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    • 5. 发明授权
    • Method for color matching of powder coating composition
    • 粉末涂料组合物配色方法
    • US06348520B1
    • 2002-02-19
    • US09494118
    • 2000-01-28
    • Kazuhiko OhnishiYugen KawamotoHidefumi Takanashi
    • Kazuhiko OhnishiYugen KawamotoHidefumi Takanashi
    • C08K700
    • C09D5/03Y10S524/904Y10S525/934
    • The present invention provide a method for color matching of a thermosetting powder coating composition, the method comprising the steps of: (1) dryblending two or more kinds of starting colored thermosetting powder coating compositions of different colors having an average particle size of 20 &mgr;m or less to achieve color matching, and (2) granulating the dryblend to a particle size in the range suitable for powder coating, by heating and agitating the dryblend, or by adding a specific solid binder, or by grinding and classifying a sheet or grains formed by compressing the dryblend. According to the present invention, color matching can be easily made, and a color-matched powder coating composition is obtained which is excellent in application characteristics, finished appearance and film properties.
    • 本发明提供一种热固性粉末涂料组合物的颜色匹配方法,该方法包括以下步骤:(1)将两种或多种平均粒度为20μm的不同颜色的起始着色的热固性粉末涂料组合物干混,或 较少实现配色,以及(2)通过加热和搅拌干混物,或通过加入特定的固体粘合剂,或通过研磨和分级形成的片材或颗粒将干燥混合物制粒成适于粉末涂料的范围内的粒度 通过压缩干混料。 根据本发明,可以容易地进行配色,得到涂布特性,外观和膜特性优异的配色粉末涂料组合物。
    • 9. 发明授权
    • Powder coating of epoxy resin, non-cyclic polyanhydride, and aliphatic non-cyclic anhydride or dibasic acid
    • 环氧树脂,非环状聚酐和脂肪族非环状酸酐或二元酸的粉末涂料
    • US06448345B1
    • 2002-09-10
    • US09588349
    • 2000-06-07
    • Takato AdachiIchiro YoshiharaYugen Kawamoto
    • Takato AdachiIchiro YoshiharaYugen Kawamoto
    • C08L3314
    • C08G59/3209C08G59/4207C09D163/00
    • The present invention provides a thermosetting powder coating composition comprising: (A) an epoxy-containing resin; and (B) a curing agent containing acid anhydride (a) and at least one species selected from the group consisting of acid anhydride (b) and dibasic acid (c), the acid anhydride (a) being represented by formula X—COO—[CO—(CH2)m—COO]n—CO—X  (1) wherein the two X's are the same or different and independently represent a C4-12 alkyl group having a branched structure, R1—O—CO—R2—, R1—CO—R2— or R1—CO—NH—R2— in which R1 is a C1-10 monovalent saturated hydrocarbon group; R2 is a C1-10 bivalent saturated hydrocarbon group; m is an integer of 6 to 18; and n is an integer of 8 to 50, the acid anhydride (b) being represented by the formula HO—[CO—(CH2)p—COO]q—H  (2) wherein p is an integer of 6 to 18 and q is an integer of 2 to 18, and having carboxyl groups at both ends, the dibasic acid (c) being represented by the formula HOOC—(CH2)t—COOH  (3) wherein t is an integer of 6 to 18, the molar ratio of carboxyl groups to acid anhydride groups in the curing agent being in the range between 0.15:1 and 2:1, and the molar ratio of the total of carboxyl groups and acid anhydride groups in the curing agent (B) to epoxy groups in the epoxy-containing resin (A) being in the range between 0.7:1 and 1.2:1. The present invention further provides a method for forming a topcoat according to a 2-coat 1-bake system comprising the steps of applying to a substrate a thermosetting aqueous colored base coating composition, applying to the uncured surface of the base coat a clear coating composition, and curing the two coats by heating, wherein the clear coating composition is the above-mentioned thermosetting powder coating composition.
    • 本发明提供一种热固性粉末涂料组合物,其包含:(A)含环氧树脂; 和(B)含有酸酐(a)的固化剂和选自酸酐(b)和二元酸(c))中的至少一种,所述酸酐(a)由两个X代表由式 相同或不同且独立地表示具有支链结构的C 1-4-12烷基,R 1 -O-CO-R 2 - ,R 1 -CO-R 2 - 或R 1 -CO-NH-R 2 - ,其中R 1是C 1-10 一价饱和烃基; R2是C1-10二价饱和烃基; m为6〜18的整数。 n为8〜50的整数,所述酸酐(b)由式(Ⅳ)表示,为6〜18的整数,q表示2〜18的整数,两末端具有羧基,二元酸 (c)由糠醛表示,t为6〜18的整数,固化剂中羧基与酸酐基的摩尔比在0.15:1〜2:1的范围内,总摩尔比 的固化剂(B)中的羧基和酸酐基与环氧基树脂(A)中的环氧基的比例为0.7:1〜1.2:1。本发明还提供了一种形成面漆的方法 根据2涂层1烘烤系统,包括以下步骤:向基底施加热固性水性着色基底涂料组合物,将底涂层的未固化表面施加到透明涂料组合物上,并通过加热固化两个涂层,其中 透明涂料组合物是上述热固性 粉末涂料组合物。