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1. 发明授权

US07160949B2 Olefin block copolymers, processes for producing the same and uses thereof 有权
标题翻译：烯烃嵌段共聚物，其制备方法及其用途
公开(公告)号：US07160949B2
公开(公告)日：2007-01-09
申请号：US10181553
申请日：2001-01-18
申请人： Seiji Ota , Satoru Moriya , Ryoji Mori , Taku Koda , Junji Tan , Shinichi Kojoh , Hideyuki Kaneko , Shunichi Hama , Tadahito Nobori , Tomoaki Matsugi , Norio Kashiwa
发明人： Seiji Ota , Satoru Moriya , Ryoji Mori , Taku Koda , Junji Tan , Shinichi Kojoh , Hideyuki Kaneko , Shunichi Hama , Tadahito Nobori , Tomoaki Matsugi , Norio Kashiwa
IPC分类号： C08L53/00
CPC分类号： B32B27/32 , B32B5/022 , B32B27/08 , B32B27/20 , B32B2535/00 , B32B2605/08 , C08F293/00 , C08F297/08 , C08J5/18 , C08J2353/00 , C08L53/00 , C08L2666/02
摘要： Olefin block copolymers (A-1) are disclosed represented by the formula (I) PO1-g1-B1 . . . (I) wherein PO1 is a segment comprised of repeating units derived from an olefin having 2 to 20 carbon atoms, g1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B1 is a segment containing an unsaturated hydrocarbon or a hetero atom. The olefin block copolymers are suitable for uses in adhesives, various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets, modifiers and dispersions.
摘要翻译：烯属嵌段共聚物（A-1）公开了由式（I）PO 1 - 1 - 1 - 1 - 1表示。。。（I）其中PO 1是由衍生自具有2至20个碳原子的烯烃的重复单元组成的链段，g 1是酯，醚，酰胺，酰亚胺，氨基甲酸酯，脲，甲硅烷基醚或羰基连接，B 1是含有不饱和烃或杂原子的链段。烯烃嵌段共聚物适合用于粘合剂，各种模制品如建筑和土木工程材料，汽车内饰和外部材料，汽油罐，电气和电子零件，医疗保健和卫生材料，杂货材料，树脂材料具有环境降解性能，薄膜和片材，改性剂和分散体。

2. 发明授权

US07393907B2 Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof 有权
标题翻译：含极性基团的烯烃共聚物，其制备方法，含有共聚物的热塑性树脂组合物及其用途
公开(公告)号：US07393907B2
公开(公告)日：2008-07-01
申请号：US10713278
申请日：2003-11-17
申请人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
发明人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
IPC分类号： C08F232/08
CPC分类号： C08F297/02 , C08F4/65912 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08J5/18 , C08J2351/06 , C08J2371/02 , C08J2387/00 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F4/65927 , C08F222/06 , C08F2500/03 , C08F2500/12 , C08F2500/09 , C08F216/00
摘要： The present invention is a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith. A process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof are also described. The polar group-containing olefin copolymer comprises a constituent unit derived from an α-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
摘要翻译：本发明是对金属或极性树脂具有优异的粘附性的极性基团的烯烃共聚物，与其相容性优异。还描述了制备共聚物的方法，含有共聚物的热塑性树脂组合物及其用途。含有极性基团的烯烃共聚物包含衍生自2-20个碳原子的α-烯烃的构成单元和衍生自具有极性基团的直链，支链或环状极性基团单体的构成单元例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

3. 发明授权

US07714087B2 Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof 有权
标题翻译：含极性基团的烯烃共聚物，其制备方法，含有共聚物的热塑性树脂组合物及其用途
公开(公告)号：US07714087B2
公开(公告)日：2010-05-11
申请号：US12153003
申请日：2008-05-12
申请人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
发明人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
IPC分类号： C08F232/08
CPC分类号： C08F297/02 , C08F4/65912 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08J5/18 , C08J2351/06 , C08J2371/02 , C08J2387/00 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F4/65927 , C08F222/06 , C08F2500/03 , C08F2500/12 , C08F2500/09 , C08F216/00
摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
摘要翻译：含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。含极性基团的烯烃共聚物可以通过在茂金属催化剂的存在下与含极性基团的单体和/或大分子单体进行聚合来制备。含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

