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1. 发明授权

US5411689A Method for accelerating removal of residual blowing agent from extruded flexible foams 失效
标题翻译：从挤出的柔性泡沫中加速除去残余发泡剂的方法
公开(公告)号：US5411689A
公开(公告)日：1995-05-02
申请号：US37036
申请日：1993-03-25
申请人： Shau-Tarng Lee , Andrew Oiestad
发明人： Shau-Tarng Lee , Andrew Oiestad
IPC分类号： B29C35/02 , B29C37/00 , B29C44/56 , B29C44/00
CPC分类号： B29C35/0277 , B29C44/56 , B29C44/5609 , B29C37/006 , B29K2105/046 , Y10S264/15
摘要： A method is disclosed for accelerating the removal of blowing agent from elongate, flexible polyolefin foam bodies, such as polyethylene foam sheeting, in the absence of substantial tension on the foam body so as to avoid breaks in the foam body. The elongate flexible foam body is introduced into a heating zone and draped over a plurality of substantially parallel bars in an endless path. Tension on the foam body is avoided because the foam loops are free hanging between these parallel bars. An endless drive means transports the parallel bars through the heating zone about the endless path, thereby transporting the foam body through the heating zone for removal of blowing agent. Forced heated air is blown over the exposed surface of the foam body at a pre-determined temperature and for a pre-determined time sufficient to remove a substantial portion of the residual blowing agent and to cause sufficient air to diffuse into the foam body so that there is no substantial reduction in the thickness of the foam.
摘要翻译：公开了一种用于在泡沫体上不存在实质张力的情况下加速从细长的柔性聚烯烃泡沫体（例如聚乙烯泡沫片）中除去发泡剂的方法，以避免泡沫体中的断裂。细长的柔性泡沫体被引入加热区域并且在多个基本上平行的条上悬挂在环形路径中。避免泡沫体上的张力，因为泡沫环自由悬挂在这些平行杆之间。环形驱动装置将平行杆通过围绕环形路径的加热区输送，从而将泡沫体输送通过加热区以除去发泡剂。强制加热的空气以预定的温度吹过泡沫体的暴露的表面，并且预定时间足以除去大部分的残留的发泡剂并引起足够的空气扩散到泡沫体中，使得泡沫的厚度没有显着降低。

2. 发明申请

US20110197543A1 Alkaline and Heat Resistant Foam Composite and Floor Underlayment 失效
标题翻译：碱性和耐热泡沫复合材料和地板垫
公开(公告)号：US20110197543A1
公开(公告)日：2011-08-18
申请号：US12707175
申请日：2010-02-17
申请人： Shau-Tarng Lee , Claes Hermansson , Brent Sholl
发明人： Shau-Tarng Lee , Claes Hermansson , Brent Sholl
IPC分类号： E04B5/00 , E04C2/24 , B32B3/26
CPC分类号： E04B1/14 , B32B5/18 , B32B7/04 , B32B7/12 , B32B27/065 , B32B27/08 , B32B27/18 , B32B27/32 , B32B27/327 , B32B2250/02 , B32B2250/03 , B32B2250/40 , B32B2266/025 , B32B2307/306 , B32B2307/514 , B32B2307/72 , B32B2307/7242 , B32B2307/7265 , B32B2307/732 , B32B2419/04 , B32B2471/00 , E04B1/62 , E04B5/00 , Y10T428/249953 , Y10T428/249981 , Y10T428/249988 , Y10T428/24999 , Y10T428/249992 , Y10T428/249993
摘要： The invention is directed to a composite foam material that is alkaline and heat resistance. The composite foam material comprises a foam layer that having a film layer attached thereto and in which at least one of the film or foam layers includes a carbon free radical scavenger agent that is dispersed therein. The carbon free radical scavengers neutralize free radicals that are generated in the polymeric material (e.g., film or foam layer) and help prevent the degradation of the foam composite material. In particular, foam composite materials in accordance with the present invention can be used in underlayment applications in which exposure to heat can degrade the underlayment. As a result, the durability and useful life of the composite sheet material can be extended. In some embodiments of the present invention provides a floor underlayment material that overcomes many of the problems discussed above.
摘要翻译：本发明涉及一种耐碱性和耐热性的复合泡沫材料。复合泡沫材料包括具有附着于其上的膜层的泡沫层，其中至少一层膜或泡沫层包含分散在其中的自由基清除剂。碳自由基清除剂中和在聚合材料（例如膜或泡沫层）中产生的自由基，并有助于防止泡沫复合材料的降解。特别地，根据本发明的泡沫复合材料可以用于其中暴露于热量可能降低垫层的底层应用中。结果，可以延长复合片材的耐久性和使用寿命。在本发明的一些实施例中，提供了一种克服上述许多问题的地板垫层材料。

