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1. 发明专利

JP2007128782A Electrode for secondary battery 审中-公开
标题翻译：二次电池电极
公开(公告)号：JP2007128782A
公开(公告)日：2007-05-24
申请号：JP2005321387
申请日：2005-11-04
申请人： Sanyo Electric Co Ltd , Sumitomo Electric Ind Ltd , 三洋電機株式会社 , 住友電気工業株式会社
发明人： YOSHIDA KENTARO , AWATA HIDEAKI , OKUNO KAZUKI , IHARA HIROHIKO , YAGI HIROMASA
IPC分类号： H01M4/02 , H01M4/13 , H01M4/139 , H01M10/05
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide an electrode for a secondary battery capable of suppressing reduction of a battery capacity caused by the fact that an active material layer falls off from a current collector or inside fractures occur because of swelling and contraction accompanied with charge and discharge, and provide the secondary battery provided with this electrode.
SOLUTION: This is the electrode for the secondary battery in which the active material layer containing the active material to carry out storing and release of metal ions is equipped on the current collector, the active material layer contains oxygen, and in this active material layer, oxygen concentration of the boundary part to the current collector and oxygen concentration inside the active material layer satisfy (oxygen concentration at the boundary part of active material layer)/(oxygen concentration inside active material layer)
摘要翻译：要解决的问题：提供一种能够抑制活性物质层从集电体脱落的事实引起的电池容量的降低的二次电池用电极，或者由于伴随着发生膨胀和收缩而发生内部断裂充电和放电，并提供设置有该电极的二次电池。解决方案：这是用于二次电池的电极，其中含有活性材料的活性材料层用于进行金属离子的储存和释放的装置设置在集电器上，活性材料层含有氧，并且在该活性物质中材料层，与集电体的边界部分的氧浓度和活性物质层内的氧浓度满足（活性物质层的边界部位的氧浓度）/（活性物质层内的氧浓度）<3。通过降低边界部分的氧浓度，金属离子和氧气反应形成氧化物，并且通过该氧化物可以抑制与集电体的粘合强度降低或活性物质层内部被氧化物断裂作为起点。活性物质层可以通过气相法形成。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2007042329A Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：JP2007042329A
公开(公告)日：2007-02-15
申请号：JP2005223034
申请日：2005-08-01
申请人： Mitsui Chemicals Inc , Sanyo Electric Co Ltd , 三井化学株式会社 , 三洋電機株式会社
发明人： HIBARA AKIO , NOGI YOSHINOBU , YAGI HIROMASA
IPC分类号： H01M4/02 , H01M4/38 , H01M10/05 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0569
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a lithium secondary battery aiming at further high energy density by drastically alleviating lowering of discharging capacity accompanying a charging/discharging cycle.
SOLUTION: By paying attention to two characteristics of the lithium secondary battery, especially, a coefficient of cubic expansion of an anode activator at a charged state to that at a discharging state, and a composition of nonaqueous electrolyte, an anode activator containing an element of 12th to 15th group of the periodic table is used, a ratio of quantity of the anode activator to the cathode activator, discharging capacity, or the like are appropriately selected so that a coefficient of cubic expansion becomes 50% or higher, and a nonaqueous electrolyte containing fluorinated ethylene carbonate, carbonate composed of only hydrogen, oxygen and carbon, and lithium salt, of which a content of the fluorinated ethylene carbonate to the total quantity of the electrolyte is not less than 2 wt.%.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：通过显着地减轻伴随充放电循环的放电容量的降低来提供旨在进一步提高能量密度的锂二次电池。解决方案：通过注意锂二次电池的两个特性，特别是在充电状态下的阳极活化剂与放电状态下的立方膨胀系数，以及非水电解质的组成，含有使用周期表第12〜15族的元素，适当选择阳极活化剂与阴极活化剂的配合比例，放电容量等，使立方体膨胀系数成为50％以上，包含氟化碳酸亚乙酯的非水电解质，仅由氢，氧和碳组成的碳酸酯和锂盐，其中氟化碳酸亚乙酯的含量相对于电解质总量不小于2重量％。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2006269242A Negative electrode for lithium secondary battery, and lithium secondary battery 有权
标题翻译：锂二次电池负极和锂二次电池
公开(公告)号：JP2006269242A
公开(公告)日：2006-10-05
申请号：JP2005085372
申请日：2005-03-24
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： MINAMI HIROYUKI , FUKUI ATSUSHI , YAGI HIROMASA , JINNO MARUO
IPC分类号： H01M4/02 , H01M4/04 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/62 , H01M4/64 , H01M4/66 , H01M10/05
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a negative electrode for lithium secondary battery in which a negative electrode mixture layer including a negative electrode active material containing silicon and/or silicon alloy and a binder is made to be sufficiently adhered to a negative electrode current collector and cycle life of the lithium secondary battery is improved. SOLUTION: As for a negative electrode 11 for lithium secondary battery, a conductive intermediate layer 11b which does not react with Li is deposited and formed on a negative electrode current collector 11a consisting of a metal foil by supplying a material from a gas phase, and a negative electrode mixture layer 11c including a negative electrode active material containing silicon and/or silicon alloy and a binder is formed on this conductive intermediate layer, and with this state, these are sintered in a non-oxidizing atmosphere. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：为了提供一种锂二次电池的负极，其中包括含有硅和/或硅合金的负极活性物质和粘合剂的负极混合物层被充分粘附到负极提高了锂二次电池的集电极和循环寿命。解决方案：对于锂二次电池用负极11，通过从气体供给材料，在由金属箔构成的负极集电体11a上沉积不与Li反应的导电性中间层11b 在该导电性中间层上形成含有硅和/或硅合金的负极活性物质和粘合剂的负极合剂层11c，在这种状态下，在非氧化性气氛中烧结。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2005293852A Manufacturing method of lithium secondary battery and anode for the lithium secondary battery 审中-公开
