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1. 发明申请

US20080119624A1 Loop Reactor With Varying Diameter For Olefin Polymerization 有权
标题翻译：环烯烃反应器用于烯烃聚合的不同直径
公开(公告)号：US20080119624A1
公开(公告)日：2008-05-22
申请号：US10572817
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring , Markus Meierhofer
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring , Markus Meierhofer
IPC分类号： C08F2/00
CPC分类号： B01J19/2435 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , C08F2/01 , C08F2/14 , C08F210/14 , C08F2500/08 , C08F2500/24
摘要： Process for polymerizing at least one olefinic monomer selected from ethylene, propylene and 1-butene in a loop reactor in the presence of a polymerization catalyst at from 20 to 150° C., but below the melting point of a polymer to be formed, and a pressure of from 43 to 80 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and wherein the suspension is circulated by means of an axial pump, wherein the polymerization is carried out at an average solids concentration in the reactor of more than 53% by weight, in the case of continuous product discharge, and at an average solids concentration in the reactor of more than 45% by weight, in the case of discontinuous product discharge, and wherein the polymerization is carried out at an ethylene concentration of at least 10 mol %, based on the suspension medium.
摘要翻译：在聚合催化剂存在下，在环状反应器中，在20〜150℃，但低于待形成的聚合物的熔点，聚合至少一种选自乙烯，丙烯和1-丁烯的烯烃单体的方法，以及其中形成的聚合物存在于液体或超临界悬浮介质中的悬浮液中，并且其中悬浮液通过轴向泵循环，其中聚合以平均固体浓度进行反应器在连续产物排出的情况下大于53重量％，反应器中的平均固体浓度大于45重量％，在不连续的产物排出的情况下，并且其中进行聚合基于悬浮介质，乙烯浓度至少为10摩尔％。

2. 发明申请

US20070037936A1 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US20070037936A1
公开(公告)日：2007-02-15
申请号：US10572816
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring
IPC分类号： C08F2/00
CPC分类号： B01J19/1837 , B01J3/008 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , Y10S526/92 , C08F2/14 , C08F2/01 , C08F210/14
摘要： Process for polymerizing at least one olefinic monomer in a loop reactor at from 20 to 150° C., but below the melting point of the polymer to be formed, and a pressure of from 5 to 100 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and this suspension is circulated by means of an axial pump, wherein the loop reactor comprises a cyclic reactor tube whose diameter varies by at least 10%, based on the predominant reactor tube diameter, and in which there is at least one widening and narrowing in a region other than that of the axial pump.
摘要翻译：在环管反应器中在20-150℃下聚合至少一种烯属单体的方法，但低于待形成的聚合物的熔点，压力为5-100巴，其中所形成的聚合物存在于在液体或超临界悬浮介质中的悬浮液，并且该悬浮液通过轴向泵循环，其中环流反应器包括基于主要的反应器管直径，其直径变化至少10％的循环反应器管，其中在轴向泵以外的区域中至少有一个变宽和变窄。

3. 发明申请

US20080269437A1 Catalyst Comprising Chromium and Zirconium for the Polymerization and/or Copolymerization of Olefins 有权
标题翻译：包含铬和锆的催化剂用于烯烃的聚合和/或共聚
公开(公告)号：US20080269437A1
公开(公告)日：2008-10-30
申请号：US11629102
申请日：2005-06-09
申请人： Shahram Mihan , Andreas Haufe , Peter Kolle , Joachim Wulff-Doring , Ingo Treffkorn , Guido Funk
发明人： Shahram Mihan , Andreas Haufe , Peter Kolle , Joachim Wulff-Doring , Ingo Treffkorn , Guido Funk
IPC分类号： C08F4/24
CPC分类号： C08F10/00 , C08F210/16 , C08F2410/04 , C08F4/18 , C08F4/24 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/13 , C08F2500/17
摘要： Catalyst for the polymerization and/or copolymerization of olefins which is obtainable by application to a finely divided inorganic support and concluding calcination at temperatures of from 350 to 1050° C. and has a chromium content of from 0.1 to 5% by weight and a zirconium content of from 0.5 to 10% by weight, in each case based on the element in the finished catalyst, with the molar ratio of zirconium to chromium being from 0.6 to 5.
摘要翻译：用于烯烃的聚合和/或共聚的催化剂，其可通过应用于细碎的无机载体而获得，并且在350至1050℃的温度下进行煅烧并且具有0.1至5重量％的铬含量和锆含量为0.5〜10重量％，基于成品催化剂中的元素，锆与铬的摩尔比为0.6〜5。