3. 发明授权

US5348984A Expandable composition and process for extruded thermoplastic foams 失效
标题翻译：挤出热塑性泡沫的可膨胀组合物和方法
公开(公告)号：US5348984A
公开(公告)日：1994-09-20
申请号：US010275
申请日：1993-01-28
申请人： Shau-Tarng Lee
发明人： Shau-Tarng Lee
IPC分类号： C08J9/00 , C08J9/12 , C08J9/08 , C08J9/14
CPC分类号： C08J9/127 , C08J9/0023 , C08J2203/14 , C08J2323/02 , Y10S264/05 , Y10S521/91
摘要： An expandable thermoplastic composition is disclosed for extrusion foaming wherein the composition comprises a polyethylene resin; a blowing agent comprising a blend of about 50% by weight of carbon dioxide and about 50% by weight of either normal butane, isobutane, propane, or a mixture of any two or all three hydrocarbons in admixture with the resin in a ratio of about one part blowing agent to about 10 parts resin; zinc oxide nucleation agent in an amount of from about 0.05 to 0.5 kg per 100 kg of the resin; and glycerol monostearate aging modifier in an amount of from about 0.5 to 5 kg per 100 kg of the resin. A process for extrusion foaming of the composition is also disclosed.
摘要翻译：公开了用于挤出发泡的可膨胀热塑性组合物，其中组合物包含聚乙烯树脂; 一种发泡剂，其包含约50重量％的二氧化碳和约50重量％的正丁烷，异丁烷，丙烷或任何两种或全部三种与混合树脂的烃的混合物的混合物，其比例约为一份发泡剂至约10份树脂; 氧化锌成核剂的量为约0.05至0.5kg / 100kg树脂; 和甘油单硬脂酸酯老化改性剂，其量为每100kg树脂约0.5-5kg。还公开了组合物的挤出发泡方法。

4. 发明授权

US08484922B2 Alkaline and heat resistant foam composite and floor underlayment 失效
标题翻译：碱性和耐热泡沫复合材料和地板底层
公开(公告)号：US08484922B2
公开(公告)日：2013-07-16
申请号：US12707175
申请日：2010-02-17
申请人： Shau-Tarng Lee , Claes Hermansson , Brent Sholl
发明人： Shau-Tarng Lee , Claes Hermansson , Brent Sholl
IPC分类号： E04B1/14 , E04B1/62
CPC分类号： E04B1/14 , B32B5/18 , B32B7/04 , B32B7/12 , B32B27/065 , B32B27/08 , B32B27/18 , B32B27/32 , B32B27/327 , B32B2250/02 , B32B2250/03 , B32B2250/40 , B32B2266/025 , B32B2307/306 , B32B2307/514 , B32B2307/72 , B32B2307/7242 , B32B2307/7265 , B32B2307/732 , B32B2419/04 , B32B2471/00 , E04B1/62 , E04B5/00 , Y10T428/249953 , Y10T428/249981 , Y10T428/249988 , Y10T428/24999 , Y10T428/249992 , Y10T428/249993
摘要： The invention is directed to a composite foam material that is alkaline and heat resistance. The composite foam material comprises a foam layer that having a film layer attached thereto and in which at least one of the film or foam layers includes a carbon free radical scavenger agent that is dispersed therein. The carbon free radical scavengers neutralize free radicals that are generated in the polymeric material (e.g., film or foam layer) and help prevent the degradation of the foam composite material. In particular, foam composite materials in accordance with the present invention can be used in underlayment applications in which exposure to heat can degrade the underlayment. As a result, the durability and useful life of the composite sheet material can be extended. In some embodiments of the present invention provides a floor underlayment material that overcomes many of the problems discussed above.
摘要翻译：本发明涉及一种耐碱性和耐热性的复合泡沫材料。复合泡沫材料包括具有附着于其上的膜层的泡沫层，其中至少一层膜或泡沫层包含分散在其中的自由基清除剂。碳自由基清除剂中和在聚合材料（例如膜或泡沫层）中产生的自由基，并有助于防止泡沫复合材料的降解。特别地，根据本发明的泡沫复合材料可以用于其中暴露于热量可能降低垫层的底层应用中。结果，可以延长复合片材的耐久性和使用寿命。在本发明的一些实施例中，提供了一种克服上述许多问题的地板垫层材料。

