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    • 2. 发明申请
    • Method and device for analyzing the hardening of hardenable formulations
    • 用于分析可硬化制剂硬化的方法和装置
    • US20050000274A1
    • 2005-01-06
    • US10491423
    • 2002-09-27
    • Wolfgang SchrofThorsten MullerSebastian KoltzenburgMatthias KronerStephan LehmannJoachim Hadeler
    • Wolfgang SchrofThorsten MullerSebastian KoltzenburgMatthias KronerStephan LehmannJoachim Hadeler
    • G01N11/00G01N3/00G01N3/06G01N3/42G01N3/48
    • G01N3/42G01N2203/0092G01N2203/0682
    • The invention relates to a process for the combinatorial investigation of the hardening of hardenable liquid or viscous formulations (a) in which n hardenable formulations are prepared in parallel in n containers, and (b) the degree of hardening is determined at least once on each of the n formulations by inserting a measurement tip into the formulation with a certain force and measuring the maximum penetration depth achieved as a measure of the degree of hardening of this formulation, and (c) for in each case one composition of the formulations, one or more parameters that are characteristic of the kinetics of hardening are determined from the measurement values for the penetration depth at various times after preparation of the formulations. Steps (a) to (c) are preferably carried out a number of times, and a dependence of the characteristic parameter(s) on the composition of the formulations is determined by analysis of the large number of individual values obtained in this way for the parameter(s) that is (are) characteristic of the kinetics of hardening, enabling the composition of the formulations to be optimized with respect to its hardening behavior.
    • 本发明涉及用于组合研究可硬化液体或粘性制剂(a)的硬化的方法,其中在n个容器中并行制备n个可硬化制剂,和(b)硬化程度每个至少确定一次 通过以一定的力将测量尖端插入制剂中并测量作为该制剂的硬化程度的度量而获得的最大穿透深度,以及(c)在每种情况下,制剂的一种组合物,一种 或者从制剂配制后的不同时刻的穿透深度的测定值求出硬化动力学特征的更多的参数。 步骤(a)至(c)优选进行多次,并且通过分析以这种方式获得的大量个体值来确定特征参数对制剂组成的依赖性 硬化动力学特征的参数,使组合物能够根据其硬化行为进行优化。
    • 3. 发明申请
    • Preparation Comprising at Least One Conazole Fungicide
    • 包括最少一种针唑杀真菌剂的制备
    • US20080318785A1
    • 2008-12-25
    • US11918522
    • 2006-04-13
    • Sebastian KoltzenburgPeter DomboGunter OetterChristian KrugerWolfgang SchrofMatthias Bratz
    • Sebastian KoltzenburgPeter DomboGunter OetterChristian KrugerWolfgang SchrofMatthias Bratz
    • A01N43/653C08F228/02A01P3/00C08F26/06
    • C08F220/60A01N25/10A01N25/14A01N43/653C08F220/18C08F220/38A01N2300/00
    • The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l, c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
    • 本发明涉及制剂,特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂,其中a)至少一种活性物质选自唑类(活性物质1)和b)另一种 在20℃温度下的水溶性小于20g / l的活性植物保护物质(活性物质2),c)由M单体组成的至少一种共聚物CP,包括α)至少一种类型的 包含至少一个磺酸基团的单烯属不饱和单体M1和β)至少一种中性单烯属不饱和单体M2,其中活性物质1与另一种活性植物保护物质2的定量比范围为1:10至10 :1。 所述发明还涉及新型共聚物CP,其以由至少三种不同单烯属不饱和单体M组成的聚合物的形式体现并且以聚合形式包含α)至少一种类型的单烯属不饱和单体M1,其包含在 至少一种磺酸基团,β1)至少一种类型的中和单烯属不饱和单体M2b,其在20℃温度下的水溶性小于30g / l和β2)至少一种中性单烯属不饱和单体M2b,其中 在20℃的温度下的水溶解度大于50g / l。
    • 4. 发明申请
    • PREPARATION CONTAINING AT LEAST ONE TYPE OF FUNGICIDAL CONAZOLE
    • 至少含有一种类型的杀真菌剂的制剂
    • US20110166309A1
    • 2011-07-07
    • US13047435
    • 2011-03-14
    • Sebastian KOLTZENBURGPeter DomboGünter OetterChristian KrügerWolfgang SchrofMatthias Bratz
    • Sebastian KOLTZENBURGPeter DomboGünter OetterChristian KrügerWolfgang SchrofMatthias Bratz
    • C08F228/02C08F226/06
    • C08F220/60A01N25/10A01N25/14A01N43/653C08F220/18C08F220/38A01N2300/00
    • The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active-plant protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerization incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
    • 本发明涉及制剂,特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂,其中a)至少一种活性物质选自唑类(活性物质1)和b)另一种 在20℃温度下的水溶性小于20g / l的活性植物保护物质(活性物质2),c)由M单体组成的至少一种共聚物CP,其包含α)至少一种 的至少一种中性单烯属不饱和单体M2,其中活性物质1和另一种活性植物保护物质2的定量比范围为1:10 至10:1。 所述发明还涉及新型共聚物CP,其以由至少三种不同的单烯属不饱和单体M组成的聚合物的形式体现,并且以聚合形式包含α)至少一种类型的单烯属不饱和单体M1,其包含在 至少一种磺酸基团,1)至少一种中和单烯属不饱和单体M2,其在20℃温度下的水溶性小于30g / l,和2)至少一种中性单烯属不饱和单体 在20℃温度下的水溶性大于50g / l的不饱和单体M2b。
