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1. 发明授权

US06211311B1 Supported olefin polymerization catalysts 有权
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US06211311B1
公开(公告)日：2001-04-03
申请号：US09318008
申请日：1999-05-25
申请人： Shaotian Wang , Bradley P. Etherton , Karen E. Meyer , Michael W. Lynch , Linda N. Winslow , Leonard V. Cribbs , Jia-Chu X. Liu
发明人： Shaotian Wang , Bradley P. Etherton , Karen E. Meyer , Michael W. Lynch , Linda N. Winslow , Leonard V. Cribbs , Jia-Chu X. Liu
IPC分类号： C08F442
CPC分类号： B01J31/165 , B01J31/0231 , B01J31/0272 , B01J31/0274 , B01J31/0275 , B01J31/14 , B01J31/1616 , B01J31/2295 , B01J2531/0225 , B01J2531/0233 , B01J2531/0236 , B01J2531/46 , B01J2531/48 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65916 , C08F210/08 , C08F210/14
摘要： A supported olefin polymerization catalyst system and a method of making it are disclosed. The catalyst system comprises: (a) a support chemically treated with an organoaluminum, organosilicon, organomagnesium, or organoboron compound; (b) a single-site catalyst that contains a polymerization-stable, heteroatomic ligand; and (c) an activator. Chemical treatment is a key to making supported heterometallocenes that have high activity and long shelf-lives, and can effectively incorporate comonomers.
摘要翻译：公开了一种负载型烯烃聚合催化剂体系及其制备方法。催化剂体系包括：（a）用有机铝，有机硅，有机镁或有机硼化合物化学处理的载体; （b）含有聚合稳定的杂原子配体的单中心催化剂; 和（c）活化剂。化学处理是制备具有高活性和长保质期的负载型异金属茂并能有效掺入共聚单体的关键。

2. 发明授权

US5369194A Olefin polymerization method 失效
标题翻译：烯烃聚合法
公开(公告)号：US5369194A
公开(公告)日：1994-11-29
申请号：US23135
申请日：1993-02-24
申请人： Leonard V. Cribbs , Michael W. Lynch
发明人： Leonard V. Cribbs , Michael W. Lynch
IPC分类号： C08F2/06 , C08F4/60 , C08F4/633 , C08F4/64 , C08F4/659 , C08F4/685 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/02
摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bimodal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.
摘要翻译：通过使颗粒状固体载体与锆化合物或络合物接触，将锆化合物或络合物与锆的化合物或络合物接触，制备能够生产具有宽或多峰分子量分布如双峰分子量分布的聚烯烃的多部位固体催化剂组分任选地将负载的锆化合物或络合物与路易斯酸接触以产生中间产物，任选地分离和洗涤负载的锆化合物或络合物或所得中间产物以从其中除去可溶性副产物，并将洗涤或未洗涤的负载的锆化合物或复合物或中间产物与钛或钒化合物反应以产生固体催化剂组分。

3. 发明授权

US5202397A Olefin polymerization method 失效
公开(公告)号：US5202397A
公开(公告)日：1993-04-13
申请号：US923147
申请日：1992-07-31
申请人： Leonard V. Cribbs , Michael W. Lynch
发明人： Leonard V. Cribbs , Michael W. Lynch
摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bimodal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

4. 发明授权

US5155079A Multiple site olefin polymerization catalysts 失效
标题翻译：多位烯烃聚合催化剂
公开(公告)号：US5155079A
公开(公告)日：1992-10-13
申请号：US712206
申请日：1991-06-07
申请人： Leonard V. Cribbs , Michael W. Lynch
发明人： Leonard V. Cribbs , Michael W. Lynch
IPC分类号： C08F2/06 , C08F4/60 , C08F4/633 , C08F4/64 , C08F4/659 , C08F4/685 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bi-modal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

5. 发明授权

US07858718B1 Catalysts based on 2-aryl-8-anilinoquinoline ligands 失效
标题翻译：基于2-芳基-8-苯胺基喹啉配体的催化剂
公开(公告)号：US07858718B1
公开(公告)日：2010-12-28
申请号：US12460621
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Michael W. Lynch
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Michael W. Lynch
IPC分类号： C08F4/76 , C08F4/64 , C08F4/52 , C07F7/00
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/941 , C08F2/06 , C08F210/08 , C08F2500/17 , C08F210/14 , C08F4/64144
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-aryl-8-anilinoquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译：公开了可用于聚合烯烃的催化剂。催化剂包含活化剂和含有二阴离子，三齿2-芳基-8-苯胺基喹啉配体的第4族金属络合物。在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。

