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1. 发明申请

US20100105837A1 THERMOPLASTIC COMPOSITION AND MOLDED ARTICLE THEREOF 审中-公开
标题翻译：热塑性组合物及其制品
公开(公告)号：US20100105837A1
公开(公告)日：2010-04-29
申请号：US12530640
申请日：2008-03-25
申请人： Shigeru Sasaki , Katsunori Nitta
发明人： Shigeru Sasaki , Katsunori Nitta
IPC分类号： C08L53/02 , C08L53/00
CPC分类号： C08L53/025 , C08L23/02 , C08L23/10 , C08L23/12 , C08L25/06 , C08L53/02 , C08L71/12 , C08L2205/035 , C08L2666/02 , C08L2666/14 , C08L2666/04 , C08L2666/24
摘要： The present invention discloses a thermoplastic resin composition comprising: (A) 95 to 5 parts by weight of a styrenic resin and/or a polyphenylene ether resin; (B) 5 to 95 weight parts of an olefinic resin; and (C) 1 to 28 parts by weight of a partially hydrogenated block copolymer based on 100 parts by weight of the total amount of the components (A) and (B), wherein the component (C) comprises at least one polymer block X containing a vinyl aromatic compound as a main component and at least one polymer block Y containing a conjugated diene compound as a main component, a content of the vinyl aromatic compound in the component (C) is at least 10 wt % and at most 80 wt %, the vinyl bond content before hydrogenation in the component (C) is 3 wt % or more and less than 50 wt %, and 1 mol % or more and less than 40 mol % of double bonds derived from the conjugated diene compound in the block copolymer which constitutes the component (C) are hydrogenated.
摘要翻译：本发明公开了一种热塑性树脂组合物，其包含：（A）95〜5重量份的苯乙烯系树脂和/或聚苯醚树脂; （B）5〜95重量份的烯烃树脂; 和（C）基于100重量份的组分（A）和（B）的总量的1至28重量份的部分氢化嵌段共聚物，其中组分（C）包含至少一种聚合物嵌段X 含有乙烯基芳族化合物作为主要成分和至少一种含有共轭二烯化合物作为主要成分的聚合物嵌段Y，（C）成分中的乙烯基芳香族化合物的含量为10重量％以上80重量％以下％，成分（C）中氢化前的乙烯基键含量为衍生自共轭二烯化合物的双键的3重量％以上且小于50重量％，1摩尔％以上且小于40摩尔％构成组分（C）的嵌段共聚物被氢化。

2. 发明申请

US20090312449A1 HYDROGENATED BLOCK COPOLYMER, RESIN COMPOSITION COMPRISING THE HYDROGENATED BLOCK COPOLYMER, AND CROSSLINKED PRODUCT AND CROSSLINKED FOAMED PRODUCT THEREOF 审中-公开
标题翻译：加氢嵌段共聚物，包含氢化嵌段共聚物的树脂组合物和交联的产物和交联的发泡产品
公开(公告)号：US20090312449A1
公开(公告)日：2009-12-17
申请号：US12279325
申请日：2007-02-07
申请人： Shigeru Sasaki , Katsunori Nitta , Yoshifumi Araki , Jung Sik Yoon , Gi Yong Um , Chong Sun Yoo
发明人： Shigeru Sasaki , Katsunori Nitta , Yoshifumi Araki , Jung Sik Yoon , Gi Yong Um , Chong Sun Yoo
IPC分类号： C08F236/04 , C08F112/02 , C08L53/02
CPC分类号： C08L23/0853 , A43B3/00 , A43B13/04 , C08F8/00 , C08F8/04 , C08F297/02 , C08F297/04 , C08L21/00 , C08L23/04 , C08L23/0815 , C08L23/0869 , C08L53/025 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： Provided is a hydrogenated block copolymer for preparing a foam excellent in tear strength, compression set resistance, low impact resilience, and abrasion resistance.More specifically, provided is a hydrogenated block copolymer comprising a vinyl aromatic compound and a conjugated diene, wherein: (a) the vinyl aromatic unit content is greater than 35 wt. % and not greater than 90 wt. %, (b) the vinyl aromatic polymer block content is not greater than 40 wt. %, (c) the weight average molecular weight is from 5×104 to 100×104, and (d) the hydrogenation ratio of double bonds derived from the conjugated diene is less than 70%.
摘要翻译：提供一种氢化嵌段共聚物，其用于制备抗撕裂强度，抗压缩变形性，低冲击弹性和耐磨性优异的泡沫。更具体地，提供了包含乙烯基芳族化合物和共轭二烯的氢化嵌段共聚物，其中：（a）乙烯基芳族单元含量大于35重量％％且不大于90wt。％，（b）乙烯基芳族聚合物嵌段含量不大于40wt。％，（c）重均分子量为5×104〜100×104，（d）由共轭二烯衍生的双键的氢化率小于70％。

