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    • 1. 发明申请
    • Chemically amplified resist composition
    • US20080248423A1
    • 2008-10-09
    • US12076529
    • 2008-03-19
    • Satoshi YAMAGUCHIYoshiyuki TAKATAKaoru ARAKI
    • Satoshi YAMAGUCHIYoshiyuki TAKATAKaoru ARAKI
    • G03F7/004
    • G03F7/0045G03F7/0046G03F7/0397Y10S430/106Y10S430/111Y10S430/122
    • A chemically amplified resist composition comprising:(A) a salt represented by the formula (I): wherein R21 represents a C1-C30 hydrocarbon group etc., Q1 and Q2 each independently represent a fluorine atom etc., and A+ represents at least one organic cation selected from a cation represented by the formula (Ia): wherein P1, P2 and P3 each independently represent a C1-C30 alkyl group etc., a cation represented by the formula (Ib): wherein P4 and P5 each independently represent a hydrogen atom etc., and a cation represented by the formula (Ic): wherein P10, P11, P12, P13, P14, P15, P16, P17, P18, P19, P20 and P21 each independently represent a hydrogen atom etc., B represents a sulfur or oxygen atom and m represents 0 or 1, (B) a salt represented by the formula (II): A′+−E   (II) wherein A′+ represents at least one organic cation selected from cations represented by the above-mentioned formulae (Ia), (Ib) and (Ic), and E− represents at least one organic anion selected from an anion represented by the formula (II-1): −O3SQ3   (II-1) wherein Q3 represents a C1-C10 perfluoroalkyl group, and an anion represented by the formula (II-2): wherein Q4 represents a C1-C10 perfluoroalkyl group, and (C) a resin which contains a structural unit having an acid-labile group and which itself is insoluble or poorly soluble in an aqueous alkali solution but becomes soluble in an aqueous alkali solution by the action of an acid.
    • 2. 发明申请
    • CHEMICALLY AMPLIFIED RESIST COMPOSITION
    • 化学稳定组分
    • US20080193874A1
    • 2008-08-14
    • US12021149
    • 2008-01-28
    • Yoshiyuki TAKATASatoshi YAMAMOTOSatoshi YAMAGUCHI
    • Yoshiyuki TAKATASatoshi YAMAMOTOSatoshi YAMAGUCHI
    • G03F7/004
    • G03F7/0397G03F7/0045G03F7/0046Y10S430/111Y10S430/122Y10S430/123
    • The present invention provides a chemically amplified resist composition comprising:a resin which comprises a structural unit having an acid-labile group and a structural unit represented by the formula (I): wherein R1 represents a hydrogen atom or a methyl group, ring X represents a C3-C30 cyclic hydrocarbon group in which one —CH2— is substituted with —COO—, and at least one hydrogen atom in the C3-C30 cyclic hydrocarbon group may be substituted, and p represents an integer of 1 to 4, and which itself is insoluble or poorly soluble in an alkali aqueous solution but becomes soluble in an alkali aqueous solution by the action of an acid, and at least two salts selected from a salt represented by the formula (II): wherein Y1 and Y2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, A+ represents an organic counter ion and R21 represents a C1-C30 hydrocarbon group which may be substituted and at least one —CH2— in the C1-C30 hydrocarbon group may be substituted with —CO— or —O—, and a salt represented by the formula (III): A′+−O3S—R23   (III) wherein R23 represents a C1-C8 linear or branched chain perfluoroalkyl group and A′+ represents an organic counter ion.
    • 本发明提供一种化学放大抗蚀剂组合物,其包括:树脂,其包含具有酸不稳定基团的结构单元和由式(I)表示的结构单元:其中R 1表示氢原子 或甲基,环X表示其中一个-CH 2 - 被-COO-取代的C 3 -C 30环烃基,和C 3 -C 30环烃基中的至少一个氢原子 可以被取代,p表示1〜4的整数,其本身在碱性水溶液中不溶或难溶,但通过酸的作用而溶于碱性水溶液中,并且选自: 由式(II)表示的盐:其中Y 1和Y 2各自独立地表示氟原子或C 1 -C 6全氟烷基, SUP>表示有机抗衡离子,R 21表示可以被取代的C 1 -C 30烃基, C1-C30烃基中的至少一个-CH 2 - 可以被-CO-或-O-取代,和由式(III)表示的盐:<β在线式 描述=“在线公式”end =“lead”?> A' + - O 3 3 -line-formula description =“In-line Formulas”end =“tail”?>其中R 23表示C1-C8直链或支链全氟烷基,A'+ SUP >表示有机抗衡离子。