6. 发明授权

US5534472A Vanadium-containing catalyst system 失效
标题翻译：含钒催化剂体系
公开(公告)号：US5534472A
公开(公告)日：1996-07-09
申请号：US412633
申请日：1995-03-29
申请人： Linda N. Winslow , Douglas D. Klendworth , Raghu Menon , Michael W. Lynch , Garry L. Fields , Kenneth W. Johnson
发明人： Linda N. Winslow , Douglas D. Klendworth , Raghu Menon , Michael W. Lynch , Garry L. Fields , Kenneth W. Johnson
IPC分类号： B01J31/12 , B01J31/14 , B01J31/16 , B01J31/22 , C08F10/00 , C08F210/16
CPC分类号： B01J31/2226 , B01J31/128 , B01J31/143 , B01J31/1616 , C08F10/00 , B01J2531/56 , C08F210/16
摘要： A vanadium-containing catalyst system particularly suited to the polymerization of blow moldable olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting preheated silica, with (1) a compound or complex which includes at least one carbon to magnesium covalent bond and (2) a compound which includes at least one carbon to Group III metal covalent bond. The sequence of contact of the silica with compound or complex (1) and compound (2) is optional. However, unless the compound or complex (1) and the compound (2) contact the silica simultaneously, the product of this contact is next contacted with whichever of compound (1) or (2) does not initially contact the silica. The product of the step of contacting with compounds (1) and (2) is contacted with a vanadium compound which includes at least one halogen atom. Finally, the product of the vanadium compound contacting step is contacted with an alcohol. A second component of the catalyst system is an organoaluminum compound cocatalyst. The catalyst system also includes a halocarbon compound promoter as a third catalyst component.
摘要翻译：一种特别适用于可吹塑烯烃聚合物聚合的含钒催化剂体系。催化剂体系包括通过使预热的二氧化硅与（1）包含至少一个碳 - 镁共价键的化合物或络合物接触而制备的负载的第一催化剂组分和（2）包含至少一个碳至III族金属的化合物共价键。二氧化硅与化合物或络合物（1）和化合物（2）的接触顺序是任选的。然而，除非化合物或络合物（1）和化合物（2）同时与二氧化硅接触，否则接触的产物接下来与化合物（1）或（2）中最初不接触二氧化硅的化合物接触。与化合物（1）和（2）接触的步骤的产物与包含至少一个卤素原子的钒化合物接触。最后，将钒化合物接触步骤的产物与醇接触。催化剂体系的第二个组分是有机铝化合物助催化剂。催化剂体系还包括作为第三催化剂组分的卤代烃化合物促进剂。

7. 发明授权

US06908972B2 Method for making polyolefins 有权
标题翻译：聚烯烃的制备方法
公开(公告)号：US06908972B2
公开(公告)日：2005-06-21
申请号：US10123774
申请日：2002-04-16
申请人： Barbara M. Tsuie , Karen L. Neal-Hawkins , Sandor Nagy , Michael W. Lynch , Mark P. Mack , Shaotian Wang , Jean A Merrick-Mack , Clifford C. Lee , Joel A. Mutchler , Kenneth W. Johnson
发明人： Barbara M. Tsuie , Karen L. Neal-Hawkins , Sandor Nagy , Michael W. Lynch , Mark P. Mack , Shaotian Wang , Jean A Merrick-Mack , Clifford C. Lee , Joel A. Mutchler , Kenneth W. Johnson
IPC分类号： C08F4/642 , C08F4/659 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/52
CPC分类号： C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/09 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F210/14
摘要： A method for making ethylene polymers and copolymers is disclosed. The method uses a catalyst system comprising a low level of an aluminum-containing activator, a bridged indenoindolyl transition metal complex, and a treated silica support. The method enables economical preparation of ethylene copolymers having very low density. The silica-supported, bridged complexes incorporate comonomers efficiently and are valuable for a commercial slurry loop process. Use of a bridged indeno[2,1-b]indolyl complex provides exceptionally efficient comonomer incorporation, and gives polymers with a substantial and controlled level of long-chain branching. The method facilitates the production of a wide variety of polyolefins, from HDPE to plastomers.
摘要翻译：公开了制备乙烯聚合物和共聚物的方法。该方法使用包含低含量的含铝活化剂，桥连茚并吲哚基过渡金属络合物和经处理的二氧化硅载体的催化剂体系。该方法能够经济地制备具有非常低密度的乙烯共聚物。二氧化硅负载的桥接配合物有效地引入共聚单体，并且对于商业淤浆循环方法是有价值的。桥联茚并[2,1-b]吲哚基复合物的使用提供了非常有效的共聚单体掺入，并且得到具有实质和受控水平的长链支化的聚合物。该方法有助于生产从HDPE到塑性体的各种各样的聚烯烃。

