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    • 3. 发明授权
    • Electrophotographic sensitive materials containing barbituric acid or
thiobarbituric acid derivaties
    • 含有巴比妥酸或硫代巴比妥酸衍生物的电子照相感光材料
    • US4395473A
    • 1983-07-26
    • US331745
    • 1981-12-17
    • Seiji HorieMasayoshi NagataJunji NakanoHideo Sato
    • Seiji HorieMasayoshi NagataJunji NakanoHideo Sato
    • C07D239/62C07D239/66C07D403/06C07D405/06C07D409/06C07D417/06G03G5/06G03G5/00
    • G03G5/067G03G5/0638G03G5/0661
    • An electrophotographic sensitive material is described having an electrophotographic sensitive layer containing a charge generating material and a charge transfer material, wherein said charge generating material comprises a barbituric acid derivative or thiobarbituric acid derivative represented by formula (I) or (II) ##STR1## wherein (i) X represents an oxygen atom or a sulfur atom(ii) R.sup.1 represents an alkoxy group, an aralkyl group or a substituted amino group represented by ##STR2## wherein R.sup.7 and R.sup.8 each represents an unsubstituted or substituted alkyl group or phenyl group, or R.sup.7 and R.sup.8 together represent a group forming a nitrogen atom-containing heterocyclic ring,(iii) R.sup.2 and R.sup.3 each represents a hydrogen atom, a halogen atom, an alkyl group, or a lower alkoxy group,(iv) R.sup.4 represents a hydrogen atom, an alkyl group, or an unsubstituted or substituted phenyl group,(v) R.sup.5 and R.sup.6 each represents an alkyl group, an aralkyl group, or an unsubstituted or substituted phenyl group, and(v) R.sup.5 and R.sup.6 each represents an alkyl group, an aralkyl group, or an unsubstituted or substituted phenyl group, and(vi) Ar represents a group selected from those represented by the formulas ##STR3## wherein Y and Z each represents S, O or N--R.sup.12, wherein R.sup.12 represents an alkyl group having from 1 to 4 carbon atoms, R.sup.9 and R.sup.10 each represents a hydrogen atom, an alkyl group or an alkoxy group, or R.sup.9 and R.sup.10 together represent a group forming a benzene ring or a naphthalene ring, and R.sup.11, represents a hydrogen atom, an alkyl group, an aralkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amide group, or a nitro group.
    • 描述了一种电子照相感光材料,其具有含有电荷产生材料和电荷转移材料的电子照相感光层,其中所述电荷产生材料包含由式(I)或(II)表示的巴比妥酸衍生物或硫代巴比妥酸衍生物 (II)其中(i)X表示氧原子或硫原子(ii)R 1表示由下式表示的烷氧基,芳烷基或取代氨基,其中R 7和R 8各自表示 未取代或取代的烷基或苯基,或R7和R8一起表示形成含氮原子的杂环的基团,(iii)R 2和R 3各自表示氢原子,卤素原子,烷基或低级烷氧基 基团,(iv)R 4表示氢原子,烷基或未取代或取代的苯基,(v)R 5和R 6各自表示烷基,芳烷基或未取代或取代的 苯基,(v)R 5和R 6各自表示烷基,芳烷基或未取代或取代的苯基,(vi)Ar表示选自下式的化合物: 其中Y和Z各自表示S,O或N-R 12,其中R 12表示具有1至4个碳原子的烷基,R 9和R 10各自表示氢原子,烷基或烷氧基,或R 9和 R 10一起表示形成苯环或萘环的基团,R 11表示氢原子,烷基,芳烷基,烷氧基,芳氧基,酰基,烷氧基羰基,芳氧基羰基, 卤素原子,单烷基氨基,二烷基氨基,酰胺基或硝基。
    • 5. 发明授权
    • Electrophotographic photoreceptor with hydrazone
    • 电子照相感光腙
    • US4477550A
    • 1984-10-16
    • US491482
    • 1983-05-04
    • Seiji HorieMasayoshi NagataJunji NakanoHideo Sato
    • Seiji HorieMasayoshi NagataJunji NakanoHideo Sato
    • C07C67/00C07C241/00C07D279/22C09B26/02G03G5/04G03G5/06H01L51/42
    • C07C251/72C07D279/22G03G5/0616G03G5/0638