5. 发明申请

US20060222842A1 Polyolefin foam composite material 审中-公开
标题翻译：聚烯烃泡沫复合材料
公开(公告)号：US20060222842A1
公开(公告)日：2006-10-05
申请号：US11094935
申请日：2005-03-31
申请人： John Thezier , Daniel Melton , James Peterson , Shau-Tarng Lee
发明人： John Thezier , Daniel Melton , James Peterson , Shau-Tarng Lee
IPC分类号： B32B27/00
CPC分类号： B32B5/18 , B32B3/04 , B32B5/02 , B32B5/245 , B32B27/065 , B32B27/12 , B32B27/32 , B32B37/04 , B32B37/153 , B32B2037/0092 , B32B2255/10 , B32B2255/26 , B32B2266/025 , B32B2274/00 , B32B2305/022 , B32B2307/4023 , B32B2307/412 , B32B2307/544 , B32B2307/546 , B32B2509/00 , B32B2605/00 , B63B35/7909 , Y10T428/249981 , Y10T428/249991 , Y10T428/249992 , Y10T442/15 , Y10T442/195
摘要： A composite material suitable for forming a recreational device, such as a snowboard or bodyboard includes a polyolefin foam base layer, a printed layer overlying the foam base layer, and a top layer overlying the printed layer, and wherein the layers are bonded together in the absence of adhesives. The composite material is produced by positioning a printed layer over a surface of a polyolefin foam base layer and extruding a top layer onto the printed layer with sufficient heat energy that the layers are fusion bonded together in the absence of adhesives to form a composite material. The printed layer comprises a thermoplastic polymeric film having a layer of printing on at least one of its surfaces. This film is fusion bonded to the foam base layer. The top layer comprises an extrusion coating of a transparent thermoplastic polymer that is fusion bonded to the printed layer.
摘要翻译：适用于形成诸如滑雪板或车身板的休闲装置的复合材料包括聚烯烃泡沫基层，覆盖泡沫基层的印刷层和覆盖印刷层的顶层，并且其中层在没有粘合剂。复合材料通过将印刷层定位在聚烯烃泡沫基层的表面上并以足够的热能将顶层挤出到印刷层上来生产，该层在不存在粘合剂的情况下被熔合在一起以形成复合材料。印刷层包括在其至少一个表面上具有印刷层的热塑性聚合物膜。该膜与泡沫基层熔合。顶层包括与印刷层熔合的透明热塑性聚合物的挤出涂层。

6. 发明授权

US06716914B2 Compatible linear and branched ethylenic polymers and foams therefrom 有权
公开(公告)号：US06716914B2
公开(公告)日：2004-04-06
申请号：US10454702
申请日：2003-06-04
申请人： Nelson E. Malwitz , Natarajan S. Ramesh , Shau-Tarng Lee
发明人： Nelson E. Malwitz , Natarajan S. Ramesh , Shau-Tarng Lee
IPC分类号： C08F21000
CPC分类号： C08J9/141 , C08J2205/052 , C08J2323/02
摘要： An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.

7. 发明授权

US06436521B1 Polyolefin/ionomer blend for improved properties in extruded foam products 有权
标题翻译：聚烯烃/离聚物共混物，用于改善挤出泡沫产品的性能
公开(公告)号：US06436521B1
公开(公告)日：2002-08-20
申请号：US09406875
申请日：1999-09-28
申请人： Shau-Tarng Lee
发明人： Shau-Tarng Lee
IPC分类号： B32B326
CPC分类号： C08J9/0061 , C08J2201/03 , C08J2323/04 , C08J2423/00 , Y10T428/15 , Y10T428/24273 , Y10T428/24471 , Y10T428/24504 , Y10T428/249953 , Y10T428/249981 , Y10T428/249991 , Y10T428/249992 , Y10T428/249993
摘要： Ionomer present in a polyethylene resin from about 1 to 40% by weight of the resin produces superior extruded foam sheet products that approach the pore size and resiliency of foams prepared from chemical blowing agents. The results can be achieved at normal extrusion rates and on standard extrusion foaming equipment. Tear strength is improved so that collapsible foam packaging products can be produced in which the foam body is cut through except for a surface thereof that remains intact to provide a hinge or joint about which the cut foam bodies can be pivoted.
摘要翻译：存在于聚乙烯树脂中的约1至40重量％的树脂的离聚物产生了接近由化学发泡剂制备的泡沫的孔径和弹性的优异的挤出泡沫片材产品。结果可以在正常挤出速率下和标准挤出发泡设备上实现。提高撕裂强度，使得可以生产可折叠的泡沫包装产品，其中泡沫体被切割通过，除了其表面保持完整以提供铰链或接头，切割的泡沫体可围绕该铰链或接头枢转。

8. 发明授权

US5089535A Thermoplastic compositions for water soluble foams 失效
标题翻译：水溶性泡沫的热塑性组合物
公开(公告)号：US5089535A
公开(公告)日：1992-02-18
申请号：US601260
申请日：1990-10-22
申请人： Nelson E. Malwitz , Shau-Tarng Lee
发明人： Nelson E. Malwitz , Shau-Tarng Lee
IPC分类号： C08J9/00 , C08J9/14
CPC分类号： C08J9/142 , C08J9/0061 , C08J2329/04
摘要： Thermoplastic compositions of internally plasticized polyvinyl alcohol material and a low molecular weight alcohol are provided that can be extruded into water soluble biodegradable foams. The compositions can be modified to provide foams that have varying degrees of water solubility and a broad range of physical characteristics.
摘要翻译：提供内部增塑的聚乙烯醇材料和低分子量醇的热塑性组合物，其可以挤出成水溶性可生物降解泡沫。可以对组合物进行改性以提供具有不同程度的水溶性和宽范围的物理特性的泡沫。