3. 发明授权

US09139722B2 Polypropylene-based resin composition, molded article thereof, and automobile interior or exterior material using the same 有权
标题翻译：聚丙烯系树脂组合物，其成型体，以及使用该树脂组合物的汽车内外装饰材料
公开(公告)号：US09139722B2
公开(公告)日：2015-09-22
申请号：US13254938
申请日：2010-03-12
申请人： Yoshifumi Araki , Katsunori Nitta , Takashi Sato
发明人： Yoshifumi Araki , Katsunori Nitta , Takashi Sato
IPC分类号： C08L53/02 , C08L23/10 , C08L23/12 , C08L23/08 , C08L23/16 , C08C19/02 , C08K3/34 , C08L15/00
CPC分类号： C08L23/10 , C08C19/02 , C08K3/346 , C08L15/00 , C08L23/08 , C08L23/16 , C08L53/02 , C08L53/025 , C08L2666/04 , C08L23/0815
摘要： There are provided a polypropylene-based resin composition having excellent impact resistance, tensile elongation at break and rigidity, a molded article thereof, and an automobile interior or exterior material using the same. The polypropylene-based resin composition contains 50 to 90% by mass of a polypropylene-based polymer (A), 5 to 50% by mass of an ethylene-α-olefin copolymer rubber (B), and 0.1 to 5% by mass of a copolymer (C) primarily comprising a vinyl aromatic monomer unit and an alkylene monomer unit, wherein a content of an α-olefin monomer unit in all alkylene monomers is 45 mol % or more.
摘要翻译：提供了具有优异的抗冲击性，拉伸断裂伸长率和刚性的聚丙烯基树脂组合物，其模塑制品以及使用该聚丙烯的树脂组合物。聚丙烯类树脂组合物含有50〜90质量％的聚丙烯类聚合物（A），5〜50质量％的乙烯-α-烯烃共聚物橡胶（B）和0.1〜5质量％主要包含乙烯基芳族单体单元和亚烷基单体单元的共聚物（C），其中所有亚烷基单体中的α-烯烃单体单元的含量为45摩尔％以上。

4. 发明申请

US20120010351A1 POLYPROPYLENE-BASED RESIN COMPOSITION, MOLDED ARTICLE THEREOF, AND AUTOMOBILE INTERIOR OR EXTERIOR MATERIAL USING THE SAME 有权
标题翻译：基于聚丙烯的树脂组合物，其模制品，以及使用其的汽车内部或外部材料
公开(公告)号：US20120010351A1
公开(公告)日：2012-01-12
申请号：US13254938
申请日：2010-03-12
申请人： Yoshifumi Araki , Katsunori Nitta , Takashi Sato
发明人： Yoshifumi Araki , Katsunori Nitta , Takashi Sato
IPC分类号： C08L25/10
CPC分类号： C08L23/10 , C08C19/02 , C08K3/346 , C08L15/00 , C08L23/08 , C08L23/16 , C08L53/02 , C08L53/025 , C08L2666/04 , C08L23/0815
摘要： There are provided a polypropylene-based resin composition having excellent impact resistance, tensile elongation at break and rigidity, a molded article thereof, and an automobile interior or exterior material using the same. The polypropylene-based resin composition contains 50 to 90% by mass of a polypropylene-based polymer (A), 5 to 50% by mass of an ethylene-α-olefin copolymer rubber (B), and 0.1 to 5% by mass of a copolymer (C) primarily comprising a vinyl aromatic monomer unit and an alkylene monomer unit, wherein a content of an α-olefin monomer unit in all alkylene monomers is 45 mol % or more.
摘要翻译：提供了具有优异的抗冲击性，拉伸断裂伸长率和刚性的聚丙烯基树脂组合物，其模塑制品以及使用该聚丙烯的树脂组合物。聚丙烯类树脂组合物含有50〜90质量％的聚丙烯类聚合物（A），5〜50质量％的乙烯-α-烯烃共聚物橡胶（B）和0.1〜5质量％主要包含乙烯基芳族单体单元和亚烷基单体单元的共聚物（C），其中所有亚烷基单体中的α-烯烃单体单元的含量为45摩尔％以上。

