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1. 发明申请

US20100047693A1 BINDER FOR ELECTRODE MATERIAL CONTAINING SEMI-IPN OF POLYVINYL ALCOHOL AND POLYURETHANE AND LITHIUM SECONDARY BATTERY EMPLOYED WITH THE SAME 有权
标题翻译：含有聚乙烯醇和聚氨酯的锂聚合物的电极材料的粘合剂和与其同时使用的锂二次电池
公开(公告)号：US20100047693A1
公开(公告)日：2010-02-25
申请号：US12310341
申请日：2007-08-10
申请人： Seungrim Yang , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , Eun-Suok Oh , Min Ho Cho
发明人： Seungrim Yang , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , Eun-Suok Oh , Min Ho Cho
IPC分类号： H01M4/58 , C08G18/67 , H01B1/12 , H01B1/24 , H01B1/22 , H01M4/02
CPC分类号： H01M4/621 , H01M4/13 , H01M10/052
摘要： Provided is a binder for an electrode mix containing a semi-interpenetrating polymer network (semi-IPN) of polyvinyl alcohol and polyurethane, wherein the polyurethane is mixed to crosslink with the polyvinyl alcohol to form semi-IPN, and a lithium secondary battery comprising the same. The binder has superior adhesion to the electrode, excellent electrolyte resistance and improved elongation percentage, and therefore it is possible to prevent exfoliation or separation of electrode active materials from current collectors which occurs during repeated charge/discharge cycles. As a result, the capacity or power out of secondary batteries can be maintained at a constant level.
摘要翻译：提供一种用于电极混合物的粘合剂，其包含聚乙烯醇和聚氨酯的半互穿聚合物网络（semi-IPN），其中将聚氨酯混合以与聚乙烯醇交联以形成半IPN，以及锂二次电池，其包含相同。粘合剂对电极的粘合性优异，耐电解质性优异，伸长率提高，因此可以防止电极活性物质与反复充放电循环中发生的集电体剥离或分离。结果，二次电池的容量或功率可以保持在一个恒定的水平。

2. 发明授权

US07846583B2 Electrode material containing mixture of polyvinyl alcohol of high degree of polymerization and polyvinyl pyrrolidone as binder and lithium secondary battery employed with the same 有权
标题翻译：含有高聚合度的聚乙烯醇和聚乙烯吡咯烷酮作为粘合剂的混合物的电极材料和与其一起使用的锂二次电池
公开(公告)号：US07846583B2
公开(公告)日：2010-12-07
申请号：US12310700
申请日：2007-08-24
申请人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , SeungRim Yang , Min Ho Cho
发明人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , SeungRim Yang , Min Ho Cho
IPC分类号： H01M4/62
CPC分类号： H01M10/052 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/621 , H01M4/622 , H01M10/0525
摘要： An electrode mix comprising a mixture of a polyvinyl alcohol with polyvinyl pyrrolidone as a binder and a lithium secondary battery comprising the same are disclosed. The electrode mix and lithium secondary battery according to the present invention enable stable maintenance of adhesion between active materials and/or adhesion between the active material and current collector and reduction of volumetric changes of anode active materials during repeated charge/discharge cycles, through the use of a polymer having an improved elongation percentage while exhibiting very high adhesive strength, as a binder of an electrode mix. Therefore, the present invention enables production of a large-capacity lithium secondary battery particularly using a silicon- or tin-based anode active material.
摘要翻译：公开了包含聚乙烯醇与聚乙烯吡咯烷酮作为粘合剂的混合物的电极混合物和包含该混合物的锂二次电池。根据本发明的电极混合物和锂二次电池能够稳定地维持活性材料之间的粘附和/或活性材料与集电体之间的粘附，并且通过使用在反复充电/放电循环期间减少阳极活性材料的体积变化的具有改善的伸长率的聚合物，同时具有非常高的粘合强度，作为电极混合物的粘合剂。因此，本发明能够特别使用硅或锡系阳极活性物质制造大容量锂二次电池。