标题翻译：锂二次电池的锂二次电池和阳极的制造方法
公开(公告)号：JP2005293852A
公开(公告)日：2005-10-20
申请号：JP2004102371
申请日：2004-03-31
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： YAGI HIROMASA , MINAMI HIROYUKI , SAYAMA KATSUNOBU
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M10/05 , H01M4/02 , H01M4/04 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To obtain a battery with a large charge/discharge capacity and superior cycle characteristics for a lithium secondary battery, equipped with an anode using as an active material a thin film containing silicon deposited on the surfaces of a collector, a cathode, and a nonaqueous electrolyte.
SOLUTION: Of the lithium secondary battery, provided with the anode using the thin film containing silicon deposited on the surface of the collector, the cathode, and the nonaqueous electrolyte, the thin film contains metal different from the main ingredient of the surface of the collector, and the concentration of the metal is gradually decreased as going from the collector side of the film toward a surface side.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题为了获得锂二次电池具有大的充放电容量和优异的循环特性的电池，该锂二次电池配备有使用沉积在集电体表面上的含有硅的薄膜作为活性材料的阳极，阴极和非水电解质。解决方案：在使用沉积在集电体，阴极和非水电解质表面上的含有硅的薄膜的锂二次电池中，薄膜含有不同于表面主要成分的金属，并且从膜的集电体侧朝向表面侧，金属的浓度逐渐降低。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2004335256A Lithium secondary cell electrode and its manufacturing method 审中-公开
标题翻译：锂二次电池电极及其制造方法
公开(公告)号：JP2004335256A
公开(公告)日：2004-11-25
申请号：JP2003129330
申请日：2003-05-07
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： YAGI HIROMASA , MINAMI HIROYUKI , TARUI HISAKI
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M10/05 , H01M4/02 , H01M4/04 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide an electrode for a lithium secondary cell capable of increasing charge and discharge capacity and improving cycle characteristics.
SOLUTION: This electrode for the lithium secondary cell is equipped with an anode collector 1 made of a zirconium copper foil and an anode active material layer 2 made of a silicon film with boron of 0.01 atom % or more added formed on the anode collector 1 made of the zirconium copper foil.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决的问题：提供一种能够提高充放电容量并提高循环特性的锂二次电池用电极。解决方案：该锂二次电池用电极配备有由铜铜箔构成的负极集电体1和阳极活性物质层2，阳极活性物质层2由在阳极上形成的添加有0.01原子％以上的硼的硅膜构成收集器1由锆铜箔制成。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2004179136A Lithium secondary battery and manufacturing method thereof 有权
公开(公告)号：JP2004179136A
公开(公告)日：2004-06-24
申请号：JP2003027805
申请日：2003-02-05
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： MINAMI HIROYUKI , SAYAMA KATSUNOBU , YAGI HIROMASA , FUKUI ATSUSHI , TORIMAE MARIKO , KUSUMOTO YASUYUKI , TARUI HISAKI
IPC分类号： H01M4/66 , H01M2/16 , H01M4/13 , H01M4/134 , H01M4/139 , H01M4/1395 , H01M4/38 , H01M4/40 , H01M4/46 , H01M4/62 , H01M10/04 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M10/058 , H01M10/40 , H01M4/02 , H01M4/04
CPC分类号： H01M4/622 , H01M2/1673 , H01M4/0404 , H01M4/0419 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/386 , H01M4/40 , H01M4/661 , H01M10/052 , H01M10/0565 , H01M10/058 , H01M2300/0085 , Y10T29/49108 , Y10T29/49115
摘要： PROBLEM TO BE SOLVED: To improve charge and discharge cycle characteristic by improving collecting ability inside an electrode in a lithium secondary battery provided with a negative electrode, which is provided with an active material layer 2 containing the active material for electrochemically occluding and releasing lithium on a current collector 1, and a positive electrode and the non-aqueous electrolyte. SOLUTION: The active material layer 2 is expanded and shrunken by occluding and releasing lithium, and cracks 4 are formed in the active material layer 2. Solid electrolyte 3 formed into gel by combining a high polymer and the electrolyte containing lithium salt is arranged in the cracks 4. COPYRIGHT: (C)2004,JPO