5. 发明授权

US08138270B2 Process for producing block copolymer, and block copolymer or hydrogenated product thereof 有权
标题翻译：制备嵌段共聚物的方法及其嵌段共聚物或氢化产物
公开(公告)号：US08138270B2
公开(公告)日：2012-03-20
申请号：US12310165
申请日：2006-08-16
申请人： Masahiro Sasagawa , Katsunori Nitta
发明人： Masahiro Sasagawa , Katsunori Nitta
IPC分类号： C08F2/00 , C08F287/00
CPC分类号： C08F297/04 , C08F8/04
摘要： The present invention provides a process for producing a block copolymer in high productivity, by anionic polymerization by use of a lithium initiator, and also to provide the block copolymer and a hydrogenated product thereof, the block copolymer having a conjugated diene block portion with a high vinyl bond content and a vinyl aromatic block portion with a narrow molecular weight distribution and exhibiting a narrow molecular weight distribution and high strength. A conjugated diene monomer and a vinyl aromatic monomer by use of a lithium initiator, are block copolymerized by making a tertiary amine compound and (2) sodium alkoxide coexist, wherein (2)/(1) (a molar ratio)=from 0.01 or more to less than 0.1.
摘要翻译：本发明提供了通过使用锂引发剂的阴离子聚合制备高生产率的嵌段共聚物的方法，以及提供嵌段共聚物及其氢化产物，所述嵌段共聚物具有高的共轭二烯嵌段部分乙烯基键含量和乙烯基芳族嵌段部分，分子量分布窄，分子量分布窄，强度高。使用锂引发剂的共轭二烯单体和乙烯基芳族单体通过制备叔胺化合物和（2）醇钠共存而进行嵌段共聚，其中（2）/（1）（摩尔比）= 0.01或大于0.1。

6. 发明申请

US20100016508A1 PROCESS FOR PRODUCING BLOCK COPOLYMER, AND BLOCK COPOLYMER OR HYDROGENATED PRODUCT THEREOF 有权
标题翻译：生产嵌段共聚物的方法和嵌段共聚物或其氢化产物
公开(公告)号：US20100016508A1
公开(公告)日：2010-01-21
申请号：US12310165
申请日：2006-08-16
申请人： Masahiro Sasagawa , Katsunori Nitta
发明人： Masahiro Sasagawa , Katsunori Nitta
IPC分类号： C08F2/00 , C08F287/00
CPC分类号： C08F297/04 , C08F8/04
摘要： The present invention provides a process for producing a block copolymer in high productivity, by anionic polymerization by use of a lithium initiator, and also to provide the block copolymer and a hydrogenated product thereof, the block copolymer having a conjugated diene block portion with a high vinyl bond content and a vinyl aromatic block portion with a narrow molecular weight distribution and exhibiting a narrow molecular weight distribution and high strength. A conjugated diene monomer and a vinyl aromatic monomer by use of a lithium initiator, are block copolymerized by making a tertiary amine compound and (2) sodium alkoxide coexist, wherein (2)/(1) (a molar ratio)=from 0.01 or more to less than 0.1.
摘要翻译：本发明提供了通过使用锂引发剂的阴离子聚合制备高生产率的嵌段共聚物的方法，以及提供嵌段共聚物及其氢化产物，所述嵌段共聚物具有高的共轭二烯嵌段部分乙烯基键含量和乙烯基芳族嵌段部分，分子量分布窄，分子量分布窄，强度高。使用锂引发剂的共轭二烯单体和乙烯基芳族单体通过制备叔胺化合物和（2）醇钠共存而进行嵌段共聚，其中（2）/（1）（摩尔比）= 0.01或大于0.1。

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