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    • 3. 发明申请
    • HIGH PURITY COBALT, METHOD OF MANUFACTURING THEREOF, AND HIGH PURITY COBALT TARGETS
    • 高纯度钴,其制造方法和高纯度钴钴靶
    • US20070180953A1
    • 2007-08-09
    • US10803506
    • 2004-03-17
    • Masahito UchikoshiNorio YokoyamaTamas KekesiMinoru Isshiki
    • Masahito UchikoshiNorio YokoyamaTamas KekesiMinoru Isshiki
    • B22F9/24C22B23/00
    • C22B23/0423C22B3/42C22B23/0461Y02P10/234
    • High purity cobalt with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity cobalt targets are provided. The cobalt containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of cobalt chloride is adjusted to 0.1 kmol/m3 to 3 kmol/m3. Then, cobalt is added in the aqueous solution of cobalt chloride, and an inert gas is injected into the solution with agitating, in order to convert the divalent copper ions contained in the aqueous solution of cobalt chloride to monovalent copper ions. Then, the aqueous solution of cobalt chloride is fed into a column filled up with the anion exchange resins. Cobalt is not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of cobalt chloride. And then, the aqueous solution of cobalt chloride is evaporated to dryness and heated to 623 K to 873 K in a hydrogen atmosphere to generate cobalt.
    • 提供了非常少量杂质如铜的高纯度钴,其制造方法和高纯度钴靶。 将含钴杂质如铜溶解在盐酸溶液中,氯化钴水溶液的盐酸浓度调节至0.1kmol / m 3至3kmol / m 3, SUP> 3 。 然后,将钴加入到氯化钴水溶液中,并将惰性气体搅拌注入溶液中,以将氯化钴水溶液中所含的二价铜离子转化为一价铜离子。 然后,将氯化钴水溶液加入填充有阴离子交换树脂的柱中。 尽管单价铜离子被吸收在阴离子交换树脂上,但是钴不会吸收在阴离子交换树脂上。 因此,可以从氯化钴水溶液中分离出铜。 然后,将氯化钴水溶液蒸发至干,并在氢气氛中加热至623K至873K,以产生钴。
    • 6. 发明授权
    • High purity cobalt, method of manufacturing thereof, and high purity cobalt targets
    • 高纯钴,其制造方法和高纯度钴靶
    • US06740290B2
    • 2004-05-25
    • US09966861
    • 2001-09-28
    • Masahito UchikoshiNorio YokoyamaTamas KekesiMinoru Isshiki
    • Masahito UchikoshiNorio YokoyamaTamas KekesiMinoru Isshiki
    • C22C1907
    • C22B23/0423C22B3/42C22B23/0461Y02P10/234
    • High purity cobalt with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity cobalt targets are provided. The cobalt containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of cobalt chloride is adjusted to 0.1 kmol/m3 to 3 kmol/m3. Then, cobalt is added in the aqueous solution of cobalt chloride, and an inert gas is injected into the solution with agitating, in order to convert the divalent copper ions contained in the aqueous solution of cobalt chloride to monovalent copper ions. Then, the aqueous solution of cobalt chloride is fed into a column filled up with the anion exchange resins. Cobalt is not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of cobalt chloride. And then, the aqueous solution of cobalt chloride is evaporated to dryness and heated to 623 K to 873 K in a hydrogen atmosphere to generate cobalt.
    • 提供了非常少量杂质如铜的高纯度钴,其制造方法和高纯度钴靶。 将含钴杂质如铜溶解在盐酸溶液中,氯化钴水溶液的盐酸浓度调节至0.1kmol / m 3至3kmol / m 3。 然后,将钴加入到氯化钴水溶液中,并将惰性气体搅拌注入溶液中,以将氯化钴水溶液中所含的二价铜离子转化为一价铜离子。 然后,将氯化钴水溶液加入填充有阴离子交换树脂的柱中。 尽管单价铜离子被吸收在阴离子交换树脂上,但是钴不会吸收在阴离子交换树脂上。 因此,可以从氯化钴水溶液中分离出铜。 然后,将氯化钴水溶液蒸发至干,并在氢气氛中加热至623K至873K,以产生钴。
    • 7. 发明授权
    • Sputtering target and its manufacturing method
    • 溅射靶及其制造方法
    • US06409965B1
    • 2002-06-25
    • US09666241
    • 2000-09-21
    • Takahiro NagataManabu SasakiHitoshi KimuraNorio Yokoyama
    • Takahiro NagataManabu SasakiHitoshi KimuraNorio Yokoyama
    • C22C3200
    • C23C14/3414
    • An ingot is made from a used target of 30 weight % or more, and new metals of the same components, and recycled alloy powder is made by a gas atomizing process. Magnetic permeability is controlled not to exceed 2 by adjusting the content of rare earth metals in rare earth alloy powder to be at least 35 weight %. By blending the recycled alloy powder with other powder to produce alloy powder containing at least 50 weight % of rare earth alloy powder having a magnetic permeability not higher than 2 and containing at least 65 weight % of rare earth alloy powder. By sintering the alloy powder under pressure and thereafter cutting top, bottom and side surfaces of the sintered material, a target having a magnetic permeability not higher than 2 and having a thickness not less than 8 mm is fabricated.