8. 发明授权

US06630547B1 Use of silanes to control molecular weight in olefin polymerizations 失效
标题翻译：使用硅烷来控制烯烃聚合中的分子量
公开(公告)号：US06630547B1
公开(公告)日：2003-10-07
申请号：US10166934
申请日：2002-06-11
申请人： Michael W. Lynch , Shaotian Wang , William J. Sartain
发明人： Michael W. Lynch , Shaotian Wang , William J. Sartain
IPC分类号： C08F442
CPC分类号： C08F10/02 , C08F4/65916 , C08F4/65925 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F2/38 , C08F4/65912 , C08F2500/12 , C08F210/14
摘要： A process for polymerizing an olefin is disclosed. The olefin is polymerized with a catalyst precursor in the presence of an activator and an organosilane modifier. Use of the organosilane increases polyolefin molecular weight. The process is easy to practice and affords polyolefins with conventional polymerization methods such as slurry polymerizations or gas-phase polymerizations.
摘要翻译：公开了聚合烯烃的方法。在活化剂和有机硅烷改性剂存在下，烯烃与催化剂前体聚合。使用有机硅烷可提高聚烯烃的分子量。该方法易于实践，并提供具有常规聚合方法如淤浆聚合或气相聚合的聚烯烃。

9. 发明申请

US20080300370A1 Preparation of polyethylene 有权
标题翻译：聚乙烯的制备
公开(公告)号：US20080300370A1
公开(公告)日：2008-12-04
申请号：US11809688
申请日：2007-06-01
申请人： Michael W. Lynch , Craig C. Meverden
发明人： Michael W. Lynch , Craig C. Meverden
IPC分类号： C08F4/44
CPC分类号： C08F10/02 , C08F4/6567 , C08F4/6565
摘要： A process for preparing a polyethylene in a multi-stage process is described. The process comprises pre-treating a Ziegler catalyst in a first stage in the presence of a 1-olefin/ethylene mixture or a 1-olefin to produce a LLDPE or VLDPE, which have the characteristics of a polymer prepared with a single-site catalyst, e.g. high levels of short-chain branching that are uniformly distributed. The contents of the first stage are then transferred to a second stage where an ethylene or an ethylene/1-olefin mixture is polymerized in the presence of the pre-treated catalyst to form a polyethylene with good processability.
摘要翻译：描述了在多级方法中制备聚乙烯的方法。该方法包括在1-烯烃/乙烯混合物或1-烯烃的存在下在第一阶段预处理齐格勒催化剂以产生具有由单中心催化剂制备的聚合物特性的LLDPE或VLDPE ，例如高水平的短链分支均匀分布。然后将第一阶段的内容物转移到乙烯或乙烯/ 1-烯烃混合物在预处理催化剂存在下聚合以形成具有良好加工性能的聚乙烯的第二阶段。

10. 发明授权

US5399540A ZR/V multi-site olefin polymerization catalyst 失效
标题翻译： ZR / V多位烯烃聚合催化剂
公开(公告)号：US5399540A
公开(公告)日：1995-03-21
申请号：US17120
申请日：1993-02-12
申请人： Chi-I Kuo , Michael W. Lynch
发明人： Chi-I Kuo , Michael W. Lynch
IPC分类号： B01J31/02 , B01J31/14 , C08F10/00 , B01J31/00
CPC分类号： B01J31/143 , B01J31/0212 , C08F10/00
摘要： A catalyst useful in the polymerization of olefins, especially ethylene, is disclosed. The catalyst is obtained by admixing a zinc composition, a zirconium composition and a vanadium composition. The catalyst may be combined with a co-catalyst and, optionally, a modifier to yield an olefin polymerization system. The catalyst exhibits extremely high activity, good hydrogen response and produces polymers having broad molecular weight distribution ("MWD") and manifesting bimodal MWD profile.
摘要翻译：公开了一种可用于烯烃聚合，特别是乙烯的催化剂。通过混合锌组合物，锆组合物和钒组合物获得催化剂。催化剂可以与助催化剂和任选的改性剂组合以产生烯烃聚合体系。该催化剂表现出极高的活性，良好的氢气响应，并产生具有宽分子量分布（“MWD”）和显示双峰MWD谱的聚合物。

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