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1. 发明授权

US08546519B2 Polyketal compounds, synthesis, and applications 有权
标题翻译：聚缩酮化合物，合成和应用
公开(公告)号：US08546519B2
公开(公告)日：2013-10-01
申请号：US12682267
申请日：2008-10-09
申请人： Sergey Selifonov , Scott D. Rothstein , Douglas A. Wicks , Brian D. Mullen , Tara J. Mullen , Jason D. Pratt , Charles T. Williams , Chunyong Wu , Ning Zhou
发明人： Sergey Selifonov , Scott D. Rothstein , Douglas A. Wicks , Brian D. Mullen , Tara J. Mullen , Jason D. Pratt , Charles T. Williams , Chunyong Wu , Ning Zhou
IPC分类号： C08G4/00 , C08G63/00 , C08G65/34
CPC分类号： C08G63/672 , C07D493/04 , C07D493/06 , C07D493/10 , C07D493/12 , C08L25/06 , C08L27/06 , C08L59/00 , C08L67/04 , C08L2666/14 , C08L2666/04
摘要： The invention relates to polyketal compounds. The compounds are synthesized by the selective ketalization of oxocarboxylic acids, e.g. keto acids and semialdehydes, and esters thereof with tetrols and higher polyols that products two or more cyclic ketal ester moieties per molecule, wherein the cyclic ketal moieties are situated in a bis-, tris-, or polyketal conformation. The invention further relates to applications of these compounds and subsequent reactions thereof.
摘要翻译：本发明涉及聚缩酮化合物。这些化合物是通过氧化羧酸的选择性缩酮化合成的。酮酸和半醛，以及其与四元醇和高级多元醇的酯，其每分子产生两个或多个环状缩酮酯部分，其中环状缩酮部分位于双 - ，三 - 或多缩醛构象。本发明还涉及这些化合物的应用及其后续反应。

2. 发明授权

US08604223B2 Method of making ketals and acetals 有权
标题翻译：缩酮和缩醛的制备方法
公开(公告)号：US08604223B2
公开(公告)日：2013-12-10
申请号：US12757065
申请日：2010-04-09
申请人： Sergey Selifonov , Scott D. Rothstein , Brian D. Mullen
发明人： Sergey Selifonov , Scott D. Rothstein , Brian D. Mullen
IPC分类号： C07D317/20
CPC分类号： C07D407/12 , C07D317/14
摘要： The reaction of alcohols with oxocarboxylates to form acetals or ketals is catalyzed by unexpectedly low levels of protic acids. By employing low acid catalyst levels compared to amounts conventionally used, rapid formation of acetal or ketal is facilitated while the formation of oxocarboxylate esters is minimized. Further employing a significant molar excess of oxocarboxylate in conjunction with low acid catalyst level gives rise to the rapid and clean formation of acetals and ketals from oxocarboxylates and alcohols.
摘要翻译：醇与氧代羧酸酯反应形成缩醛或缩酮反应由意想不到的低水平的质子酸催化。通过使用与常规使用的量相比低的酸催化剂水平，促进缩醛或缩酮的快速形成，同时氧化羧酸酯的形成最小化。进一步使用显着摩尔过量的氧代羧酸酯与低酸催化剂水平相结合，导致来自氧代羧酸酯和醇的缩醛和缩酮的快速和清洁的形成。

3. 发明申请

US20100292491A1 Method of Making Ketals and Acetals 有权
标题翻译：制品和缩醛的方法
公开(公告)号：US20100292491A1
公开(公告)日：2010-11-18
申请号：US12757065
申请日：2010-04-09
申请人： Sergey Selifonov , Scott D. Rothstein , Brian D. Mullen
发明人： Sergey Selifonov , Scott D. Rothstein , Brian D. Mullen
IPC分类号： C07D407/12 , C07D307/16
CPC分类号： C07D407/12 , C07D317/14
摘要： The reaction of alcohols with oxocarboxylates to form acetals or ketals is catalyzed by unexpectedly low levels of protic acids. By employing low acid catalyst levels compared to amounts conventionally used, rapid formation of acetal or ketal is facilitated while the formation of oxocarboxylate esters is minimized. Further employing a significant molar excess of oxocarboxylate in conjunction with low acid catalyst level gives rise to the rapid and clean formation of acetals and ketals from oxocarboxylates and alcohols.
摘要翻译：醇与氧代羧酸酯反应形成缩醛或缩酮反应由意想不到的低水平的质子酸催化。通过使用与常规使用的量相比低的酸催化剂水平，促进缩醛或缩酮的快速形成，同时氧化羧酸酯的形成最小化。进一步使用显着摩尔过量的氧代羧酸酯与低酸催化剂水平相结合，导致来自氧代羧酸酯和醇的缩醛和缩酮的快速和清洁的形成。