4. 发明申请

US20090137757A1 Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof 有权
标题翻译：含极性基团的烯烃共聚物，其制备方法，含有共聚物的热塑性树脂组合物及其用途
公开(公告)号：US20090137757A1
公开(公告)日：2009-05-28
申请号：US12153003
申请日：2008-05-12
申请人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
发明人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
IPC分类号： C08F4/44
CPC分类号： C08F297/02 , C08F4/65912 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08J5/18 , C08J2351/06 , C08J2371/02 , C08J2387/00 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F4/65927 , C08F222/06 , C08F2500/03 , C08F2500/12 , C08F2500/09 , C08F216/00
摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
摘要翻译：含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。含极性基团的烯烃共聚物可以通过在金属茂催化剂的存在下将α-烯烃与含极性基团的单体和/或大分子单体进行聚合来制备。含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

5. 发明申请

US20090280318A1 OLEFIN POLYMER, COMPOSITION THEREOF AND ADHESIVE RESIN COMPRISING THE COMPOSITION 审中-公开
标题翻译： OLEFIN聚合物，其组合物和包含组合物的粘合树脂
公开(公告)号：US20090280318A1
公开(公告)日：2009-11-12
申请号：US12096655
申请日：2006-12-08
申请人： Tomoaki Matsugi , Junji Saito , Hideyuki Kaneko , Norio Kashiwa , Shin-ichi Kojoh , Takayuki Onogi , Motoaki Isokawa , Seiji Ota , Shigeyuki Yasui
发明人： Tomoaki Matsugi , Junji Saito , Hideyuki Kaneko , Norio Kashiwa , Shin-ichi Kojoh , Takayuki Onogi , Motoaki Isokawa , Seiji Ota , Shigeyuki Yasui
IPC分类号： B32B27/32 , C08F8/00 , C09J131/02
CPC分类号： C08L53/00 , C08F8/00 , C08F8/08 , C08F8/12 , C08F8/18 , C08F8/20 , C08F8/42 , C08F255/00 , C08F255/02 , C08F293/00 , C08F293/005 , C08F2810/50 , C08L23/0846 , C08L23/0884 , C08L23/0892 , C08L51/06 , C08L2205/02 , C08L2666/02 , C08L2666/14 , C09J123/02 , C09J123/0846 , C09J151/06 , C09J153/00 , Y10T428/263 , C08L2666/06 , C08F210/02 , C08F110/06 , C08F255/023 , C08F110/14 , C08F210/12
摘要： Provided is a new adhesive polyolefin resin composition, containing 1 to 100% by weight of a high polymer structure, that has good heat resistance and excellent adhesion performance to polyolefins and various polar materials, wherein a polyolefin segment (A) is bonded with an addition polymer segment (B) of a non-olefinic vinyl monomer and a reactive group is introduced into the addition polymer segment (B) and an adhesive or dispersion obtained therefrom.
摘要翻译：提供了一种新的粘合剂聚烯烃树脂组合物，其含有1至100重量％的高聚物结构，其具有良好的耐热性和对聚烯烃和各种极性材料的优异粘合性能，其中聚烯烃链段（A）与添加剂将非烯烃类乙烯基单体和反应性基团的聚合物链段（B）导入到加成聚合物链段（B）中，并由其获得粘合剂或分散体。

6. 发明申请

US20090136774A1 Resin Composition Comprising Olefinic Block polymer and Application Thereof 审中-公开
标题翻译：包含烯烃嵌段聚合物的树脂组合物及其应用
公开(公告)号：US20090136774A1
公开(公告)日：2009-05-28
申请号：US12225671
申请日：2007-03-28
申请人： Takayuki Onogi , Hideyuki Kaneko , Tomoaki Matsugi , Koutarou Suzuki , Nobou Kawahara , Seiji Ota , Shigeyuki Yasui
发明人： Takayuki Onogi , Hideyuki Kaneko , Tomoaki Matsugi , Koutarou Suzuki , Nobou Kawahara , Seiji Ota , Shigeyuki Yasui
IPC分类号： B32B27/08 , C08L53/00
CPC分类号： C08L23/12 , B32B27/08 , C08F293/00 , C08F293/005 , C08L23/02 , C08L23/0815 , C08L25/12 , C08L33/00 , C08L53/00 , C08L53/02 , C08L55/02 , C08L69/00 , C08L71/12 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/04 , C08L2666/14 , C09J153/00 , Y10T428/31913 , C08L2666/26 , C08L2666/24
摘要： The present invention is to provide a resin composition excellent in mechanical properties and solvent resistance, and the resin composition (C) of the present invention comprises an polyolefin (A1) and an olefinic block polymer (A2), wherein the olefinic block polymer (A2) comprises, as a constitutional unit, a block (a) which is a polyolefin component and a block (b) which is a polymer unit composed of a vinyl monomer having a solubility parameter of from 18 to 25 J/m and the block (a) and the block (b) are bonded each other by a covalent bond. Moreover, another invention of the present invention is to provide a laminated structure having a laminated configuration in which a layer comprising an olefinic polymer layer and a layer comprising other synthetic resins, a metal and the like are strongly bonded through an adhesive layer, wherein the adhesive layer comprises the resin composition (C).
摘要翻译：本发明提供机械性能和耐溶剂性优异的树脂组合物，本发明的树脂组合物（C）含有聚烯烃（A1）和烯烃嵌段聚合物（A2），其中烯烃嵌段聚合物（A2 ）包含作为结构单元的作为聚烯烃组分的嵌段（a）和作为由溶度参数为18〜25J / m的乙烯基单体构成的聚合物单元的嵌段（b）和嵌段 a）和嵌段（b）通过共价键彼此键合。此外，本发明的另一发明是提供一种层叠结构，其中包含烯属聚合物层的层和包含其它合成树脂，金属等的层通过粘合剂层牢固地结合，其中，粘合剂层包含树脂组合物（C）。