3. 发明授权

US07960056B2 Binder for electrode material containing semi-IPN of polyvinyl alcohol and polyurethane and lithium secondary battery employed with the same 有权
标题翻译：含有聚乙烯醇的半IPN和聚氨酯的电极材料的粘合剂以及与此相同的锂二次电池
公开(公告)号：US07960056B2
公开(公告)日：2011-06-14
申请号：US12310341
申请日：2007-08-10
申请人： SeungRim Yang , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , Eun-Suok Oh , Min Ho Cho
发明人： SeungRim Yang , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , Eun-Suok Oh , Min Ho Cho
IPC分类号： H01M4/02 , H01M4/58
CPC分类号： H01M4/621 , H01M4/13 , H01M10/052
摘要： Provided is a binder for an electrode mix containing a semi-interpenetrating polymer network (semi-IPN) of polyvinyl alcohol and polyurethane, wherein the polyurethane is mixed to crosslink with the polyvinyl alcohol to form semi-IPN, and a lithium secondary battery comprising the same. The binder has superior adhesion to the electrode, excellent electrolyte resistance and improved elongation percentage, and therefore it is possible to prevent exfoliation or separation of electrode active materials from current collectors which occurs during repeated charge/discharge cycles. As a result, the capacity or power out of secondary batteries can be maintained at a constant level.
摘要翻译：提供一种用于电极混合物的粘合剂，其包含聚乙烯醇和聚氨酯的半互穿聚合物网络（semi-IPN），其中将聚氨酯混合以与聚乙烯醇交联以形成半IPN，以及锂二次电池，其包含相同。粘合剂对电极的粘合性优异，耐电解质性优异，伸长率提高，因此可以防止电极活性物质与反复充放电循环中发生的集电体剥离或分离。结果，二次电池的容量或功率可以保持在一个恒定的水平。

4. 发明申请

US20090305139A1 Electrode material containing mixture of polyvinyl alcohol of high degree of polymerization and polyvinyl pyrrolidone as binder and lithium secondary 有权
标题翻译：含有高聚合度的聚乙烯醇和聚乙烯吡咯烷酮作为粘合剂和锂二次混合物的电极材料
公开(公告)号：US20090305139A1
公开(公告)日：2009-12-10
申请号：US12310700
申请日：2007-08-24
申请人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , SeungRim Yang , Min Ho Cho
发明人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Ki Woo Chun , Minjung Ryu , SeungRim Yang , Min Ho Cho
IPC分类号： H01M4/58 , H01M4/62 , H01M4/02
CPC分类号： H01M10/052 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/621 , H01M4/622 , H01M10/0525
摘要： An electrode mix comprising a mixture of a polyvinyl alcohol with polyvinyl pyrrolidone as a binder and a lithium secondary battery comprising the same are disclosed. The electrode mix and lithium secondary battery according to the present invention enable stable maintenance of adhesion between active materials and/or adhesion between the active material and current collector and reduction of volumetric changes of anode active materials during repeated charge/discharge cycles, through the use of a polymer having an improved elongation percentage while exhibiting very high adhesive strength, as a binder of an electrode mix. Therefore, the present invention enables production of a large-capacity lithium secondary battery particularly using a silicon- or tin-based anode active material.
摘要翻译：公开了包含聚乙烯醇与聚乙烯吡咯烷酮作为粘合剂的混合物的电极混合物和包含该混合物的锂二次电池。根据本发明的电极混合物和锂二次电池能够稳定地维持活性材料之间的粘附和/或活性材料与集电体之间的粘附，并且通过使用在反复充电/放电循环期间减少阳极活性材料的体积变化的具有改善的伸长率的聚合物，同时具有非常高的粘合强度，作为电极混合物的粘合剂。因此，本发明能够特别使用硅或锡系阳极活性物质制造大容量锂二次电池。