4. 发明授权

US08569523B2 Method of making ketals and acetals 有权
公开(公告)号：US08569523B2
公开(公告)日：2013-10-29
申请号：US12757065
申请日：2010-04-09
申请人： Sergey Selifonov , Scott D. Rothstein , Brian D. Mullen
发明人： Sergey Selifonov , Scott D. Rothstein , Brian D. Mullen
IPC分类号： C07D317/20
摘要： The reaction of alcohols with oxocarboxylates to form acetals or ketals is catalyzed by unexpectedly low levels of protic acids. By employing low acid catalyst levels compared to amounts conventionally used, rapid formation of acetal or ketal is facilitated while the formation of oxocarboxylate esters is minimized. Further employing a significant molar excess of oxocarboxylate in conjunction with low acid catalyst level gives rise to the rapid and clean formation of acetals and ketals from oxocarboxylates and alcohols.

5. 发明申请

US20130085201A1 KETAL LACTONES AND STEREOSPECIFIC ADDUCTS OF OXOCARBOXYLIC KETALS WITH TRIMETHYLOL COMPOUNDS, POLYMERS CONTAINING THE SAME, METHODS OF MANUFACTURE, AND USES THEREOF 审中-公开
标题翻译：含三羧甲基化合物的聚氧乙烯酮的硬脂酸酯和立体化学添加剂，含有它们的聚合物，制造方法及其用途
公开(公告)号：US20130085201A1
公开(公告)日：2013-04-04
申请号：US13497345
申请日：2010-09-27
申请人： Sergey Selifonov , Ning Zhou , Brian D. Mullen
发明人： Sergey Selifonov , Ning Zhou , Brian D. Mullen
IPC分类号： C07D493/08 , C08G63/06 , C08L67/04 , C07D319/06 , C07D493/18
CPC分类号： C07D493/08 , C07D319/06 , C07D493/18 , C08G18/4269 , C08G63/06 , C08G63/664 , C08L67/04
摘要： Ketal lactones of and methods for making such ketal lactones are disclosed. Also described are methods for making isolated cis- and trans-stereoisomers of hydroxyester ketals of oxocarboxylic acids and polymers having ketal units of such stereoisomers within the polymer backbone.
摘要翻译：公开了酮缩酮内酯和制备此类缩酮内酯的方法。还描述了在聚合物主链中制备具有氧代羧酸的羟酯缩酮的分离的顺式和反式立体异构体和具有这种立体异构体的缩酮单元的聚合物的方法。

6. 发明申请

US20120118201A1 POLYKETAL ADDUCTS, METHODS OF MANUFACTURE AND USES THEREOF 有权
标题翻译：聚酮制剂，制造方法及其用途
公开(公告)号：US20120118201A1
公开(公告)日：2012-05-17
申请号：US13294690
申请日：2011-11-11
申请人： Brian D. Mullen , Marc D. Scholten , Tara J. Mullen , Cora M. Leibig , Vivek Badarinarayana
发明人： Brian D. Mullen , Marc D. Scholten , Tara J. Mullen , Cora M. Leibig , Vivek Badarinarayana
IPC分类号： C08K5/1565 , C08L67/04 , C08L27/06 , C08L23/00 , C08L69/00 , C08L79/08 , C08L25/06 , C08L77/00 , C08L1/02 , C08L81/04 , C08L81/06 , C07D407/12 , C08L83/04
CPC分类号： C07D407/12 , C08K5/1565 , C08L59/02 , C08L77/00 , C08L79/08 , Y02P20/582 , C08L27/06
摘要： Disclosed herein is a polyketal adduct obtained by forming an ester between a hydrocarbon polyol and a ketocarboxylic acid to produce an intermediate polyketocarboxylic ester. The intermediate polyketocarboxylic ester can be purified via crystallization to achieve purities of greater than 99.0% and then ketalized to produce the polyketal adduct, which can be used in polymer compositions. The polyketal adduct I is obtained at high purity and at high yield.
摘要翻译：本文公开了通过在烃多元醇和酮羧酸之间形成酯以产生中间体多酮羧酸酯而获得的聚缩酮加成物。可以通过结晶纯化中间体多酮羧酸酯以实现大于99.0％的纯度，然后缩醛化以产生可用于聚合物组合物中的聚缩酮加合物。以高纯度和高收率获得聚缩酮加成物I.