7. 发明申请

US20060204771A1 POLYESTER RESIN AND POLYESTER RESIN LAMINATE CONTAINER 有权
标题翻译：聚酯树脂和聚酯树脂层压容器
公开(公告)号：US20060204771A1
公开(公告)日：2006-09-14
申请号：US10567793
申请日：2004-05-31
申请人： Junji Tan , Yasuhiro Mutou , Seiji Ota , Toyoaki Sasaki
发明人： Junji Tan , Yasuhiro Mutou , Seiji Ota , Toyoaki Sasaki
IPC分类号： B32B27/36 , C08G63/02
CPC分类号： B32B27/08 , B32B27/36 , B32B2250/244 , B32B2270/00 , B32B2307/7242 , B32B2439/40 , B32B2439/70 , B32B2553/00 , C08G63/60 , Y10T428/31786
摘要： The present invention provides a polyester resin which comprises (a-1) 45 to 99% by mole of an oxycarboxylic acid unit having 5 carbon atoms or less, (a-2) 0.5 to 27.5% by mole of an aromatic dicarboxylic acid unit, and (a-3) 0.5 to 27.5% by mole of an aliphatic diol unit having 4 carbon atoms or less, and containing (a-1) to (a-3) in a total amount of 95% by mole or greater, wherein the relationship between the content of the oxycarboxylic acid, expressed as M % by mole, and the density ρ (kg/m3) of the polyester resin, satisfies the formula ρ≧1349+M×0.85.
摘要翻译：本发明提供一种聚酯树脂，其包含（a-1）45〜99摩尔％的碳原子数5以下的羟基羧酸单元，（a-2）0.5〜27.5摩尔％的芳香族二羧酸单元，和（a-3）0.5〜27.5摩尔％的碳原子数为4以下的脂肪族二醇单元，总计为95摩尔％以上的（a-1）〜（a-3）以M摩尔％表示的羟基羧酸的含量与聚酯树脂的密度rho（kg / m 3）之间的关系满足式rho = 1349 + Mx0.85 。

8. 发明授权

US08106132B2 Polyester resin composition 有权
标题翻译：聚酯树脂组合物
公开(公告)号：US08106132B2
公开(公告)日：2012-01-31
申请号：US10538750
申请日：2004-01-08
申请人： Junji Tan , Yasuhiro Mutou , Seiji Ota
发明人： Junji Tan , Yasuhiro Mutou , Seiji Ota
IPC分类号： C08G63/06 , C08G63/46 , C08G63/08
CPC分类号： C08G63/60 , C08G63/06 , C08L67/00 , C08L67/02 , C08L67/04 , C08L2666/18
摘要： There is provided by the present invention a polyester resin composition containing a copolyester having hydroxy carboxylic acid units as constituent units or a polyoxycarboxylic acid, wherein hydroxy carboxylic acid units of 5 or less carbon atoms are contained in amounts of 2 to 75% by mol based on 100% by mol of all the constituent units contained in the composition, and a molar ratio SAA of hydroxy carboxylic acid units both of whose neighboring units are hydroxy carboxylic acid units to all the hydroxy carboxylic acid units contained and a molar ratio SBB of hydroxy carboxylic acid units neither of whose neighboring units is a hydroxy carboxylic acid unit to all the hydroxy carboxylic acid units contained satisfy the following formula: 0.03
摘要翻译：本发明提供一种含有具有羟基羧酸单元作为构成单元的共聚酯或多元羧酸的聚酯树脂组合物，其中含有5〜5个碳原子的羟基羧酸单元的含量为2〜75摩尔％对于组合物中所含的全部构成单元为100摩尔％，羟基羧酸单元的羟基羧酸单元的摩尔比SAA为羟基羧酸单元与所有羟基羧酸单元的摩尔比SBB，羟基羧酸单元的摩尔比羧酸单元与所有羟基羧酸单元都不是羟基羧酸单元，它们都不满足下式：0.03