5. 发明授权

US08585921B2 Electrode material containing polyvinyl alcohol as binder and rechargeable lithium battery comprising the same 有权
标题翻译：含有聚乙烯醇作为粘合剂的电极材料和包含其的可再充电锂电池
公开(公告)号：US08585921B2
公开(公告)日：2013-11-19
申请号：US11622834
申请日：2007-01-12
申请人： Minjung Ryu , Young-Min Kim , Eun-Suok Oh , SeungRim Yang , Juhyun Kim , Ki Woo Chun , ChanHong Lee , Ki-Young Lee , Seo-Jae Lee , JongMoon Jin , Taeyeon Kim
发明人： Minjung Ryu , Young-Min Kim , Eun-Suok Oh , SeungRim Yang , Juhyun Kim , Ki Woo Chun , ChanHong Lee , Ki-Young Lee , Seo-Jae Lee , JongMoon Jin , Taeyeon Kim
IPC分类号： H01M4/13 , C01B31/16
CPC分类号： H01M4/621 , H01M4/0404 , H01M4/386 , H01M4/387 , H01M4/587 , H01M4/622 , H01M10/052 , H01M2004/027
摘要： Provided is an electrode mix for a secondary battery containing an electrode active material, comprising a PVA having a degree of polymerization of more than 2500 and a degree of saponification of more than 90% as a binder, and a lithium secondary battery comprising the same. Use of the binder according to the present invention can provide advantageous effects such as improved adhesive strength between the electrode mix and current collector and between the electrode mixes, prevention of the peeling and separation of the active material even after repeated charge/discharge cycles, and inhibition of decreases in the capacity or output power retention rate of the secondary battery.
摘要翻译：本发明提供一种含有电极活性物质的二次电池的电极混合物，其包含聚合度大于2500，聚合度大于90％的PVA作为粘合剂，以及包含该电极活性物质的锂二次电池。根据本发明的粘合剂的使用可以提供有益效果，例如电极混合物和集电器之间以及电极混合物之间的粘合强度的改善，即使在重复的充电/放电循环之后也防止了活性材料的剥离和分离，以及抑制二次电池的容量或输出功率保持率的降低。

6. 发明申请

US20070264568A1 ELECTRODE MATERIAL CONTAINING POLYVINYL ALCOHOL AS BINDER AND RECHARGEABLE LITHIUM BATTERY COMPRISING THE SAME 有权
标题翻译：含有聚乙烯醇的电极材料作为粘合剂和包含其的可充电锂电池
公开(公告)号：US20070264568A1
公开(公告)日：2007-11-15
申请号：US11622834
申请日：2007-01-12
申请人： Minjung Ryu , Young-Min Kim , Eun-Suok Oh , SeungRim Yang , Juhyun Kim , Ki Woo Chun , ChanHong Lee , Ki-Young Lee , Seo-Jae Lee , JongMoon Jin , Taeyeon Kim
发明人： Minjung Ryu , Young-Min Kim , Eun-Suok Oh , SeungRim Yang , Juhyun Kim , Ki Woo Chun , ChanHong Lee , Ki-Young Lee , Seo-Jae Lee , JongMoon Jin , Taeyeon Kim
IPC分类号： H01M4/60
CPC分类号： H01M4/621 , H01M4/0404 , H01M4/386 , H01M4/387 , H01M4/587 , H01M4/622 , H01M10/052 , H01M2004/027
摘要： Provided is an electrode mix for a secondary battery containing an electrode active material, comprising a PVA having a degree of polymerization of more than 2500 and a degree of saponification of more than 90% as a binder, and a lithium secondary battery comprising the same. Use of the binder according to the present invention can provide advantageous effects such as improved adhesive strength between the electrode mix and current collector and between the electrode mixes, prevention of the peeling and separation of the active material even after repeated charge/discharge cycles, and inhibition of decreases in the capacity or output power retention rate of the secondary battery.
摘要翻译：本发明提供一种含有电极活性物质的二次电池的电极混合物，其包含聚合度大于2500，聚合度大于90％的PVA作为粘合剂，以及包含该电极活性物质的锂二次电池。根据本发明的粘合剂的使用可以提供有益效果，例如电极混合物和集电器之间以及电极混合物之间的粘合强度的改善，即使在重复的充电/放电循环之后也防止了活性材料的剥离和分离，以及抑制二次电池的容量或输出功率保持率的降低。

