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1. 发明授权

US06515085B1 Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US06515085B1
公开(公告)日：2003-02-04
申请号：US08371048
申请日：1995-01-10
申请人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe' , Umberto Scata'
发明人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe' , Umberto Scata'
IPC分类号： C08F4649
CPC分类号： C08F10/00 , Y02P20/52 , C08F4/6543 , C08F4/6465 , C08F4/6565 , C08F4/64 , C08F4/651
摘要： Catalyst-forming components and catalysts for the polymerization of olefins based on said components are disclosed. The catalysts comprise the reaction product of: (a) an Al alkyl compound; (b) a silicon compound containing at least a Si—OR or Si—OCOR or Si—NR2 bond, R being a hydrocarbyl radical; and (c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate or said halogenated Ti compound and a silicon compound as defined in (b) in a molar ratio with the supported Ti compound from 1.0 mole to 5 moles of silicon compound per mole of Ti compound. The present invention refers to new supported components of catalysts for the polymerization of CH2═CHR olefins wherein R is an alkyl radical with 1 to 4 carbon atoms, or an aryl radical, and mixtures of said olefins with ethylene, and to the catalysts obtained from said components.
摘要翻译：公开了基于所述组分的用于烯烃聚合的催化剂形成组分和催化剂。催化剂包含以下反应产物：（a）Al烷基化合物;（b）至少含有Si-OR或Si-OCOR或Si-NR2键的硅化合物，R是烃基; 和（c）固体，其包含活性形式的二卤化镁作为必需的载体，并且在其上负载有Ti卤化物或卤代Ti-醇化物或所述卤代Ti化合物和（b）中定义的硅化合物与负载的Ti化合物的摩尔比为每摩尔Ti化合物1.0摩尔至5摩尔的硅化合物。本发明涉及用于聚合CH 2 = CHR烯烃的催化剂的新的负载组分，其中R是具有1-4个碳原子的烷基或芳基，以及所述烯烃与乙烯的混合物，以及由说组件。

2. 发明授权

US06194342B1 Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US06194342B1
公开(公告)日：2001-02-27
申请号：US08469735
申请日：1995-06-06
申请人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe′ , Umberto Scata′
发明人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe′ , Umberto Scata′
IPC分类号： B01J3104
CPC分类号： C08F10/00 , Y02P20/52 , C08F4/6543 , C08F4/6465 , C08F4/6565 , C08F4/64 , C08F4/651
摘要： The present invention relates to supported catalysts for the polymerization of alpha-olefins which comprise the reaction product of: (a) an Al-alkyl compound; (b) a silicon compound containing at least one Si—OR or Si—OCOR or Si—NR2 bond, R being a hydrocarbyl radical; (c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate and a particular type of electron donor compound. The present invention also relates to supported catalyst components.
摘要翻译：本发明涉及用于α-烯烃聚合的载体催化剂，其包含以下反应产物：（a）Al-烷基化合物;（b）含有至少一个Si-OR或Si-OCOR或Si- NR2键，R是烃基;（c）包含活性形式的二卤化镁作为必需的载体的固体，并且其上载有Ti卤化物或卤代Ti-醇化物和特定类型的电子给体化合物。本发明还涉及负载型催化剂组分。

3. 发明授权

US5618771A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US5618771A
公开(公告)日：1997-04-08
申请号：US469734
申请日：1995-06-06
申请人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe , Umberto Scata
发明人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe , Umberto Scata
IPC分类号： C08F4/00 , B01J31/38 , C08F4/02 , C08F4/04 , C08F4/60 , C08F4/64 , C08F4/646 , C08F4/649 , C08F4/65 , C08F4/651 , C08F4/654 , C08F4/658 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/00 , Y02P20/52
摘要： Disclosed are catalysts for the polymerization of alpha-olefins which comprise the reaction product of:(a) an Al alkyl compound;(b) a silicon compound containing at least a Si--OR or Si--OCOR or Si--NR.sub.2 bond, R being a hydrocarbyl radical;(c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate and a particular, selected type of electron-donor compound.
摘要翻译：公开了用于α-烯烃聚合的催化剂，其包括以下反应产物：（a）Al烷基化合物; （b）至少含有Si-OR或Si-OCOR或Si-NR2键的硅化合物，R为烃基; （c）固体，其包含活性形式的二卤化镁作为必需的载体，并且其上载有Ti卤化物或卤代钛醇化物和特定的选择类型的电子给体化合物。