7. 发明授权

US09212176B2 Polyketal adducts, methods of manufacture and uses thereof 有权
标题翻译：聚缩酮加成物，其制造方法和用途
公开(公告)号：US09212176B2
公开(公告)日：2015-12-15
申请号：US13294690
申请日：2011-11-11
申请人： Brian D. Mullen , Marc D. Scholten , Tara J. Mullen , Cora M. Leibig , Vivek Badarinarayana , Matthew J. Tjosaas
发明人： Brian D. Mullen , Marc D. Scholten , Tara J. Mullen , Cora M. Leibig , Vivek Badarinarayana , Matthew J. Tjosaas
IPC分类号： C07D407/12 , C08K5/1565 , C08L79/08 , C08L77/00 , C08L59/02
CPC分类号： C07D407/12 , C08K5/1565 , C08L59/02 , C08L77/00 , C08L79/08 , Y02P20/582 , C08L27/06
摘要： Disclosed herein is a polyketal adduct obtained by forming an ester between a hydrocarbon polyol and a ketocarboxylic acid to produce an intermediate polyketocarboxylic ester. The intermediate polyketocarboxylic ester can be purified via crystallization to achieve purities of greater than 99.0% and then ketalized to produce the polyketal adduct, which can be used in polymer compositions. The polyketal adduct I is obtained at high purity and at high yield.
摘要翻译：本文公开了通过在烃多元醇和酮羧酸之间形成酯以产生中间体多酮羧酸酯而获得的聚缩酮加成物。可以通过结晶纯化中间体多酮羧酸酯以实现大于99.0％的纯度，然后缩醛化以产生可用于聚合物组合物中的聚缩酮加合物。以高纯度和高收率获得聚缩酮加成物I.

8. 发明授权

US09271034B2 Adding content during data stream acquisition 有权
标题翻译：在数据流采集期间添加内容
公开(公告)号：US09271034B2
公开(公告)日：2016-02-23
申请号：US12640818
申请日：2009-12-17
申请人： Yeqing Wang , Brian D. Mullen
发明人： Yeqing Wang , Brian D. Mullen
IPC分类号： H04N7/10 , H04N21/438 , H04N21/44 , H04N21/81 , H04N21/433
CPC分类号： H04N21/8126 , H04N21/4331 , H04N21/4384 , H04N21/44016 , H04N21/812
摘要： A device is provided for use with extended content data on a first data stream and second content data on a second data stream. The device includes a processing portion, an acquisition portion and a buffer. The acquisition portion is in communication with the processing portion. The acquisition portion can acquire the first data stream, can transition to the second data stream to receive the second content data and can provide the second content data to the processing portion. The buffer can receive the extended content data. The processing portion can instruct the acquisition portion to transition from the first data stream to the second data stream to receive the second content data. The buffer can further provide the extended content data to the processing portion based on the acquisition portion transitioning from the first data stream to the second data stream. The processing portion can further process the extended content data portion as received from the buffer.
摘要翻译：提供了一种用于第一数据流上的扩展内容数据和第二数据流上的第二内容数据的设备。该设备包括处理部分，获取部分和缓冲器。采集部与处理部进行通信。获取部分可以获取第一数据流，可以转换到第二数据流以接收第二内容数据，并且可以向处理部分提供第二内容数据。缓冲区可以接收扩展内容数据。处理部分可以指示采集部分从第一数据流转换到第二数据流以接收第二内容数据。缓冲器可以基于从第一数据流到第二数据流的获取部分转换，进一步向处理部分提供扩展内容数据。处理部分可以进一步处理从缓冲器接收到的扩展内容数据部分。