    • An electrophotographic photoreceptor is described comprising an N-arylamino substituted hydrazone compound represented by formula (I), (II), or (III), in a light-sensitive layer thereof provided on a conductive support; formulae (I), (II), and (III) are as follows: ##STR1## wherein X represents O, S or N--R.sup.6 ; R.sup.1 and R.sup.2 each represents a non-substituted or a substituted straight or branched chain alkyl group containing from 1 to 12 carbon atoms, a non-substituted or a substituted straight or branched chain aralkyl group containing from 7 to 20 carbon atoms, or a non-substituted or a substituted aryl group, the aryl group including monovalent residues of monocyclic aromatic rings and condensed polycyclic aromatic rings having from 2 to 4 rings therein; R.sup.3, R.sup.4, R.sup.5, and R.sup.7 each represents hydrogen, a non-substituted or a substituted straight or branched chain alkyl group containing from 1 to 12 carbon atoms, a non-substituted or a substituted straight or branched chain aralkyl group containing from 7 to 20 carbon atoms, a straight or a branched chain alkoxy group containing from 1 to 4 carbon atoms, an aryloxy group containing from 6 to 10 carbon atoms, an acyl group containing from 2 to 8 carbon atoms, an alkoxycarbonyl group containing from 2 to 5 carbon atoms, a halogen atom, a nitro group, a monoalkylamino group whose alkyl moiety contains from 1 to 4 carbon atoms, a dialkylamino group whose alkyl moiety contains from 1 to 4 carbon atoms, or an amido group containing from 2 to 8 carbon atoms; and R.sup.6 represents a non-substituted or a substituted straight or branched chain alkyl group containing from 1 to 12 carbon atoms, or a non-substituted or a substituted straight or branched chain aralkyl group containing from 1 to 12 carbon atoms.
    • 描述的电子照相感光体在其设置在导电性载体上的感光层中包含由式(I),(II)或(III)表示的N-芳基氨基取代的腙化合物; (I),(II)和(III)如下:其中X表示O,S或N-R6;(II)其中X表示O,S或N-R6; R 1和R 2各自表示含有1至12个碳原子的未取代或取代的直链或支链烷基,含有7至20个碳原子的未取代或取代的直链或支链芳烷基, 取代或取代的芳基,芳基包括单环芳环的一价残基和其中具有2至4个环的稠合多环芳环; R3,R4,R5和R7各自表示氢,含有1至12个碳原子的未取代或取代的直链或支链烷基,未取代或取代的直链或支链芳烷基,其含有7至 20个碳原子,含有1至4个碳原子的直链或支链烷氧基,含有6至10个碳原子的芳氧基,含2至8个碳原子的酰基,含2至5个碳原子的烷氧基羰基 碳原子,卤素原子,硝基,烷基部分含有1至4个碳原子的单烷基氨基,烷基部分含有1至4个碳原子的二烷基氨基或含有2至8个碳原子的酰氨基 ; R6表示含有1至12个碳原子的未取代或取代的直链或支链烷基,或含有1至12个碳原子的未取代或取代的直链或支链芳烷基。
    • 6. 发明授权
    • Organic electrophotographic sensitive materials
    • 有机电子照相感光材料
    • US4396694A
    • 1983-08-02
    • US331746
    • 1981-12-17
    • Masayoshi NagataSeiji HorieJunji NakanoHideo Sato
    • Masayoshi NagataSeiji HorieJunji NakanoHideo Sato
    • G03G5/06G03G5/05
    • C07C251/72G03G5/0612G03G5/0637G03G5/0638
    • An electrophotographic sensitive material is described comprising an electrophotographic sensitive layer containing a compound represented by the formula (1) ##STR1## wherein R.sup.1 and R.sup.2 each represents an unsubstituted or substituted straight chain or branched chain alkyl group having from 1 to 12 carbon atoms, an unsubstituted or substituted straight chain or branched chain aralkyl group having from 7 to 20 carbon atoms or an aryl group consisting of a monovalent group consisting of an unsubstituted or substituted monocyclic aromatic hydrocarbon or polycyclic aromatic hydrocarbon having from 2 to 4 nuclei from which a hydrogen atom is removed; R.sup.3 represents an unsubstituted or substituted straight chain or branched chain alkyl group having from 1 to 12 carbon atoms, an unsubstituted or substituted aralkyl group having from 7 to 20 carbon atoms or an unsubstituted or substituted aryl group; and R.sup.4 and R.sup.5 each represents an unsubstituted or substituted straight chain or branched chain alkyl group having from 1 to 12 carbon atoms, an unsubstituted or substituted nitrogen-containing heterocyclic compound from which a hydrogen atom is removed, a halogen atom, an alkoxy group, an aryloxy group, a dialkylamino group, or a hydrogen atom.