7. 发明授权

US08053113B2 Composite binder containing carbon nanotube and lithium secondary battery employing the same 有权
标题翻译：含有碳纳米管的复合粘合剂和使用其的锂二次电池
公开(公告)号：US08053113B2
公开(公告)日：2011-11-08
申请号：US11515081
申请日：2006-09-01
申请人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Minjung Ryu , SeungRim Yang
发明人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Minjung Ryu , SeungRim Yang
IPC分类号： H01M4/13
CPC分类号： H01M4/621 , H01M4/133 , H01M4/134 , H01M4/587 , H01M10/052
摘要： Provided is a nanocomposite binder for an electrode mix of a secondary battery, comprising carbon nanotubes in a photo- and/or thermo-polymerizable material or polymer, or a mixture thereof; and a lithium secondary battery comprising the same.The carbon nanotube-containing composite binder according to the present invention and a lithium secondary battery comprising the same employs a novel nanocomposite, prepared by combination of carbon nanotubes with a conventional binder material, as a binder of an anode. As a result, the present invention provides advantages such as improved conductivity of the anode due to decreased electrical resistance of the binder, and enhanced mechanical properties of the binder and thereby being capable of preventing the separation of an anode active material layer from a current collector due to volume changes occurring upon charge/discharge cycles.
摘要翻译：本发明提供一种用于二次电池的电极混合物的纳米复合粘合剂，其包含光 - 和/或热可聚合材料或聚合物中的碳纳米管或其混合物; 和包含该锂二次电池的锂二次电池。根据本发明的含碳纳米管复合粘合剂和包含该纳米复合材料的锂二次电池使用通过碳纳米管与常规粘合剂材料组合制备的新型纳米复合材料作为阳极的粘合剂。结果，本发明提供了优点，例如由于粘合剂的电阻降低导致阳极的导电性提高，粘合剂的机械性能的提高，从而能够防止阳极活性物质层与集电体分离由于充放电循环时发生体积变化。

8. 发明申请

US20070202403A1 Composite binder containing carbon nanotube and lithium secondary battery employing the same 有权
标题翻译：含有碳纳米管的复合粘合剂和使用其的锂二次电池
公开(公告)号：US20070202403A1
公开(公告)日：2007-08-30
申请号：US11515081
申请日：2006-09-01
申请人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Minjung Ryu , SeungRim Yang
发明人： Eun-Suok Oh , Young-Min Kim , Juhyun Kim , Minjung Ryu , SeungRim Yang
IPC分类号： H01M4/62 , H01M4/58 , H01B1/24
CPC分类号： H01M4/621 , H01M4/133 , H01M4/134 , H01M4/587 , H01M10/052
摘要： Provided is a nanocomposite binder for an electrode mix of a secondary battery, comprising carbon nanotubes in a photo- and/or thermo-polymerizable material or polymer, or a mixture thereof; and a lithium secondary battery comprising the same. The carbon nanotube-containing composite binder according to the present invention and a lithium secondary battery comprising the same employs a novel nanocomposite, prepared by combination of carbon nanotubes with a conventional binder material, as a binder of an anode. As a result, the present invention provides advantages such as improved conductivity of the anode due to decreased electrical resistance of the binder, and enhanced mechanical properties of the binder and thereby being capable of preventing the separation of an anode active material layer from a current collector due to volume changes occurring upon charge/discharge cycles.
摘要翻译：本发明提供一种用于二次电池的电极混合物的纳米复合粘合剂，其包含光 - 和/或热可聚合材料或聚合物中的碳纳米管或其混合物; 和包含该锂二次电池的锂二次电池。根据本发明的含碳纳米管复合粘合剂和包含该纳米复合材料的锂二次电池使用通过碳纳米管与常规粘合剂材料组合制备的新型纳米复合材料作为阳极的粘合剂。结果，本发明提供了优点，例如由于粘合剂的电阻降低导致阳极的导电性提高，粘合剂的机械性能的提高，从而能够防止阳极活性物质层与集电体分离由于充放电循环时发生体积变化。

