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1. 发明申请

US20050014874A1 Flame-retardant polyamides 审中-公开
标题翻译：阻燃聚酰胺
公开(公告)号：US20050014874A1
公开(公告)日：2005-01-20
申请号：US10890366
申请日：2004-07-13
申请人： Sebastian Hoerold , Wolfgang Wanzke , Ottmar Schacker , Elke Schlosser
发明人： Sebastian Hoerold , Wolfgang Wanzke , Ottmar Schacker , Elke Schlosser
IPC分类号： C08K5/5313 , C08L77/00 , C08L77/02 , C08L77/06 , C08K5/34 , C08K5/53
CPC分类号： C08K5/0066 , C08K5/5313 , C08L77/00 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2666/84
摘要： The invention relates to flame-retardant aromatic or semiaromatic copolyamides comprising, as flame retardant, at least one phosphinic salt of the formula (I), and/or one diphosphinic salt of the formula (II), and/or polymers of these, where R1, R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na; K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4.
摘要翻译：本发明涉及阻燃芳族或半芳族共聚酰胺，其包含作为阻燃剂的至少一种式（I）的次膦酸盐和/或一种式（II）的二膦酸盐，和/或这些的聚合物，其中 R 1，R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na; K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4。

2. 发明申请

US20130190432A1 Flame Retardant-Stabilizer Combination For Thermoplastic Polymers 审中-公开
标题翻译：阻燃稳定剂组合热塑性聚合物
公开(公告)号：US20130190432A1
公开(公告)日：2013-07-25
申请号：US13878145
申请日：2011-09-30
申请人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K5/5313 , C08K5/3492 , C08K5/10 , C08K3/22 , C08K5/5317 , C08K5/56 , C08K5/52 , C08K3/38
CPC分类号： C08K5/5313 , C08K3/22 , C08K3/38 , C08K5/0008 , C08K5/10 , C08K5/34922 , C08K5/34924 , C08K5/52 , C08K5/5317 , C08K5/56
摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.
摘要翻译：一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。

3. 发明授权

US09534109B2 Flame retardant-stabilizer combination for thermoplastic polymers 有权
标题翻译：用于热塑性聚合物的阻燃 - 稳定剂组合
公开(公告)号：US09534109B2
公开(公告)日：2017-01-03
申请号：US13809716
申请日：2011-07-06
申请人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K13/02 , C08K5/00 , C08K5/16 , C08K5/3492 , C08K5/524 , C08K5/5313
CPC分类号： C08K13/02 , C08K5/0066 , C08K5/16 , C08K5/34922 , C08K5/524 , C08K5/5313
摘要： A flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof, as component B a nitrogen-containing synergist or a phosphorus/nitrogen flame retardant, and as component C a metal oxide coated with a metal salt and/or metal hydroxide coated with a metal salt.
摘要翻译：作为组分A的作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物作为组分B的含氮增效剂的阻燃稳定剂组合物或磷/氮阻燃剂，作为组分C，涂覆有被金属盐涂覆的金属盐和/或金属氢氧化物的金属氧化物。

4. 发明申请

US20130210968A1 Flame-Retardant Polyester Compounds 审中-公开
标题翻译：阻燃聚酯化合物
公开(公告)号：US20130210968A1
公开(公告)日：2013-08-15
申请号：US13878167
申请日：2011-10-25
申请人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser , Bernd Nass
发明人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser , Bernd Nass
IPC分类号： C08K5/5399 , C08K5/3492
CPC分类号： C08K5/5399 , C08K5/3492 , C08K5/34922 , C08K5/53
摘要： The invention relates to flame-retardant polyester compounds comprising as component A 40% to 89.9% by weight of thermoplastic polyesters, as component B 5% to 25% by weight of phosphinic salt of the formula (V) and/or diphosphinic salt of the formula (VI) and/or polymers thereof, in which R1 and R2 are H or C1-C6-alkyl and/or aryl; R3 is C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; and x is 1 to 4, and as component C 5% to 25% by weight of a phosphazene, as component D 0% to 15% by weight of reaction products of melamine with phosphoric acid and/or condensed phosphoric acids, as component E 0% to 45% by weight of reinforcing agents, and as component F 0.1% to 3% by weight of further additives, the sum of the components by weight being 100% by weight.
摘要翻译：本发明涉及阻燃聚酯化合物，其包含作为组分A 40％至89.9％重量的热塑性聚酯，作为组分B 5％至25％重量的式（V）的次膦酸盐和/或二式（VI）和/或其聚合物，其中R 1和R 2是H或C 1 -C 6 - 烷基和/或芳基; R3是C1-C10-亚烷基，C6-C10-亚芳基， - - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分C 5〜25重量％的磷腈，作为成分D的组分D为0〜15重量％的三聚氰胺与磷酸和/或缩合磷酸的反应产物，作为组分E 0〜45重量％的增强剂，作为成分F为0.1〜3重量％的其他添加剂，其重量份数为100重量％。