4. 发明申请

US20080051532A1 Process for Preparing a Chromium-Based Catalyst for the Polymerization and/or Copolymerization of Olefins 有权
标题翻译：制备用于烯烃聚合和/或共聚的铬基催化剂的方法
公开(公告)号：US20080051532A1
公开(公告)日：2008-02-28
申请号：US11628827
申请日：2005-06-09
申请人： Shahram Mihan , Andreas Haupe , Peter Kolle , Joachim Wulff-Doring , Ingo Treffkorn , Guido Funk
发明人： Shahram Mihan , Andreas Haupe , Peter Kolle , Joachim Wulff-Doring , Ingo Treffkorn , Guido Funk
IPC分类号： C08F4/18 , C08F2/00
CPC分类号： C08F10/00 , C08F210/16 , C08F2410/04 , C08F210/14 , C08F2500/04 , C08F2500/17 , C08F2500/12 , C08F4/22 , C08F4/025 , C08F4/16
摘要： Process for preparing a supported catalyst for the polymerization and/or copolymerization of olefins which has a chromium content of from 0.01 to 5% by weight, based on the element, which comprises (a) preparing a homogeneous solution comprising an organic or inorganic chromium compound and at least one further organic or inorganic compound of elements selected from among Mg, Ca, Sr, B, Al, Si, P, Bi, Sc, V, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Hf, Ta, W in a protic or aprotic polar solvent, (b) bringing the solution from a) into contact with a finely divided inorganic support to form a catalyst precursor, (c) if appropriate, removing the solvent from the catalyst precursor and (d) calcining the catalyst precursor at temperatures of from 350 to 950° C., preferably 400 to 900° C., under oxidative conditions.
摘要翻译：制备用于烯烃聚合和/或共聚的负载催化剂的方法，该催化剂的铬含量为0.01至5重量％，基于该元素，其包括（a）制备包含有机或无机铬化合物的均匀溶液以及选自Mg，Ca，Sr，B，Al，Si，P，Bi，Sc，V，Mn，Fe，Co，Ni，Cu，Zn，Zr，Nb中的至少一种有机或无机化合物， Mo，Ru，Rh，Pd，Hf，Ta，W在质子或非质子极性溶剂中，（b）使来自a）的溶液与细碎的无机载体接触以形成催化剂前体，（c）从催化剂前体中除去溶剂，和（d）在氧化条件下，在350-950℃，优选400-900℃的温度下煅烧催化剂前体。

5. 发明申请

US20070179051A1 Preparation of supported catalysts for polymerization 审中-公开
标题翻译：负载聚合催化剂的制备
公开(公告)号：US20070179051A1
公开(公告)日：2007-08-02
申请号：US10588391
申请日：2005-02-02
申请人： Shahram Mihan , Joachim Wulff-Doring , Alexander Koppl , Wolfgang Rohde
发明人： Shahram Mihan , Joachim Wulff-Doring , Alexander Koppl , Wolfgang Rohde
IPC分类号： C08F2/00 , B01J23/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F4/025 , C08F4/24 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/24 , C08F4/22 , C08F4/78
摘要： The invention relates to a process for preparing a supported catalyst, in particular for the polymerization and/or copolymerization of olefins, which comprises: a) preparing a hydrogel; b) milling the hydrogel to give a finely particulate hydrogel; c) producing a slurry based on the finely particulate hydrogel; d) drying the slurry comprising the finely particulate hydrogel to give the support for catalysts; e) producing the supported catalyst by applying at least one transition metal and/or at least one transition metal compound to the support for catalysts and, if appropriate, activating the applied metal and/or compound, wherein a finely particulate hydrogel in which at least 5% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦3 μm; and/or at least 40% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦12 μm, and/or at least 75% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦35 μm, is produced in step b) and a support which can be prepared as set forth in steps a) to d) is used to produce catalysts in step e).
摘要翻译：本发明涉及一种制备负载型催化剂的方法，特别是用于烯烃的聚合和/或共聚合，其包括：a）制备水凝胶; b）研磨水凝胶以得到细颗粒水凝胶; c）基于细颗粒水凝胶生产浆料; d）干燥包含细颗粒状水凝胶的浆料，得到催化剂载体; e）通过将至少一种过渡金属和/或至少一种过渡金属化合物施加到催化剂的载体上，并且如果合适地活化所施加的金属和/或化合物，制备负载型催化剂，其中至少基于颗粒的总体积，5体积％的颗粒具有在>0μm至<3μm的范围内的粒度; 和/或至少40体积％的颗粒，基于颗粒的总体积，其粒度范围为>0μm至≤12μm，和/或至少75体积％基于颗粒的总体积的颗粒具有在>0μm至<=35μm的范围内的粒度，在步骤b）中制备，并且可以如步骤a）至d所述制备的载体）用于在步骤e）中制备催化剂。

