuya Tsunekawa
    • Tetsuya MachidaShigetoshi MaekawaTakuji HigashiojiTetsuya Tsunekawa
    • B32B27/18B32B27/20B32B27/36B32B27/32B32B27/34
    • G11B5/733C08J5/18C08J2367/02H01G4/206H05K1/0373H05K1/0393H05K2201/0129H05K2201/0209Y10S428/91Y10T428/25Y10T428/256Y10T428/257Y10T428/268Y10T428/31507Y10T428/31721Y10T428/31728Y10T428/31786Y10T428/31855
    • In order to provide a film having excellent heat resistance, thermal dimensional stability, and mechanical properties, in particular, a film capable of satisfying required properties, e.g., higher strength in accordance with the reduction in thickness of a base film, improved thermal dimensional stability and mechanical properties in a use environment, and higher heat resistance and improved thermal dimensional stability in accordance with the needs for miniaturization and more functionality in electrical and electronic areas, a thermoplastic resin is allowed to contain transition metal oxide particles, and is formed into a biaxially oriented thermoplastic resin film, wherein the melting point of the film is allowed to become higher than the melting point of the thermoplastic resin to be used. Preferably, the difference between a peak temperature (melting point T1) of the heat of fusion in the first run of the measurement of the biaxially oriented thermoplastic resin film with a differential scanning calorimeter (DSC) and a peak temperature (melting point T2) of the heat of fusion in the second run is allowed to satisfy the following Formula. 2° C.≦T1-T2≦30° C. Alternatively, the plane orientation factor of the biaxially oriented thermoplastic resin film containing the transition metal oxide particles is controlled at 0.120 or more and less than 0.280.
    • 为了提供具有优异的耐热性,热尺寸稳定性和机械性能的膜,特别是能够满足所需性能的膜,例如根据底膜厚度的降低而具有更高的强度,改善的热尺寸稳定性 和使用环境中的机械性能,并且根据电气和电子领域中的小型化和更多功能性的需要,具有更高的耐热性和改进的热尺寸稳定性,允许热塑性树脂含有过渡金属氧化物颗粒,并形成为 双轴取向热塑性树脂膜,其中使所述膜的熔点变得高于所使用的热塑性树脂的熔点。 优选地,使用差示扫描量热计(DSC)进行的双轴取向热塑性树脂膜的测量的第一次运行中的熔化热的峰值温度(熔点T <1 <1>)与 允许第二次运行中的熔化热的峰值温度(熔点T 2 N 2)满足下式。 <?in-line-formula description =“In-line Formulas”end =“lead”?> 2°C <= T <1> 另外,将含有过渡金属氧化物粒子的双轴取向热塑性树脂膜的平面取向系数控制在0.120以上, 小于0.280。
    • 9. 发明申请
    • Biaxially oriented thermoplastic resin film
    • 双轴取向热塑性树脂薄膜
    • US20050020803A1
    • 2005-01-27
    • US10501041
    • 2003-01-08
    • Tetsuya MachidaShigetoshi MaekawaTakuji HigashiojiTetsuya Tsunekawa
    • Tetsuya MachidaShigetoshi MaekawaTakuji HigashiojiTetsuya Tsunekawa
    • C08J5/18H01G4/20H05K1/00H05K1/03C08G64/00C08G2/00
    • G11B5/733C08J5/18C08J2367/02H01G4/206H05K1/0373H05K1/0393H05K2201/0129H05K2201/0209Y10S428/91Y10T428/25Y10T428/256Y10T428/257Y10T428/268Y10T428/31507Y10T428/31721Y10T428/31728Y10T428/31786Y10T428/31855
    • In order to provide a film having excellent heat resistance, thermal dimensional stability, and mechanical properties, in particular, a film capable of satisfying required properties, e.g., higher strength in accordance with the reduction in thickness of a base film, improved thermal dimensional stability and mechanical properties in a use environment, and higher heat resistance and improved thermal dimensional stability in accordance with the needs for miniaturization and more functionality in electrical and electronic areas, a thermoplastic resin is allowed to contain transition metal oxide particles, and is formed into a biaxially oriented thermoplastic resin film, wherein the melting point of the film is allowed to become higher than the melting point of the thermoplastic resin to be used. Preferably, the difference between a peak temperature (melting point T1) of the heat of fusion in the first run of the measurement of the biaxially oriented thermoplastic resin film with a differential scanning calorimeter (DSC) and a peak temperature (melting point T2) of the heat of fusion in the second run is allowed to satisfy the following Formula. 2° C.≦T1−T2≦30° C. Alternatively, the plane orientation factor of the biaxially oriented thermoplastic resin film containing the transition metal oxide particles is controlled at 0.120 or more and less than 0.280.
    • 为了提供具有优异的耐热性,热尺寸稳定性和机械性能的膜,特别是能够满足所需性能的膜,例如根据底膜厚度的降低而具有更高的强度,改善的热尺寸稳定性 和使用环境中的机械性能,并且根据电气和电子领域中的小型化和更多功能性的需要,具有更高的耐热性和改进的热尺寸稳定性,允许热塑性树脂含有过渡金属氧化物颗粒,并形成为 双轴取向热塑性树脂膜,其中使所述膜的熔点变得高于所使用的热塑性树脂的熔点。 优选地,使用差示扫描量热计(DSC)测定第一次双轴取向热塑性树脂膜的测定中的熔融热的峰值温度(熔点T1)与峰温度(熔点T2)之间的差 允许第二次运行中的熔化热满足下式。 2℃。<= T1-T2 <= 30℃。 或者,将含有过渡金属氧化物粒子的双轴取向热塑性树脂膜的面取向系数控制在0.120以上且小于0.280。