    • 铸锭由30重量%以上的使用靶材制成,相同成分的新金属,再生合金粉末由气体雾化法制成。 通过将稀土类合金粉末中的稀土金属的含量调整至少35重量%,将磁导率控制在2以下。 通过将再循环合金粉末与其它粉末混合,制造含有至少50重量%的磁导率不高于2的稀土合金粉末并含有至少65重量%的稀土合金粉末的合金粉末。 通过在压力下烧结合金粉末,然后切割烧结材料的顶部,底部和侧面,制造具有不高于2的磁导率并且厚度不小于8mm的靶。
    • 9. 发明授权
    • High purity cobalt, method of manufacturing thereof, and high purity cobalt targets
    • 高纯钴,其制造方法和高纯度钴靶
    • US07279024B2
    • 2007-10-09
    • US10803506
    • 2004-03-17
    • Masahito UchikoshiNorio YokoyamaTamas KekesiMinoru Isshiki
    • Masahito UchikoshiNorio YokoyamaTamas KekesiMinoru Isshiki
    • C22B23/00
    • C22B23/0423C22B3/42C22B23/0461Y02P10/234
    • High purity cobalt with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity cobalt targets are provided. The cobalt containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of cobalt chloride is adjusted to 0.1 kmol/m3 to 3 kmol/m3. Then, cobalt is added in the aqueous solution of cobalt chloride, and an inert gas is injected into the solution with agitating, in order to convert the divalent copper ions contained in the aqueous solution of cobalt chloride to monovalent copper ions. Then, the aqueous solution of cobalt chloride is fed into a column filled up with the anion exchange resins. Cobalt is not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of cobalt chloride. And then, the aqueous solution of cobalt chloride is evaporated to dryness and heated to 623 K to 873 K in a hydrogen atmosphere to generate cobalt.
    • 提供了非常少量杂质如铜的高纯度钴,其制造方法和高纯度钴靶。 将含钴杂质如铜溶解在盐酸溶液中,氯化钴水溶液的盐酸浓度调节至0.1kmol / m 3至3kmol / m 3, SUP> 3 。 然后,将钴加入到氯化钴水溶液中,并将惰性气体搅拌注入溶液中,以将氯化钴水溶液中所含的二价铜离子转化为一价铜离子。 然后,将氯化钴水溶液加入填充有阴离子交换树脂的柱中。 尽管单价铜离子被吸收在阴离子交换树脂上,但是钴不会吸收在阴离子交换树脂上。 因此,可以从氯化钴水溶液中分离出铜。 然后,将氯化钴水溶液蒸发至干,并在氢气氛中加热至623K至873K,以产生钴。
    • 10. 发明授权
    • Metal purification method and metal refinement method
    • 金属净化方法和金属细化方法
    • US06391081B1
    • 2002-05-21
    • US09533537
    • 2000-03-23
    • Masahito UchikoshiNorio YokoyamaMinoru IsshikiKouji Mimura
    • Masahito UchikoshiNorio YokoyamaMinoru IsshikiKouji Mimura
    • C22B905
    • C22B4/005C22B9/226C22B23/06
    • A metal purification method and a metal refinement method in which metals of high purity can be easily refined and recovered without increasing the size of the purification and refining devices or complicating the operation. To this end, metals containing impurities are molten in a plasma arc containing active hydrogen to remove the impurities. If the metals contain ceramics inclusions, the metals are molten in a plasma arc containing active hydrogen and the ceramics inclusions are caused to float over the molten metal by exploiting the difference of density between the molten metal and the ceramics inclusions. The floating ceramics inclusions are decomposed and removed. For application to refining, the metal oxides are molten in a plasma arc containing active hydrogen so as to be reduced to metals.
    • 金属净化方法和金属精制方法,其中可以容易地精炼和回收高纯度的金属,而不增加净化和精制装置的尺寸或使操作变得复杂。 为此,含有杂质的金属在含有活性氢的等离子弧中熔融以除去杂质。 如果金属含有陶瓷夹杂物,则金属在含有活性氢的等离子体电弧中熔融,并且通过利用熔融金属和陶瓷夹杂物之间的密度差,使陶瓷夹杂物漂浮在熔融金属上。 浮选的陶瓷夹杂物被分解和去除。 为了应用于精炼,金属氧化物在含有活性氢的等离子体电弧中熔化,从而还原成金属。