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    • 1. 发明申请
    • Dye-Sensitized Solar Cell via Co-Sensitization with Cooperative Dyes
    • 染料敏化太阳能电池与合作染料的共同敏化
    • US20140216553A1
    • 2014-08-07
    • US13758819
    • 2013-02-04
    • Sean VailDavid EvansKaren NishimuraWei PanJong-Jan Lee
    • Sean VailDavid EvansKaren NishimuraWei PanJong-Jan Lee
    • H01G9/20C09K3/00
    • H01G9/2063H01G9/2031H01L51/0078Y02E10/542
    • A co-sensitized dye-sensitized solar cell (DSC) is provided, made from a transparent substrate and a transparent conductive oxide (TCO) film overlying the transparent substrate. An n-type semiconductor layer overlies the TCO, and is co-sensitized with a first dye (D1) and a second dye (D2). A redox electrolyte is in contact with the co-sensitized n-type semiconductor layer, and a counter electrode overlies the redox electrolyte. The first dye (D1) has a first optical absorbance local maxima at a first wavelength (A1) and a second optical absorbance local maxima at a second wavelength (A2), longer than the first wavelength. The second dye (D2) has a third optical absorbance local maxima at a third wavelength (A3) between the first wavelength (A1) and the second wavelength (A2). In one aspect, the first dye (D1) includes a porphyrin material, for example, a metalloporphyrin obtained by complexation with a transition metal such as zinc (i.e. zinc porphyrin (ZnP)).
    • 提供由透明基板和覆盖透明基板的透明导电氧化物(TCO)膜制成的共感染染料敏化太阳能电池(DSC)。 n型半导体层覆盖在TCO上,并与第一染料(D1)和第二染料(D2)共感光。 氧化还原电解质与共敏化n型半导体层接触,并且反电极覆盖在氧化还原电解质上。 第一染料(D1)在第一波长(A1)具有第一吸光度局部最大值,在第二波长(A2)处具有比第一波长长的第二吸光度局部最大值。 第二染料(D2)在第一波长(A1)和第二波长(A2)之间的第三波长(A3)具有第三吸光度局部最大值。 一方面,第一染料(D1)包括卟啉材料,例如通过与诸如锌的过渡金属(即卟啉锌(ZnP))络合而获得的金属卟啉)。