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    • 1. 发明申请
    • Method for producing (meth) acrylic acid
    • US20050192464A1
    • 2005-09-01
    • US11061019
    • 2005-02-18
    • Seong KangSeok ChoiKyoung HaGeon KimBoo WooSang LeeYoung KimKoo Kang
    • Seong KangSeok ChoiKyoung HaGeon KimBoo WooSang LeeYoung KimKoo Kang
    • C07C51/43C07C51/42C07C51/48
    • C07C51/48C07C57/04
    • The present invention relates to a method for producing (meth)acrylic acid comprising a process of recovering (meth)acrylic acid as an aqueous (meth)acrylic acid from a (meth)acrylic acid-containing gas mixture produced by the catalytic gas phase oxidation of at least one reactant selected from the group consisting of propane, propylene, isobutylene and (meth)acrolein, and a system usable for the method. The recovery process comprises the steps of: (1) feeding the (meth)acrylic acid-containing gas mixture into a quenching tower and condensing it in the quenching tower so as to recover an aqueous (meth)acrylic acid solution from the bottom of the quenching tower, in which some of the recovered aqueous solution of (meth)acrylic acid is recycled to the top part of the quenching tower so as to condense the (meth)acrylic acid-containing gas mixture; (2) passing the uncondensed part of the (meth)acrylic acid-containing gas mixture from the quenching tower through the top of the quenching tower to an absorption column; (3) absorbing (meth)acrylic acid contained in the uncondensed part of the (meth)acrylic acid-containing gas mixture in the absorption column with a absorption solvent; (4) feeding the (meth)acrylic acid solution resulting from the absorption in the step (3) to a desorption column; and (5) separating the solvent used in the step (3) from the (meth)acrylic acid solution in the desorption column, so that the substance from which the solvent has been removed in the desorption column is fed to the quenching tower, and the separated solvent is recycled to the absorption column. The inventive method is an efficient and economic method which allows a reduction in energy consumption in subsequent purification processes by maximizing the concentration of an aqueous solution of (meth)acrylic solution recovered at the bottom of the quenching tower and minimizing the concentration of (meth)acrylic acid lost from the vent gas of the absorption column.
    • 3. 发明申请
    • Method of producing unsaturated acid from olefin
    • 从烯烃生产不饱和酸的方法
    • US20060211884A1
    • 2006-09-21
    • US11378438
    • 2006-03-17
    • Boo WooJun KoKyoung HaSeong KangSeok ChoiYoung Kim
    • Boo WooJun KoKyoung HaSeong KangSeok ChoiYoung Kim
    • C07C51/16C07C51/235
    • B01J8/067B01J2208/00212B01J2208/025C07C51/215C07C51/252C07C57/04
    • Disclosed is a shell-and-tube heat exchanger type reactor that can be used for a process of producing unsaturated acids from olefins via fixed-bed catalytic partial oxidation, which comprises at least one reaction tube, each including at least one first-step catalyst layer, in which olefins are oxidized by a first-step catalyst to mainly produce unsaturated aldehydes, and at least two second-step catalyst layers, in which the unsaturated aldehydes are oxidized by a second-step catalyst to produce unsaturated acids, wherein a first catalyst layer of the second-step catalyst layers, disposed right adjacent to the first-step catalyst layer, has an activity corresponding to 5˜30% of the activity of the catalyst layer having a highest activity among the second-step catalyst layers. A method of producing unsaturated acids from olefins by using the reactor is also disclosed.
    • 公开了一种壳管式热交换器型反应器,其可用于通过固定床催化部分氧化由烯烃生产不饱和酸的方法,其包括至少一个反应管,每个反应管包含至少一个第一步催化剂 层,其中烯烃被第一步催化剂氧化以主要产生不饱和醛,以及至少两个第二步催化剂层,其中不饱和醛被第二步催化剂氧化以产生不饱和酸,其中第一 与第一级催化剂层相邻设置的第二级催化剂层的催化剂层具有相当于第二级催化剂层中活性最高的催化剂层的活性的5〜30%的活性。 还公开了通过使用反应器由烯烃生产不饱和酸的方法。
    • 6. 发明申请
    • Method of producing unsaturated acid in fixed-bed catalytic partial oxidation reactor with high efficiency
    • 固定床催化部分氧化反应器高效生产不饱和酸的方法
    • US20070073084A1
    • 2007-03-29
    • US11483752
    • 2006-07-10
    • Kyoung HaBoo WooJun KoSeong KangSeok ChoiYoung Kim
    • Kyoung HaBoo WooJun KoSeong KangSeok ChoiYoung Kim
    • B01J8/04C07C51/16C07C51/235
    • C07C45/34B01J8/0453B01J8/0457B01J8/067B01J2208/00212B01J2208/0053B01J2208/025B01J2219/0004C07C45/35C07C45/36C07C45/37C07C51/215C07C51/252C07C47/21C07C47/22C07C57/04
    • Disclosed is a process for producing unsaturated aldehydes and/or unsaturated acids from olefins or alkanes in a fixed bed shell-and-tube heat exchanger-type reactor by catalytic vapor phase oxidation. A heat exchanger-type reactor for use in such a process is also disclosed. In the process, at least one of the first-step reaction zone and the second-step reaction zone is divided into two or more shell spaces by at least one partition; each of the divided shell spaces is independently heat-controlled; a heat transfer medium in the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone has a temperature ranging from the lowest active temperature of a catalyst layer packed in a reaction tube corresponding to the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone to [the lowest active temperature+20° C.], when referring to the two or more shell spaces corresponding to the first-step reaction zone sequentially as the first shell space of the first-step reaction zone, the second shell space of the first-step reaction zone, . . . , the nth shell space of the first-step reaction zone, and the two or more shell spaces corresponding to the second-step reaction zone sequentially as the first shell space of the second-step reaction zone, the second shell space of the second-step reaction zone, . . . , the nth shell space of the second-step reaction zone; and the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone is controlled in such a manner that the first shell space provides a reactant conversion contribution per length as defined in Equation 1 or 2 of 1.2˜2.5.