9. 发明申请

US20060257740A1 Lithium secondary battery containing silicon-based or tin-based anode active material 有权
公开(公告)号：US20060257740A1
公开(公告)日：2006-11-16
申请号：US11402598
申请日：2006-04-12
申请人： Young-Min Kim , Eun-Suok Oh , Juhyun Kim , Minjung Ryu
发明人： Young-Min Kim , Eun-Suok Oh , Juhyun Kim , Minjung Ryu
IPC分类号： H01M4/62 , H01M4/58
CPC分类号： H01M10/052 , H01M4/02 , H01M4/0404 , H01M4/134 , H01M4/386 , H01M4/387 , H01M4/621 , H01M4/622 , H01M4/70 , H01M2004/027
摘要： Provided is a lithium secondary battery comprising an anode mix including a silicon- or tin-based material as an anode active material, and as a binder, a photo-polymerizable material composed of one or more monomers selected from the group consisting of an epoxy derivative, polyester acrylate and epoxy acrylate, or oligomers or polymers thereof, wherein an anode can be prepared within a short period of time via a simplified manufacturing process by applying the anode mix to a current collector and polymerizing the applied anode mix with light-irradiation, and further, superior charge/discharge cycle characteristics of the battery are provided due to stable maintenance of binding between active materials and between the active material and current collector, regardless of significant volume changes of the anode active material occurring upon charging/discharging the battery.

10. 发明授权

US07611802B2 Lithium secondary battery containing silicon-based or tin-based anode active material 有权
标题翻译：含有硅基或锡基阳极活性材料的锂二次电池
公开(公告)号：US07611802B2
公开(公告)日：2009-11-03
申请号：US11396762
申请日：2006-04-03
申请人： Young-Min Kim , Eun-Suok Oh , Juhyun Kim , Minjung Ryu
发明人： Young-Min Kim , Eun-Suok Oh , Juhyun Kim , Minjung Ryu
IPC分类号： H01M4/58 , H01M4/62
CPC分类号： H01M4/621 , H01M4/0435 , H01M4/0471 , H01M4/386 , H01M4/387 , H01M4/622 , H01M10/052 , H01M10/0564 , H01M2004/027
摘要： Provided is a lithium secondary battery comprising an anode mix including a silicon- or tin-based material as an anode active material, and as a binder, a photo-polymerizable material composed of one or more monomers selected from the group consisting of an epoxy derivative, polyester acrylate and epoxy acrylate, or oligomers or polymers thereof, wherein an anode can be prepared within a short period of time via a simplified manufacturing process by applying the anode mix to a current collector and polymerizing the applied anode mix with light-irradiation, and further, superior charge/discharge cycle characteristics of the battery are provided due to stable maintenance of binding between active materials and between the active material and current collector, regardless of significant volume changes of the anode active material occurring upon charging/discharging the battery.
摘要翻译：本发明提供一种锂二次电池，其包含阳极混合物，其包含作为负极活性物质的硅或锡基材料，作为粘合剂，由一种或多种选自以下的单体组成的光聚合材料：环氧衍生物，聚酯丙烯酸酯和环氧丙烯酸酯，或其低聚物或聚合物，其中通过将阳极混合物施加到集电器并通过光照射聚合所施加的阳极混合物，可以通过简化的制造工艺在短时间内制备阳极，此外，由于在活性材料之间和活性材料与集电器之间的稳定的维持下，提供了电池优异的充电/放电循环特性，而不管在对电池充电/放电时发生的阳极活性材料的显着的体积变化。

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