9. 发明授权

US06809125B1 Foam comprising polyolefin blend and method for producing same 有权
标题翻译：包含聚烯烃共混物的泡沫及其制造方法
公开(公告)号：US06809125B1
公开(公告)日：2004-10-26
申请号：US09586493
申请日：2000-06-02
申请人： Shau-Tarng Lee , Natarajan S. Ramesh
发明人： Shau-Tarng Lee , Natarajan S. Ramesh
IPC分类号： C08L2308
CPC分类号： C08L23/06 , C08L23/0815 , C08L2203/14 , C08L2666/06
摘要： A foam and method for making such foam includes a blend of a low density polyethylene and a higher density ethylene polymer. The ethylene polymer has a density ranging from greater than 0.94 to about 0.97 grams/cubic centimeter and a melt flow index of greater than 10 g/10 minutes, and may include at least one member selected from ethylene/alpha-olefin copolymer, ethylene homopolymer, and blends thereof.
摘要翻译：泡沫和制造这种泡沫的方法包括低密度聚乙烯和较高密度乙烯聚合物的共混物。乙烯聚合物的密度范围大于0.94至约0.97克/立方厘米，熔体流动指数大于10g / 10分钟，并且可包括至少一种选自乙烯/α-烯烃共聚物，乙烯均聚物，及其混合物。

10. 发明授权

US06232355B1 Polyolefin products and process additives therefor having reduced transfer to substrates 有权
标题翻译：聚烯烃产品及其加工添加剂具有减少的转移到基材
公开(公告)号：US06232355B1
公开(公告)日：2001-05-15
申请号：US09614499
申请日：2000-07-11
申请人： Nelson E. Malwitz , Natarajan S. Ramesh , Shau-Tarng Lee
发明人： Nelson E. Malwitz , Natarajan S. Ramesh , Shau-Tarng Lee
IPC分类号： C08J900
CPC分类号： C08K5/103 , C08J9/0023 , C08J9/0028 , C08J9/141 , C08J2203/14 , C08J2323/02 , C08K5/20 , Y10S516/915 , C08L23/02
摘要： A process additive for polyolefin films and foams produces products having reduced aging time and reduced greasiness and reduced grease-like transfer as compared to glycerol monostearate (GMS). Carbon dioxide based blowing agents are suitable. The process additive comprises a fatty acid N-aliphatic alcohol amide of the general formula R—CON(R′)R″. R is a fatty hydrocarbon radical having from about 8 to 30 carbons. R′ typically is hydrogen. R′ can also be an alkyl radical of from about 1 to 6 carbons or an alkyl alcohol radical of from about 1 to 6 carbons. R″ is an alkyl alcohol fragment of from about 1 to 6 carbons. The alkyl alcohol fragments can be monohydric or polyhydric. Secondary fatty monoalkanolamides in which R′ is hydrogen are particularly useful, especially stearamide monoethanolamine (MEA). The benefits of the invention can be achieved and enhanced in some examples by mixing the fatty acid N-aliphatic alcohol amide with an ester of a long chain fatty acid with a polyhydric alcohol, including GMS. Examples of fatty acid N-aliphatic alcohol amides include cocamide MEA, lauramide monoisopropylamine (MIPA), oleamide MIPA, and stearamide 2,3-propanediol.
摘要翻译：与甘油单硬脂酸酯（GMS）相比，用于聚烯烃膜和泡沫的工艺添加剂产生具有减少的老化时间和减少的油脂并减少类似脂肪的转移的产物。二氧化碳基发泡剂是合适的。加工添加剂包括通式为R-CON（R'）R“的脂肪酸N-脂族醇酰胺。 R是具有约8至30个碳的脂肪烃基。 R'通常是氢。 R'也可以是约1至6个碳的烷基或约1至6个碳的烷基醇基团。 R“是约1至6个碳的烷基醇片段。烷基醇片段可以是一元或多元。其中R'是氢的二级脂肪单烷醇酰胺特别有用，特别是硬脂酰胺单乙醇胺（MEA）。通过将脂肪酸N-脂肪醇酰胺与长链脂肪酸的酯与多元醇（包括GMS）混合，可以在一些实施例中实现和增强本发明的益处。脂肪酸N-脂肪醇酰胺的实例包括椰油酰胺MEA，月桂酰胺单异丙胺（MIPA），油酰胺MIPA和硬脂酰胺2,3-丙二醇。

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