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1. 发明授权

US10017704B2 Integrated hydrotreating and steam pyrolysis system for direct processing of a crude oil 有权
公开(公告)号：US10017704B2
公开(公告)日：2018-07-10
申请号：US15450779
申请日：2017-03-06
申请人： Saudi Arabian Oil Company
发明人： Raheel Shafi , Julio Hasselmeyer , Abdennour Bourane , Ibrahim A. Abba , Abdul Rahman Zafer Akhras
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , C10G9/36 , C10G45/00 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： An integrated hydrotreating and steam pyrolysis system for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. Hydroprocessed effluent is thermally cracked in the presence of steam to produce a mixed product stream, which is separated. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins and aromatics are recovered from the separated mixed product stream.

2. 发明授权

US09771530B2 Integrated slurry hydroprocessing and steam pyrolysis of crude oil to produce petrochemicals 有权
公开(公告)号：US09771530B2
公开(公告)日：2017-09-26
申请号：US14994923
申请日：2016-01-13
申请人： Saudi Arabian Oil Company
发明人： Essam Sayed , Raheel Shafi , Abdul Rahman Zafer Akhras , Abdennour Bourane , Ibrahim A. Abba
IPC分类号： C10G69/06 , C10G47/26 , C10G49/12 , C10G9/16 , C10G49/00 , C10G67/10 , C10G51/06 , C10G9/00 , C10G9/14
CPC分类号： C10G69/06 , C10G9/16 , C10G47/26 , C10G49/007 , C10G49/12 , C10G67/10 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： An integrated slurry hydroprocessing and steam pyrolosyis process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil, a steam pyrolysis residual liquid fraction and slurry reside are combined and treated in a hydroprocessing zone in the presence of hydrogen under conditions effective to produce an effluent having an increased hydrogen content. The effluent is thermally cracked with steam under conditions effective to produce a mixed product stream and steam pyrolysis residual liquid fraction. The mixed product stream is separated and olefins and aromatics are recovered and hydrogen is purified and recycled.

3. 发明申请

US20130068661A1 PROCESS FOR THE SEQUENTIAL HYDROCONVERSION AND HYDRODESULFURIZATION OF WHOLE CRUDE OIL 有权
标题翻译：全部原油的顺序氢化和水解的方法
公开(公告)号：US20130068661A1
公开(公告)日：2013-03-21
申请号：US13671976
申请日：2012-11-08
申请人： SAUDI ARABIAN OIL COMPANY
发明人： Stephane Cyrille Kressmann , Raheel Shafi , Ali Hussain Alzaid , Esam Z. Hamad
IPC分类号： C10G65/12 , C10G65/14
CPC分类号： C10G65/12 , B01J23/20 , B01J23/26 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/1061 , B01J35/109 , C10G45/04 , C10G47/02 , C10G65/14 , C10G2300/202 , C10G2300/206 , C10G2300/308 , C10G2300/4006
摘要： The invention relates to a method for removing sulfur from crude oils using a catalytic hydrotreating process operating at moderate temperature and pressure and reduced hydrogen consumption. The process produces sweet crude oil having a sulfur content of between about 0.1 and 1.0 wt % in addition to reduced crude density. The method employs least two reactors in series, wherein the first reactor includes a hydroconversion catalyst and the second reactor includes a desulfurization catalyst.
摘要翻译：本发明涉及使用在中等温度和高压下操作并降低氢消耗的催化加氢处理方法从原油中除去硫的方法。该方法除了降低粗密度外，还产生硫含量在约0.1至1.0重量％之间的甜油。该方法采用串联的最少两个反应器，其中第一反应器包括加氢转化催化剂，第二反应器包括脱硫催化剂。

4. 发明申请

US20180187099A1 INTEGRATED SOLVENT DEASPHALTING, HYDROTREATING AND STEAM PYROLYSIS SYSTEM FOR DIRECT PROCESSING OF A CRUDE OIL 审中-公开
公开(公告)号：US20180187099A1
公开(公告)日：2018-07-05
申请号：US15905107
申请日：2018-02-26
申请人： Saudi Arabian Oil Company
发明人： Abdennour Bourane , Raheel Shafi , Essam Sayed , Ibrahim A. Abba , Abdul Rahman Zafer Akhras
IPC分类号： C10G55/04 , C10G45/00 , C10G9/36 , C10G67/04 , C10G69/06 , C10G21/00
CPC分类号： C10G55/04 , C10G9/36 , C10G21/003 , C10G45/00 , C10G67/0463 , C10G67/049 , C10G69/06 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： A system is provided integrating a steam pyrolysis zone integrated with a solvent deasphalting zone and a hydrotreating zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics.