9. 发明授权

US07754813B2 Resin modifier and polar group-containing polymer composition containing the same 有权
标题翻译：含有该树脂改性剂和含极性基团的聚合物组合物
公开(公告)号：US07754813B2
公开(公告)日：2010-07-13
申请号：US10594091
申请日：2005-03-10
申请人： Shuichi Murakami , Seiji Ota , Junji Tan
发明人： Shuichi Murakami , Seiji Ota , Junji Tan
IPC分类号： C08F8/30 , C08L101/02 , C08L23/00
CPC分类号： C08F8/30 , C08L23/0815 , C08L23/10 , C08L51/06 , C08L53/00 , C08L53/02 , C08L67/00 , C08L2205/08 , C08F10/00 , C08L2666/02
摘要： A resin modifier (C) obtained by reacting a polyolefin (A) having a group which reacts with a carbodiimide group, and a carbodiimide group-containing compound (B), wherein the content of the carbodiimide group is from 1 to 200 mmol per 100 g of the resin modifier, and a polar group-containing polymer composition (F) comprising from 1 to 30% by weight of the resin modifier (C), from 99 to 20% by weight of a polar group-containing polymer (D), and from 0 to 80% by weight of an olefin polymer (E). The modifier can provide improved low-temperature impact resistance of a polymer alloy including a polar group-containing polymer and an olefin polymer (such as polylactic acid and polypropylene), and can provide a molded article with smooth surface when the polymer alloy is molded. A polar group-containing polymer composition is also set forth.
摘要翻译：通过使具有与碳二亚胺基反应的基团的聚烯烃（A）与含碳二亚胺基化合物（B）反应而得到的树脂改性剂（C），其中，碳二亚胺基的含量为100〜100mmol / 100 g的树脂改性剂和含有1〜30重量％的树脂改性剂（C）的含极性基团的聚合物组合物（F），99〜20重量％的含极性基团的聚合物（D），和0〜80重量％的烯烃聚合物（E）。改性剂可以提供包含含极性基团的聚合物和烯烃聚合物（例如聚乳酸和聚丙烯）的聚合物合金的改进的低温耐冲击性，并且可以在模制聚合物合金时提供具有光滑表面的模制品。还列出了含极性基团的聚合物组合物。

10. 发明授权

US07153587B2 Polyester resin and polyester resin laminate container 有权
标题翻译：聚酯树脂和聚酯树脂层压容器
公开(公告)号：US07153587B2
公开(公告)日：2006-12-26
申请号：US10567793
申请日：2004-05-31
申请人： Junji Tan , Yasuhiro Mutou , Seiji Ota , Toyoaki Sasaki
发明人： Junji Tan , Yasuhiro Mutou , Seiji Ota , Toyoaki Sasaki
IPC分类号： B32B27/36 , C08G63/06 , C08G63/12 , C08G63/16 , C08G63/183
CPC分类号： B32B27/08 , B32B27/36 , B32B2250/244 , B32B2270/00 , B32B2307/7242 , B32B2439/40 , B32B2439/70 , B32B2553/00 , C08G63/60 , Y10T428/31786
摘要： The present invention provides a polyester resin which comprises (a-1) 45 to 99% by mole of an oxycarboxylic acid unit having 5 carbon atoms or less, (a-2) 0.5 to 27.5% by mole of an aromatic dicarboxylic acid unit, and (a-3) 0.5 to 27.5% by mole of an aliphatic diol unit having 4 carbon atoms or less, and containing (a-1) to (a-3) in a total amount of 95% by mole or greater,wherein the relationship between the content of the oxycarboxylic acid, expressed as M % by mole, and the density ρ (kg/m3) of the polyester resin, satisfies the formula ρ≧1349+M×0.85.
摘要翻译：本发明提供一种聚酯树脂，其包含（a-1）45〜99摩尔％的碳原子数5以下的羟基羧酸单元，（a-2）0.5〜27.5摩尔％的芳香族二羧酸单元，和（a-3）0.5〜27.5摩尔％的碳原子数为4以下的脂肪族二醇单元，总计为95摩尔％以上的（a-1）〜（a-3）以M摩尔％表示的羟基羧酸的含量与聚酯树脂的密度rho（kg / m 3）之间的关系满足式rho = 1349 + Mx0.85 。

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