6. 发明授权

US07553916B2 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US07553916B2
公开(公告)日：2009-06-30
申请号：US10572816
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring
IPC分类号： C08F2/12 , B01J19/18
CPC分类号： B01J19/1837 , B01J3/008 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , Y10S526/92 , C08F2/14 , C08F2/01 , C08F210/14
摘要： Process for polymerizing at least one olefinic monomer in a loop reactor at from 20 to 150° C., but below the melting point of the polymer to be formed, and a pressure of from 5 to 100 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and this suspension is circulated by means of an axial pump, wherein the loop reactor comprises a cyclic reactor tube whose diameter varies by at least 10%, based on the predominant reactor tube diameter, and in which there is at least one widening and narrowing in a region other than that of the axial pump.
摘要翻译：在环管反应器中在20-150℃下聚合至少一种烯属单体的方法，但低于待形成的聚合物的熔点，压力为5-100巴，其中所形成的聚合物存在于在液体或超临界悬浮介质中的悬浮液，并且该悬浮液通过轴向泵循环，其中环流反应器包括基于主要的反应器管直径，其直径变化至少10％的循环反应器管，其中在轴向泵以外的区域中至少有一个变宽和变窄。

7. 发明授权

US07517938B2 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US07517938B2
公开(公告)日：2009-04-14
申请号：US10572817
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring , Markus Meierhöfer
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring , Markus Meierhöfer
IPC分类号： C08F2/12 , B01J19/18
CPC分类号： B01J19/2435 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , C08F2/01 , C08F2/14 , C08F210/14 , C08F2500/08 , C08F2500/24
摘要： Process for polymerizing at least one olefinic monomer selected from ethylene, propylene and 1-butene in a loop reactor in the presence of a polymerization catalyst at from 20 to 150° C., but below the melting point of a polymer to be formed, and a pressure of from 43 to 80 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and wherein the suspension is circulated by means of an axial pump, wherein the polymerization is carried out at an average solids concentration in the reactor of more than 53% by weight, in the case of continuous product discharge, and at an average solids concentration in the reactor of more than 45% by weight, in the case of discontinuous product discharge, and wherein the polymerization is carried out at an ethylene concentration of at least 10 mol %, based on the suspension medium.
摘要翻译：在聚合催化剂存在下，在环状反应器中，在20〜150℃，但低于待形成的聚合物的熔点，聚合至少一种选自乙烯，丙烯和1-丁烯的烯烃单体的方法，以及其中形成的聚合物存在于液体或超临界悬浮介质中的悬浮液中，并且其中悬浮液通过轴向泵循环，其中聚合以平均固体浓度进行反应器在连续产物排出的情况下大于53重量％，反应器中的平均固体浓度大于45重量％，在不连续的产物排出的情况下，并且其中进行聚合基于悬浮介质，乙烯浓度至少为10摩尔％。

8. 发明授权

US08999875B2 Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use 有权
标题翻译：制备用于烯烃聚合的负载催化剂体系的方法，催化剂体系及其用途
公开(公告)号：US08999875B2
公开(公告)日：2015-04-07
申请号：US13700098
申请日：2011-05-26
申请人： Fabiana Fantinel , Shahram Mihan , Rainer Karer , Volker Fraaije
发明人： Fabiana Fantinel , Shahram Mihan , Rainer Karer , Volker Fraaije
IPC分类号： C08F4/653 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/08 , C08F4/619 , C08F4/6192
CPC分类号： C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61925 , C08L23/0815 , Y10S526/943 , C08F4/025 , C08F4/61904 , C08L2666/06 , C08F210/14 , C08F2500/17 , C08F4/7042
摘要： The invention refers to a process for preparing a supported catalyst system for the polymerization of olefins comprising at least one active catalyst component on a support, the process comprisingA) impregnating a dry porous support component with a mixture comprising at least one precatalyst, at least one cocatalyst, and a first solvent, such that the total volume of the mixture is from 0.8 to 2.0 times the total pore volume of the support component, and B) thereafter, adding a second solvent in an amount of more than 1.5 times the total pore volume of the support component. The invention refers further to a catalyst system made by this process and the use of this catalyst system for polymerization or copolymerization of olefins.
摘要翻译：本发明涉及一种制备负载型催化剂体系的方法，所述催化剂体系包括在载体上包含至少一种活性催化剂组分的烯烃聚合，所述方法包括：A）至少将含有至少一种预催化剂的混合物浸渍在干多孔载体组分中，至少一种助催化剂和第一溶剂，使得混合物的总体积为载体组分的总孔体积的0.8-2.0倍，B）然后，加入第二种溶剂的总量的1.5倍以上载体组分的孔体积。本发明还涉及通过该方法制备的催化剂体系和该催化剂体系用于烯烃聚合或共聚的用途。