9. 发明申请

US20130081078A1 Method for Tag Insertion and Notification for DVR Addressable Advertisement 有权
标题翻译： DVR可寻址广告的标签插入和通知方法
公开(公告)号：US20130081078A1
公开(公告)日：2013-03-28
申请号：US13246909
申请日：2011-09-28
申请人： Christopher S. Del Sordo , Brian J. Copley , Brian D. Mullen , Scott D. Sellers , Jay W. Strater , Yeqing Wang
发明人： Christopher S. Del Sordo , Brian J. Copley , Brian D. Mullen , Scott D. Sellers , Jay W. Strater , Yeqing Wang
IPC分类号： H04N21/85
CPC分类号： G06Q30/0241 , H04N21/4331 , H04N21/44016 , H04N21/44222 , H04N21/4532 , H04N21/6582 , H04N21/812
摘要： A method and computing device that provides viewer impression data for a recorded digital video stream. The method receives a digital video stream as a series of segments, and stores it as a recorded digital video stream having a transition between two consecutive segments at a transition position. The method stores a notification tag that is associated with the transition, and that includes a tag position in the recorded digital video stream, a notification mode, and tag data. During playback of the recorded digital video stream, the method generates a play mode status event, and generates a transition notification when the playback encounters the notification tag and, based on the notification mode, the transition associated with the notification tag. The method collects viewer impression data for one of the two consecutive segments from the play mode status event and the transition notification.
摘要翻译：一种为记录的数字视频流提供观看者印象数据的方法和计算装置。该方法将数字视频流作为一系列段接收，并将其作为在转换位置处具有在两个连续段之间的转变的记录的数字视频流存储。该方法存储与转换相关联的通知标签，并且其包括记录的数字视频流中的标签位置，通知模式和标签数据。在重放记录的数字视频流期间，该方法产生播放模式状态事件，并且当播放遇到通知标签时，并且基于通知模式，生成与通知标签相关联的转变的转换通知。该方法从播放模式状态事件和转换通知收集两个连续段中的一个的观看者印象数据。

10. 发明授权

US07652083B2 Thermoplastic compostions, methods of making, and articles formed therefrom 有权
标题翻译：热塑性组合物，制造方法和由其形成的制品
公开(公告)号：US07652083B2
公开(公告)日：2010-01-26
申请号：US11736262
申请日：2007-04-17
申请人： Brian D. Mullen
发明人： Brian D. Mullen
IPC分类号： C08L69/00 , C08G64/14
CPC分类号： C08G64/14 , C08K5/0066 , C08K5/42 , C08K5/549 , C08L69/00 , C08L2666/84
摘要： A thermoplastic composition comprises a polycarbonate having repeating structural carbonate units of the formula (1): wherein at least 60 percent of the total number of R1 groups contain aromatic organic groups and the balance thereof are aliphatic, alicyclic, or aromatic groups; and wherein the polycarbonate comprises terminal groups derived from reaction with a cyanophenol of the formula wherein Y is a halogen, C1-3 alkyl group, C1-3 alkoxy group, C7-12 arylalkyl, C7-12 alkylaryl, or nitro group, y is 0 to 4, and c is 1 to 5, provided that y+c is 1 to 5; a branching agent; and a flame retardant. The compositions are useful in the manufacture of a wide variety of parts, particularly those having a thin wall.
摘要翻译：热塑性组合物包含具有式（1）的重复结构碳酸酯单元的聚碳酸酯：其中R1基团总数的至少60％含有芳族有机基团，其余为脂族，脂环族或芳族基团; 并且其中所述聚碳酸酯包含衍生自下式的氰基苯酚的端基：其中Y是卤素，C 1-3烷基，C 1-3烷氧基，C 7-12芳基烷基，C 7-12烷基芳基或硝基，y是 0〜4，c为1〜5，条件是y + c为1〜5; 支链剂; 和阻燃剂。组合物可用于制造各种各样的部件，特别是具有薄壁的部件。

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