5. 发明授权

US09284502B2 Integrated solvent deasphalting, hydrotreating and steam pyrolysis process for direct processing of a crude oil 有权
标题翻译：综合溶剂脱沥青，加氢处理和蒸汽热解过程直接加工原油
公开(公告)号：US09284502B2
公开(公告)日：2016-03-15
申请号：US13865062
申请日：2013-04-17
申请人： Saudi Arabian Oil Company
发明人： Abdennour Bourane , Raheel Shafi , Essam Sayed , Ibrahim A. Abba , Abdul Rahman Zafer Akhras
IPC分类号： C10G69/06 , C10G45/00 , C10G9/36 , C10G67/04 , C10G21/00
CPC分类号： C10G55/04 , C10G9/36 , C10G21/003 , C10G45/00 , C10G67/0463 , C10G67/049 , C10G69/06 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a solvent deasphalting zone and a hydrotreating zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated solvent deasphalting, hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises: charging the crude oil to a solvent deasphalting zone with an effective amount of solvent for producing a deasphalted and demetalized oil stream and a bottom asphalt phase; charging the deasphalted and demetalized oil stream and hydrogen to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; thermally cracking the hydroprocessed effluent in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
摘要翻译：提供了一种方法，其涉及与溶剂脱沥青区和加氢处理区整合的蒸汽热解区，以允许原油原料直接加工以生产包括烯烃和芳族化合物的石化产品。用于直接加工原油以生产烯烃和芳族石油化学品的综合溶剂脱沥青，加氢处理和蒸汽热解过程包括：用有效量的溶剂将原油装入溶剂脱沥青区，用于产生脱沥青和脱金属的油料流，底部沥青相; 将脱沥青和脱金属的油流和氢气加氢到加氢处理区，在有效地产生具有降低的污染物含量，增加的链烷烃含量，减少的矿山相关指数和增加的美国石油协会重力的加氢处理流出物的条件下操作; 在蒸汽存在下对加氢处理的流出物进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流中回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流中回收热解燃料油。

6. 发明授权

US10246651B2 Integrated solvent deasphalting, hydrotreating and steam pyrolysis system for direct processing of a crude oil 有权
公开(公告)号：US10246651B2
公开(公告)日：2019-04-02
申请号：US15905107
申请日：2018-02-26
申请人： Saudi Arabian Oil Company
发明人： Abdennour Bourane , Raheel Shafi , Essam Sayed , Ibrahim A. Abba , Abdul Rahman Zafer Akhras
IPC分类号： C10G67/04 , C10G55/04 , C10G69/06 , C10G45/00 , C10G9/36 , C10G21/00
摘要： A system is provided integrating a steam pyrolysis zone integrated with a solvent deasphalting zone and a hydrotreating zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics.

7. 发明授权

US09650576B2 Steam cracking process and system with integral vapor-liquid separation 有权
公开(公告)号：US09650576B2
公开(公告)日：2017-05-16
申请号：US14491147
申请日：2014-09-19
申请人： Saudi Arabian Oil Company
发明人： Abdul Rahman Zafer Akhras , Abdennour Bourane , Raheel Shafi , Ibrahim A. Abba
IPC分类号： C10G9/36 , C10G9/16
CPC分类号： C10G9/36 , C10G9/16
摘要： An integrated vapor-liquid separation device is provided in conjunction with a steam pyrolysis cracking unit operation. In certain aspects, a feed is charged to the inlet of a convection portion of a steam pyrolysis unit where the feed is heated to conditions effective for steam cracking The convection section effluent is separated in a vapor-liquid separator and the separator vapor effluent is charged to the inlet steam cracking portion of the steam pyrolysis zone. The liquid effluent can be further processed, recycled within the system or a combination thereof. In additional aspects, a feed separated upstream of the convection portion of a steam pyrolysis unit using a flash vessel equipped with a vapor-liquid separator device described herein.