5. 发明申请

US20130109792A1 Flame Retardant-Stabilizer Combination For Thermoplastic Polymers 有权
标题翻译：阻燃稳定剂组合热塑性聚合物
公开(公告)号：US20130109792A1
公开(公告)日：2013-05-02
申请号：US13809716
申请日：2011-07-06
申请人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K13/02
CPC分类号： C08K13/02 , C08K5/0066 , C08K5/16 , C08K5/34922 , C08K5/524 , C08K5/5313
摘要： Flame retardant-stabilizer combination for thermoplastic polymersThe invention relates to a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 30 to 79.9% by weight of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each H, C1-C18-alkyl, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 is linear or branched C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 20 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and as component C 0.1 to 20% by weight of a metal oxide and/or metal hydroxide coated with a metal salt, component C comprising 50 to 95% by weight of metal oxide and/or metal hydroxide and 5 to 50% by weight of metal salt and the sum of components A to C always being 100% by weight.
摘要翻译：用于热塑性聚合物的阻燃稳定剂组合物本发明涉及一种用于热塑性聚合物的阻燃剂 - 稳定剂组合物，其包含作为组分A 30至79.9重量％的式（I）的次膦酸盐和/或二其中R 1，R 2相同或不同并且各自为H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 7 -C 18 - 芳烷基和/或C 7 -C 18烷基芳基的式（II）和/或其聚合物 ; R3是直链或支链C1-C10-亚烷基，C6-C10-亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，作为组分B 20至50重量％的含氮增效剂或磷/氮阻燃剂和作为组分C的0.1至20重量％的涂覆有金属氧化物和/或金属氢氧化物的组分金属盐，包含50-95重量％的金属氧化物和/或金属氢氧化物和5-50重量％的金属盐的组分C，组分A至C的总和总是100重量％。

6. 发明申请

US20050137300A1 Flame retardant and stabilizer combined, for polyesters and polyamides 审中-公开
标题翻译：阻燃和稳定剂组合，用于聚酯和聚酰胺
公开(公告)号：US20050137300A1
公开(公告)日：2005-06-23
申请号：US11015188
申请日：2004-12-17
申请人： Elke Schlosser , Hans-Matthias Deger , Sebastian Hoerold
发明人： Elke Schlosser , Hans-Matthias Deger , Sebastian Hoerold
IPC分类号： C08L101/00 , C08K3/00 , C08K3/34 , C08K5/00 , C08K5/15 , C08K5/151 , C08K5/34 , C08K5/3412 , C08K5/3492 , C08K5/35 , C08K5/521 , C08K5/5313 , C08L23/08 , C08L51/00 , C08L67/02 , C08L75/04 , C08L77/00 , C09K21/00
CPC分类号： C08K5/0008 , C08K5/34928 , C08K5/5313 , C08L67/02 , C08L77/00 , C08L2666/02
摘要： The invention relates to a flame retardant and stabilizer combined for thermoplastic polymers, which comprises, as component A, a phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II), and/or polymers of these, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, and which comprises, as component B, at least one chain extender from the following classes of compounds b1) bislactams, b2) bisoxazolines or bisoxazines, and/or b3) epoxides, b4) anhydrides of polybasic carboxylic acids.
摘要翻译：本发明涉及用于热塑性聚合物的阻燃剂和稳定剂，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐，和/或这些的聚合物，其中R 1和R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，并且其包含作为组分B的至少一种以下类别的化合物b1）双内酰胺，b2）双恶唑啉或双恶嗪，和/或b3）环氧化物的增链剂，b4）多元羧酸的酸酐。

7. 发明申请

US20090054564A1 Piperazine polyphosphate, methods for its preparation and its use 审中-公开
标题翻译：哌嗪多磷酸盐，其制备方法及其用途
公开(公告)号：US20090054564A1
公开(公告)日：2009-02-26
申请号：US12229434
申请日：2008-08-22
申请人： Frank Eisentraeger , Sebastian Hoerold , Wolfgang Wanzke , Michael Hill
发明人： Frank Eisentraeger , Sebastian Hoerold , Wolfgang Wanzke , Michael Hill
IPC分类号： C08K5/3462 , C09K21/10 , C09K21/12
CPC分类号： C09K21/12 , C07D295/023 , C08K5/5205 , C10M137/08 , C10M2223/043 , C10N2230/12
摘要： The invention relates to a piperazine polyphosphate which has an average chain length of from 2.2 to 10 phosphate units, to a method for its preparation and to its use.
摘要翻译：本发明涉及平均链长为2.2-10个磷酸酯单元的哌嗪多磷酸酯，其制备方法及其用途。