7. 发明专利

JP2004171904A Manufacturing method of electrode for lithium secondary battery 有权
公开(公告)号：JP2004171904A
公开(公告)日：2004-06-17
申请号：JP2002335883
申请日：2002-11-20
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： YAGI HIROMASA , MINAMI HIROYUKI , TARUI HISAKI
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/04 , H01M4/02
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of an electrode for a lithium secondary battery capable of suppressing deterioration of a charge and discharge characteristic and deterioration of workability due to embrittlement of a collector.
SOLUTION: The manufacturing method of the electrode for the lithium secondary battery is provided with a process of forming an active material layer comprising an amorphous silicon layer on a surface of the collector 6 comprising a surface-roughened rolled zirconium copper foil having heat resistance by spattering a target (a silicon target) 7 in an atmosphere containing mixed gas of gaseous argon (60sccm) and gaseous hydrogen (0-20sccm).
COPYRIGHT: (C)2004,JPO

8. 发明专利

JP2006260928A Manufacturing method for electrode for lithium secondary battery and lithium secondary battery 有权
标题翻译：锂二次电池和锂二次电池电极的制造方法
公开(公告)号：JP2006260928A
公开(公告)日：2006-09-28
申请号：JP2005076503
申请日：2005-03-17
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： KOBAYASHI KEI , YAGI HIROMASA , CHITO DAIZO , HIRASE MASAKI , SAYAMA KATSUNOBU
IPC分类号： H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/66 , H01M10/05
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method for an electrode for a lithium secondary battery with a high charging and discharging capacity and an excellent charging and discharging cycle property and capable of manufacturing an electrode with small deformation caused by charging and discharging such as wrinkles. SOLUTION: This manufacturing method for the electrode for lithium secondary battery manufacturing the electrode by depositing and forming a thin film comprising an active material storing and discharging lithium on a current collector comprises a process applying a tensile load to the electrode at least in one direction after forming the thin film up to a plastic deformation area of the current collector. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：提供一种具有高充放电能力和优异的充放电循环特性的锂二次电池用电极的制造方法，能够制造由充放电引起的变形小的电极如皱纹。解决方案：通过沉积和形成包含在集电器上储存和放电锂的活性材料的薄膜制造电极的该锂二次电池用电极的制造方法包括至少在电极上施加拉伸载荷的工序在形成薄膜之后的一个方向直到集电体的塑性变形区域。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2006073212A Non-aqueous electrolyte battery 有权
标题翻译：非水电解电池
公开(公告)号：JP2006073212A
公开(公告)日：2006-03-16
申请号：JP2004251445
申请日：2004-08-31
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： HIRASE MASAKI , YAGI HIROMASA , CHITO DAIZO , SAYAMA KATSUNOBU
IPC分类号： H01M4/04 , H01M4/02 , H01M4/13 , H01M4/134 , H01M4/139 , H01M4/1395 , H01M4/38 , H01M4/66 , H01M10/05
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of a lithium secondary battery electrode in which charge and discharge cycle characteristics are enhanced by improving the adhesiveness of an active material layer to a current collector by suppressing the occurrence of deformation such as a wrinkle in the current collector, and the manufacturing cost of the battery can be reduced by forming the active material on the current collector at a high formation speed.
SOLUTION: A concavo-convex shape is formed on the surface of a current collector 1, and a low-deposition speed layer 11 and a high-deposition speed layer 13 are formed on the current collector 1 in this order.
COPYRIGHT: (C)2006,JPO&NCIPI

10. 发明专利

JP2006066165A Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：JP2006066165A
公开(公告)日：2006-03-09
申请号：JP2004246101
申请日：2004-08-26
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： YAGI HIROMASA , MINAMI HIROYUKI , SAYAMA KATSUNOBU
IPC分类号： H01M4/02 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/66 , H01M10/05 , H01M10/052 , H01M10/0567
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To obtain a lithium secondary battery with large charging/discharging capacity and excellent cycle property, composed of an anode formed by depositing a non-crystalline thin film made of a silicon non-crystalline thin film or silicon as a main component on a current collector and using the non-crystalline thin film as an activator; a cathode; and a nonaqueous electrolyte. SOLUTION: The lithium secondary cell, composed of an anode formed by depositing a non-crystalline thin film made of a silicon non-crystalline thin film or silicon as a main component on a current collector and using the non-crystalline thin film as an activator; of a cathode; and of a nonaqueous electrolyte, is characterized by containing lithium carbonate in the nonaqueous electrolyte. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题为了获得具有大的充电/放电容量和优异的循环性能的锂二次电池，由通过沉积由非晶硅薄膜或硅制成的非晶体薄膜形成的阳极组成，集电器上的主要成分，使用非晶质薄膜作为活化剂; 阴极和非水电解质。解决方案：锂二次电池由通过在集电器上沉积由非晶硅非晶薄膜或硅作为主要成分制成的非晶薄膜而形成的阳极组成，并使用非晶体薄膜作为激活剂; 的阴极; 和非水电解质的特征在于在非水电解质中含有碳酸锂。版权所有（C）2006，JPO＆NCIPI

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