    • 公开了一种通过催化气相氧化在固定床管壳式热交换器型反应器中由烯烃或烷烃生产不饱和醛和/或不饱和酸的方法。 还公开了一种用于这种方法的热交换器型反应器。 在该过程中,至少一个第一步骤反应区和第二步反应区被至少一个隔板分成两个或多个壳层空间; 每个分开的壳空间是独立的热控制的; 在第一步骤反应区的第一壳体空间或第二阶段反应区的第一壳体空间中的传热介质的温度范围从填充在对应于第一步骤的反应管的反应管中的催化剂层的最低活性温度 当提及对应于第一步反应的两个或多个壳层空间时,第一步反应区的壳体空间或第二步反应区的第一壳空间为[最低活性温度+ 20℃] 作为第一步反应区的第一壳空间,第一步反应区的第二壳空间。 。 。 ,第一步反应区的第n个第<! - SIPO - >壳空间,以及对应于第二步反应区的两个或多个壳层空间依次作为第二步反应区的第一壳空间, 第二步反应区的第二个壳体空间。 。 。 ,第二步反应区的第n个壳空间; 并且以这样的方式控制第一步骤反应区或第二阶段反应区的第一壳层空间的第一壳层空间,使得第一壳空间提供如式1或2中定义的每个长度的反应物转化贡献 1.2〜2.5。
    • 7. 发明申请
    • Security router system and method of authenticating user who connects to the system
    • 安全路由器系统和连接系统认证用户的方法
    • US20060101261A1
    • 2006-05-11
    • US11220887
    • 2005-09-07
    • Sang LeeYong JeonYoung KimJeong KimJong Jang
    • Sang LeeYong JeonYoung KimJeong KimJong Jang
    • H04L9/00
    • H04L9/3226H04L63/083H04L63/1416
    • Provided are a security router system for a network and a method of authenticating a user who connects to the system. The security routing system includes: a plurality of physical link ports inputting/outputting packets; a physical layer matching unit transmitting/receiving packets to the physical link ports and generating a media access control (MAC) frame; and a network processor including routing processing means that establishes a transport route for input packets via the physical layer matching unit and processes routing protocols, packet forwarding means that forward the input packets to their destinations, intrusion detection means that classify the input packets based on a packet classification standard and determine whether the input packets are attacks from outside, and user authentication means that determine whether a user is authorized to connect to a router, thereby reducing expenses required to build a network while maintaining security in comparison with a conventional firewall or intrusion detection system, and increasing reliability and safety of the network by preventing harmful traffic since each router performs a network security function.
    • 提供了一种用于网络的安全路由器系统和用于认证连接到系统的用户的方法。 安全路由系统包括:多个物理链路端口输入/输出分组; 物理层匹配单元向物理链路端口发送/接收分组并生成媒体接入控制(MAC)帧; 以及网络处理器,包括经由所述物理层匹配单元建立用于输入分组的传输路由并处理路由协议的路由处理装置,将所述输入分组转发到其目的地的分组转发装置,基于所述输入分组对所述输入分组进行分类的入侵检测装置 分组分类标准,并确定输入分组是否是外部的攻击,用户认证意味着确定用户是否被授权连接到路由器,从而与常规防火墙或入侵相比,降低了构建网络所需的开销,同时保持了安全性 检测系统,以及由于每个路由器执行网络安全功能,防止有害的流量,从而提高网络的可靠性和安全性。
    • 9. 发明申请
    • Apparatus and method for computing SHA-1hash function
    • 用于计算SHA-1hash函数的装置和方法
    • US20050144204A1
    • 2005-06-30
    • US10917685
    • 2004-08-12
    • Yun LeeSung JunYoung ParkSang LeeYoung KimKyo II Chung
    • Yun LeeSung JunYoung ParkSang LeeYoung KimKyo II Chung
    • G06F7/06G06F7/00H04L9/32
    • H04L9/0643
    • An apparatus and method for computing a SHA-1 hash function value are provided. The apparatus includes a first register unit including a plurality of registers that store a first bit string of predetermined lengths for generation of a hash function value; a second register unit storing input data in units of second bit strings with predetermined lengths, and sequentially outputting the second bit strings; a third register unit performing an operation on the first bit string of the plurality of registers and the second bit strings output from the second register unit so as to generate and store a third bit string, and updating first-bit string of the plurality of registers based on the third bit string; and an adding unit combining the first bit string stored in the first register unit, the first bit string of the third bit string stored in the third register unit, and the original initial values stored in the first register unit so as to obtain a hash function value. Accordingly, it is possible to reduce the size of the apparatus and stably compute a hash function value at a high speed.
    • 提供了一种用于计算SHA-1散列函数值的装置和方法。 该装置包括:第一寄存器单元,包括多个寄存器,用于存储用于生成散列函数值的预定长度的第一位串; 第二寄存器单元,以预定长度的第二位串为单位存储输入数据,并顺序地输出第二位串; 第三寄存器单元,对所述多个寄存器中的第一位串执行操作,以及从所述第二寄存器单元输出的所述第二位串,以产生和存储第三位串,并且更新所述多个寄存器中的第一位串 基于第三位串; 以及添加单元,组合存储在第一寄存器单元中的第一位串,存储在第三寄存器单元中的第三位串的第一位串和存储在第一寄存器单元中的原始初始值,以获得散列函数 值。 因此,可以减小装置的尺寸并且可以高速稳定地计算散列函数值。