    • 描述了一种电子照相感光材料,其包含含有由式(1)表示的化合物的电子照相感光层,其中R 1和R 2各自表示未取代或取代的具有1至12个碳原子的直链或支链烷基 原子,具有7至20个碳原子的未取代或取代的直链或支链芳烷基或由具有2至4个核的未取代或取代的单环芳烃或多环芳烃组成的一价基团的芳基组成的芳基, 去除氢原子; R3表示未取代或取代的具有1至12个碳原子的直链或支链烷基,未取代或取代的具有7至20个碳原子的芳烷基或未取代或取代的芳基; R 4和R 5各自表示未取代或取代的具有1〜12个碳原子的直链或支链烷基,未取代或取代的除去氢原子的含氮杂环化合物,卤素原子,烷氧基, 芳氧基,二烷基氨基或氢原子。
    • 7. 发明授权
    • Electrophotographic photoreceptor
    • 电子照相感光体
    • US4403025A
    • 1983-09-06
    • US276745
    • 1981-06-24
    • Seiji HorieMasayoshi NagataJunji NakanoHideo Sato
    • Seiji HorieMasayoshi NagataJunji NakanoHideo Sato
    • C07C67/00C07C241/00C07D279/22C09B26/02G03G5/04G03G5/06H01L51/42
    • C07C251/72C07D279/22G03G5/0616G03G5/0638
    • An electrophotographic photoreceptor is described comprising an N-arylamino substituted hydrazone compound represented by formula (I), (II), or (III), in a light-sensitive layer thereof provided on a conductive support; formulae (I), (II), and (III) are as follows: ##STR1## wherein X represents O, S or N--R.sup.6 ; R.sup.1 and R.sup.2 each represents a non-substituted or a substituted straight or branched chain alkyl group containing from 1 to 12 carbon atoms, a non-substituted or a substituted straight or branched chain aralkyl group containing from 7 to 20 carbon atoms, or a non-substituted or a substituted aryl group, the aryl group including monovalent residues of monocyclic aromatic rings and condensed polycyclic aromatic rings having from 2 to 4 rings therein; R.sup.3, R.sup.4, R.sup.5, and R.sup.7 each represents hydrogen, a non-substituted or a substituted straight or branched chain alkyl group containing from 1 to 12 carbon atoms, a non-substituted or a substituted straight or branched chain aralkyl group containing from 7 to 20 carbon atoms, a straight or a branched chain alkoxy group containing from 1 to 4 carbon atoms, an aryloxy group containing from 6 to 10 carbon atoms, an acyl group containing from 2 to 8 carbon atoms, an alkoxycarbonyl group containing from 2 to 5 carbon atoms, a halogen atom, a nitro group, a monoalkylamino group whose alkyl moiety contains from 1 to 4 carbon atoms, a dialkylamino group whose alkyl moiety contains from 1 to 4 carbon atoms, or an amido group containing from 2 to 8 carbon atoms; and R.sup.6 represents a non-substituted or a substituted straight or branched chain alkyl group containing from 1 to 12 carbon atoms, or a non-substituted or a substituted straight or branched chain aralkyl group containing from 1 to 12 carbon atoms.
    • 描述的电子照相感光体在其设置在导电性载体上的感光层中包含由式(I),(II)或(III)表示的N-芳基氨基取代的腙化合物; (I),(II)和(III)如下:其中X表示O,S或N-R6;(II)其中X表示O,S或N-R6; R 1和R 2各自表示含有1至12个碳原子的未取代或取代的直链或支链烷基,含有7至20个碳原子的未取代或取代的直链或支链芳烷基, 取代或取代的芳基,芳基包括单环芳环的一价残基和其中具有2至4个环的稠合多环芳环; R3,R4,R5和R7各自表示氢,含有1至12个碳原子的未取代或取代的直链或支链烷基,未取代或取代的直链或支链芳烷基,其含有7至 20个碳原子,含有1至4个碳原子的直链或支链烷氧基,含有6至10个碳原子的芳氧基,含2至8个碳原子的酰基,含2至5个碳原子的烷氧基羰基 碳原子,卤素原子,硝基,烷基部分含有1至4个碳原子的单烷基氨基,烷基部分含有1至4个碳原子的二烷基氨基或含有2至8个碳原子的酰胺基 ; R6表示含有1至12个碳原子的未取代或取代的直链或支链烷基,或含有1至12个碳原子的未取代或取代的直链或支链芳烷基。