    • 5. 发明授权
    • Preparation containing at least one type of fungicidal conazole
    • 含有至少一种类型的杀真菌唑的制剂
    • US08906399B2
    • 2014-12-09
    • US13047435
    • 2011-03-14
    • Sebastian KoltzenburgPeter DomboGünter OetterChristian KrügerWolfgang SchrofMatthias Bratz
    • Sebastian KoltzenburgPeter DomboGünter OetterChristian KrügerWolfgang SchrofMatthias Bratz
    • A01N25/08A01N25/00A01N25/32A01N25/28C08F26/08C08F12/30A01N25/10C08F220/18C08F220/38A01N25/14A01N43/653C08F220/60
    • C08F220/60A01N25/10A01N25/14A01N43/653C08F220/18C08F220/38A01N2300/00
    • The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active-plant protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerization incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
    • 本发明涉及制剂,特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂,其中a)至少一种活性物质选自唑类(活性物质1)和b)另一种 在20℃温度下的水溶性小于20g / l的活性植物保护物质(活性物质2),c)由M单体组成的至少一种共聚物CP,其包含α)至少一种 的至少一种中性单烯属不饱和单体M2,其中活性物质1和另一种活性植物保护物质2的定量比范围为1:10 至10:1。 所述发明还涉及新型共聚物CP,其以由至少三种不同的单烯属不饱和单体M组成的聚合物的形式体现,并且以聚合形式包含α)至少一种类型的单烯属不饱和单体M1,其包含在 至少一种磺酸基团,1)至少一种中和单烯属不饱和单体M2,其在20℃温度下的水溶性小于30g / l,和2)至少一种中性单烯属不饱和单体 在20℃温度下的水溶性大于50g / l的不饱和单体M2b。
    • 6. 发明授权
    • Preparation comprising at least one conazole fungicide
    • 包含至少一种唑类杀真菌剂的制剂
    • US07927617B2
    • 2011-04-19
    • US11918522
    • 2006-04-13
    • Sebastian KoltzenburgPeter DomboGünter OetterChristian KrügerWolfgang SchrofMatthias Bratz
    • Sebastian KoltzenburgPeter DomboGünter OetterChristian KrügerWolfgang SchrofMatthias Bratz
    • A01N25/12
    • C08F220/60A01N25/10A01N25/14A01N43/653C08F220/18C08F220/38A01N2300/00
    • The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active-plant protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerization incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
    • 本发明涉及制剂,特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂,其中a)至少一种活性物质选自唑类(活性物质1)和b)另一种 在20℃温度下的水溶性小于20g / l的活性植物保护物质(活性物质2),c)由M单体组成的至少一种共聚物CP,其包含α)至少一种 的至少一种中性单烯属不饱和单体M2,其中活性物质1和另一种活性植物保护物质2的定量比范围为1:10 至10:1。 所述发明还涉及新型共聚物CP,其以由至少三种不同的单烯属不饱和单体M组成的聚合物的形式体现,并且以聚合形式包含α)至少一种类型的单烯属不饱和单体M1,其包含在 至少一种磺酸基团,1)至少一种中和单烯属不饱和单体M2,其在20℃温度下的水溶性小于30g / l,和2)至少一种中性单烯属不饱和单体 在20℃温度下的水溶性大于50g / l的不饱和单体M2b。
    • 7. 发明申请
    • Method and device for analysing blushing in dispersion films
    • 用于分析分散膜中的发红的方法和装置
    • US20050014282A1
    • 2005-01-20
    • US10499632
    • 2003-01-13
    • Wolfgang SchrofThorsten MullerAlexander CentnerStephan LehmannJoachim Hadeler
    • Wolfgang SchrofThorsten MullerAlexander CentnerStephan LehmannJoachim Hadeler
    • G01N21/47G01N21/00
    • G01N21/4738
    • The invention relates to a process for parallel and automated evaluation of the blushing of n samples of dispersion films, which comprises (a) providing an illuminated array of n spatially separated samples of the dispersion films, (b) imaging the array of n samples by means of a CCD camera at m+1 different times t0 to tm and digitizing the images, (c) automatically determining multiple brightnesses B(k, ti) for each sample at different times ti selected from t0 to tm from the m+1 different digitized images for at least a portion of the n samples, where B(k, ti) is the brightness of the kth of n samples at the respective time ti and is a measure for the blushing of this sample at this time, (d) determining values P(k) of a parameter characteristic of the kinetics of the blushing from the different brightnesses B(k, ti) for each sample for at least a portion of the n samples, where P(k) is the value of the characteristic parameter for the kth of the n samples.
    • 本发明涉及用于并行和自动评估分散膜的n个样品的白化的方法,其包括(a)提供分散膜的n个空间分离的样品的照射阵列,(b)通过以下方式对n个样品的阵列进行成像: 在m + 1个不同时刻t0到tm的CCD照相机的手段,并对图像进行数字化;(c)在从m + 1不同的t0到tm的不同时刻ti自动确定每个样本的多个亮度B(k,ti) 对于n个样本的至少一部分的数字化图像,其中B(k,ti)是在相应时间ti的n个样本的第k个的亮度,并且是此时该样本的白化的量度,(d) 对于n个样本的至少一部分,针对每个样本的不同亮度B(k,ti)的脸红动力学参数特性的值P(k),其中P(k)是特征值 n个样本的第k个参数。