8. 发明授权

US10344227B2 Integrated hydrotreating and steam pyrolysis system including residual bypass for direct processing of a crude oil 有权
公开(公告)号：US10344227B2
公开(公告)日：2019-07-09
申请号：US15933655
申请日：2018-03-23
申请人： Saudi Arabian Oil Company
发明人： Raheel Shafi , Abdennour Bourane , Essam Sayed , Ibrahim A. Abba , Abdul Rahman Zafer Akhras
IPC分类号： C10G69/06 , C10G45/00 , C10G9/36
摘要： A system is provided that is directed to a steam pyrolysis zone integrated with a hydroprocessing zone including residual bypass to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics.

9. 发明授权

US09587185B2 Integrated hydrotreating and steam pyrolysis process for direct processing of a crude oil 有权
标题翻译：用于直接加工原油的综合加氢处理和蒸汽热解过程
公开(公告)号：US09587185B2
公开(公告)日：2017-03-07
申请号：US15012383
申请日：2016-02-01
申请人： Saudi Arabian Oil Company
发明人： Raheel Shafi , Julio Hasselmeyer , Abdennour Bourane , Ibrahim A. Abba , Abdul Rahman Zafer Akhras
IPC分类号： C10G69/06 , C10G45/00 , C10G9/36 , C10G69/08 , C10G69/10
CPC分类号： C10G69/06 , C10G9/36 , C10G45/00 , C10G2300/201 , C10G2300/308 , C10G2300/4081 , C10G2400/20 , C10G2400/30
摘要： An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. Hydroprocessed effluent is thermally cracked in the presence of steam to produce a mixed product stream, which is separated. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins and aromatics are recovered from the separated mixed product stream.
摘要翻译：提供了一种用于直接加工原油的综合加氢处理和蒸汽热解方法，用于生产烯烃和芳族石油化学品。将原油和氢气加入加氢处理区，在有效地产生减少了污染物含量，增加的链烷烃含量，降低的矿山相关指数和增加的美国石油研究所重力的加氢处理流出物的条件下操作。在蒸汽存在下，加氢处理的流出物被热裂解以产生分离的混合产物流。将来自混合产物流的氢气纯化并再循环至加氢处理区，并从分离的混合产物流中回收烯烃和芳族化合物。

10. 发明授权

US09284501B2 Integrated slurry hydroprocessing and steam pyrolysis of crude oil to produce petrochemicals 有权
标题翻译：综合浆料加氢处理和蒸汽热解原油生产石化产品
公开(公告)号：US09284501B2
公开(公告)日：2016-03-15
申请号：US13847969
申请日：2013-03-20
申请人： Saudi Arabian Oil Company
发明人： Esam Sayed , Raheel Shafi , Abdul Rahman Zafer Akhras , Abdennour Bourane , Ibrahim A. Abba
IPC分类号： C10G69/06 , C10G47/26 , C10G49/12 , C10G9/16 , C10G49/00 , C10G67/10 , C10G9/00 , C10G9/14 , C10G51/06
CPC分类号： C10G69/06 , C10G9/16 , C10G47/26 , C10G49/007 , C10G49/12 , C10G67/10 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： An integrated slurry hydroprocessing and steam pyrolosyis process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil, a steam pyrolysis residual liquid fraction and slurry reside are combined and treated in a hydroprocessing zone in the presence of hydrogen under conditions effective to produce an effluent having an increased hydrogen content. The effluent is thermally cracked with steam under conditions effective to produce a mixed product stream and steam pyrolysis residual liquid fraction. The mixed product stream is separated and olefins and aromatics are recovered and hydrogen is purified and recycled.
摘要翻译：提供了一种用于从原油原料生产烯烃和芳族石油化学品的综合浆料加氢处理和蒸汽热解法。将原油，蒸气热解残留液体馏分和淤浆存在下，在氢气存在下，在加氢处理区中，在有效地产生具有增加的氢含量的流出物的条件下进行处理。在有效产生混合产物流和蒸气热解残留液体馏分的条件下，流出物用蒸汽热裂解。分离混合的产物流，回收烯烃和芳族化合物，纯化和回收氢气。

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