8. 发明申请

US20050101704A1 Flame retardant additive for polymers compounds with improved hydro-thermal stability 审中-公开
标题翻译：具有改善的水热稳定性的聚合物化合物的阻燃添加剂
公开(公告)号：US20050101704A1
公开(公告)日：2005-05-12
申请号：US10839991
申请日：2004-05-06
申请人： Frank Eisentraeger , Werner Krause , Sebastian Hoerold , Wolfgang Wanzke , Peter Anna , Gyoergy Bertalan , Gyoergy Marosi , Andrea Marton , Emese Zimonyi
发明人： Frank Eisentraeger , Werner Krause , Sebastian Hoerold , Wolfgang Wanzke , Peter Anna , Gyoergy Bertalan , Gyoergy Marosi , Andrea Marton , Emese Zimonyi
IPC分类号： C09K21/04 , C08K3/32 , C08K5/54 , C08L101/00 , C09K21/12 , C09K21/14 , C08K5/34 , C08K5/49
CPC分类号： C08K3/32 , C09K21/12
摘要： The invention relates to a flame retardant polymer compound comprising from 50-95 wt % polymer matrix related to the total amount of the flame retardant polymeric compound and 5-50 wt % of flame retardant additive system related to the total amount of the flame retardant polymeric compound.
摘要翻译：本发明涉及一种阻燃聚合物化合物，其包含与阻燃聚合物的总量相关的50-95重量％的聚合物基质和5-50重量％的与阻燃聚合物总量相关的阻燃添加剂体系复合。

9. 发明申请

US20110263745A1 Flame Retardant Combinations For Polyesters And Flame Retarded Polyester Moulding Compositions Therefrom 审中-公开
标题翻译：聚酯和阻燃聚酯成型组合物的阻燃组合
公开(公告)号：US20110263745A1
公开(公告)日：2011-10-27
申请号：US12920917
申请日：2009-12-17
申请人： Wolfgang Wanzke , Sebastian Hoerold , Marc-Andre Lebel , Karl Dieter Freitag
发明人： Wolfgang Wanzke , Sebastian Hoerold , Marc-Andre Lebel , Karl Dieter Freitag
IPC分类号： C08K5/3492
CPC分类号： C08K5/0066 , C08K5/34924 , C08K5/53 , C08L67/02
摘要： Disclosed are new compositions consisting of mixtures of flame retardants for thermoplastic polyesters based on a phosphinate salt, phosphonate oligomers, polymers or copolymers and a melamine derivative. The compositions exhibit an excellent combination of processing characteristics, thermal and mechanical properties, and are flame retardant. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.
摘要翻译：公开了由基于次膦酸盐，膦酸酯低聚物，聚合物或共聚物和三聚氰胺衍生物的热塑性聚酯的阻燃剂的混合物组成的新组合物。组合物表现出加工特性，热和机械性能的优异组合，并且是阻燃剂。进一步公开的是由这些材料制成的制品，例如纤维，薄膜，涂覆的基材，模制品，泡沫，纤维增强制品或其任何组合。

10. 发明申请

US20060089435A1 Flameproof agent-stabiliser-combination for thermoplastic polymers 审中-公开
标题翻译：用于热塑性聚合物的防火剂 - 稳定剂组合
公开(公告)号：US20060089435A1
公开(公告)日：2006-04-27
申请号：US10526691
申请日：2003-08-26
申请人： Sebastian Hoerold , Wolfgang Wanzke , Ottmar Schacker , Bernd Nass , Martin Sicken
发明人： Sebastian Hoerold , Wolfgang Wanzke , Ottmar Schacker , Bernd Nass , Martin Sicken
IPC分类号： C08K5/49
CPC分类号： C08K5/5313 , C08K3/22
摘要： A flame retardant-stabilizer combination for thermoplastic polymers, comprising, as component A, from 25 to 99.9% by weight of a phosphinic acid salt of the formula (I) and/or of a diphosphinic acid salt of the formula (II) and/or polymers thereof, as component B, from 0 to 75% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 50% by weight of magnesium oxide, zinc oxide, manganese oxide, tin oxide, dihydrotalcite, hydrocalumite, magnesium hydroxide, calcium hydroxide, zinc hydroxide, tin oxide hydrate, manganese hydroxide, zinc borate, basic zinc silicate, zinc stannate or mixtures of these substances, the sum of the components always being 100% by weight.
摘要翻译：一种用于热塑性聚合物的阻燃剂 - 稳定剂组合物，其包含作为组分A的25至99.9重量％的式（I）的次膦酸盐和/或式（II）的二次膦酸盐和/ 或其聚合物，作为组分B，0至75重量％的含氮增效剂或磷/氮阻燃剂，并且作为组分C，0.1-50重量％的氧化镁，氧化锌，锰氧化物，氧化锡，二氢铁矿，氢氧化钙，氢氧化镁，氢氧化钙，氢氧化锌，氧化锡水合物，氢氧化锰，硼酸锌，碱式硅酸锌，锡酸锌或这些物质的混合物，总和为100％重量。

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