9. 发明申请

US20130023631A1 Process for the preparation of ethylene copolymer compositions in the presence of an oligomerization catalyst 有权
标题翻译：在低聚催化剂存在下制备乙烯共聚物组合物的方法
公开(公告)号：US20130023631A1
公开(公告)日：2013-01-24
申请号：US13521717
申请日：2011-01-20
申请人： Katrin Schuhen , Lenka Lukesova , Shahram Mihan
发明人： Katrin Schuhen , Lenka Lukesova , Shahram Mihan
IPC分类号： C08F210/02 , C08F2/34
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , Y02P20/52 , C08F2/02 , C08F2/34 , C08F2500/07 , C08F2500/17 , C08F210/14 , C08F2500/05 , C08F2500/12 , C08F4/61904 , C08F4/7042
摘要： Process for the preparation of an ethylene copolymer composition having a polydispersity index Mw/Mn of from 3 to 100, comprising a) feeding ethylene to at least one polymerization reactor; b) performing in the at least one polymerization reactor an oligomerization of ethylene in the presence of an oligomerization catalyst component (C) to produce comonomer; c) performing simultaneously in the at least one polymerization reactor polymerization reactions in the presence of catalyst components (A) and (B) producing, respectively, a first and a second polyethylene fraction, wherein the weight average molecular weight Mw of the first polyethylene fraction produced by catalyst component (A) is less than the Mw of the second polyethylene fraction produced by catalyst component (B) and the comonomer incorporation ability of catalyst component (B) is higher than the comonomer incorporation ability of catalyst component (A); and d) withdrawing the ethylene copolymer composition from the polymerization reactor.
摘要翻译：制备多分散指数Mw / Mn为3至100的乙烯共聚物组合物的方法，包括：a）将乙烯进料至至少一个聚合反应器; b）在所述至少一个聚合反应器中在低聚催化剂组分（C）的存在下进行乙烯的低聚以产生共聚单体; c）在催化剂组分（A）和（B）的存在下在所述至少一个聚合反应器聚合反应中同时进行第一和第二聚乙烯级分的制备，其中第一聚乙烯级分的重均分子量Mw 由催化剂成分（A）制造的催化剂成分（B）的共聚单体引入能力低于催化剂成分（B）生成的第二聚乙烯馏分的Mw，催化剂成分（B）的共聚单体引入能力高于催化剂成分（A）的共聚单体引入能力。和d）从聚合反应器中取出乙烯共聚物组合物。

10. 发明申请

US20120283369A1 Polymerization process in the presence of an antistatic agent 审中-公开
标题翻译：在抗静电剂存在下的聚合过程
公开(公告)号：US20120283369A1
公开(公告)日：2012-11-08
申请号：US13514968
申请日：2010-12-16
申请人： Lars Koelling , Shahram Mihan , Gerhardus Meier
发明人： Lars Koelling , Shahram Mihan , Gerhardus Meier
IPC分类号： C08L81/06 , C08K5/42
CPC分类号： C08F10/00 , C08F110/02 , C08F2/005 , C08F2500/12 , C08F2500/04
摘要： Process for the polymerization of olefins at temperatures of from −20 to 200° C. and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst and an antistatic agent, wherein the antistatic agent is an antistatically acting composition comprising a polysulfone copolymer, a polymeric compound comprising basic nitrogen atoms, an oil-soluble sulfonic acid and optionally a solvent and the polysulfone copolymer, the polymeric compound comprising basic nitrogen atoms and the oil-soluble sulfonic acid constitute together at least 1 wt. % of the antistatically acting composition, and wherein the antistatically acting composition, when contacted as solution or suspension in heptane, wherein the solution or suspension has a concentration of about 80 g of the antistatically acting composition per liter of heptane, with a 2 M solution of triethylaluminum in heptane at 0° C., generates less than 5 cm3, measured at 23° C. and atmospheric pressure, of ethane per gram of the antistatically acting composition and use of an antistatically acting composition as antistatic agent for the polymerization of olefins at temperatures of from −20 to 200° C. and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst.
摘要翻译：在聚合催化剂和抗静电剂存在下，在-20至200℃的温度和0.1至20MPa的压力下烯烃的聚合方法，其中抗静电剂是包含聚砜共聚物，包含碱性氮原子的聚合化合物，油溶性磺酸和任选的溶剂和聚砜共聚物，包含碱性氮原子的聚合化合物和油溶性磺酸一起构成至少1重量％％的抗静电作用组合物，并且其中所述抗静电作用组合物当作为溶液或悬浮液在庚烷中接触时，其中所述溶液或悬浮液的浓度为每升庚烷约80g抗静电作用组合物，与2M溶液的三乙基铝在庚烷中在0℃下产生小于5cm 3，在23℃和大气压下测量每克抗静电作用组合物的乙烷和抗静电作用组合物的用作抗静电剂用于烯烃聚合在-20至200℃的温度和0.1至20MPa的压力下，在聚合催化剂存在下进行。

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