4. 发明授权

US06777508B1 Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US06777508B1
公开(公告)日：2004-08-17
申请号：US08291081
申请日：1994-08-17
申请人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe′ , Umberto Scata′
发明人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe′ , Umberto Scata′
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F4/6543 , C08F4/6465 , C08F4/651
摘要： Disclosed are catalysts for the polymerization of alpha-olefins which comprise the reaction product of: (a) an Al-alkyl compound; (b) a silicon compound containing at least one Si—OR or Si—OCOR or Si—NR2 bond, R being a hydrocarbyl radical; (c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate and a particular type of electron donor compound. The present invention refers to new supported components of catalysts for the polymerization of CH2═CHR olefins wherein R is an alkyl radical with 1 to 4 carbon atoms, or an aryl radical, and mixtures of said olefins with ethylene and the catalysts obtained from said components.
摘要翻译：公开了用于α-烯烃聚合的催化剂，其包含以下反应产物：（a）Al-烷基化合物;（b）含有至少一个Si-OR或Si-OCOR或Si-NR 2键的硅化合物，R 是一种烃基;（c）一种固体，其包含活性形式的二卤化镁作为必需的载体，并在其上负载有Ti卤化物或卤代Ti-醇化物和特定类型的电子给体化合物。本发明涉及用于CH 2 = CHR烯烃聚合的催化剂的新负载组分，其中R是具有1-4个碳原子的烷基或芳基，以及所述烯烃与乙烯的混合物和由所述组分获得的催化剂。

5. 发明授权

US5539067A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US5539067A
公开(公告)日：1996-07-23
申请号：US439678
申请日：1995-05-12
申请人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier C. Barbe' , Umerto Scata'
发明人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier C. Barbe' , Umerto Scata'
IPC分类号： C08F4/00 , B01J31/38 , C08F4/02 , C08F4/04 , C08F4/60 , C08F4/64 , C08F4/646 , C08F4/649 , C08F4/65 , C08F4/651 , C08F4/654 , C08F4/658 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/00 , Y02P20/52
摘要： Disclosed are catalysts for the polymerization of alpha-olefins which comprise the reaction product of:(a) an Al alkyl compound;(b) a silicon compound containing at least a Si--OR or Si--OCOR or Si--NR.sub.2 bond, R being a hydrocarbyl radical;(c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate and a particular, selected type of electron-donor compound.
摘要翻译：公开了用于α-烯烃聚合的催化剂，其包括以下反应产物：（a）Al烷基化合物; （b）至少含有Si-OR或Si-OCOR或Si-NR2键的硅化合物，R为烃基; （c）固体，其包含活性形式的二卤化镁作为必需的载体，并且其上载有Ti卤化物或卤代钛醇化物和特定的选择类型的电子给体化合物。

6. 发明授权

US4713416A Thermoplastic compositions including polyphenylenether, having improved impact strength and processability characteristics 失效
标题翻译：热塑性组合物包括聚苯乙烯，具有改进的冲击强度和加工特性
公开(公告)号：US4713416A
公开(公告)日：1987-12-15
申请号：US671314
申请日：1984-11-14
申请人： Luciano Del Giudice , Roberto Nocci , Umberto Giannini , Giuseppe Gianotti
发明人： Luciano Del Giudice , Roberto Nocci , Umberto Giannini , Giuseppe Gianotti
IPC分类号： C08L23/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/06 , C08L53/00 , C08L67/00 , C08L69/00 , C08L71/00 , C08L71/12 , C08L77/00 , C08L101/00 , C08L61/04 , C08L71/04
CPC分类号： C08L71/123 , C08L67/00 , C08L69/00 , C08L71/00 , C08L77/00 , Y10S525/905
摘要： Thermoplastic compositions based on polyphenylenether resins, endowed with improved mechanical, thermal and solvent-resistance characteristics, comprising, for 100 parts by weight of polyphenylenether resin:(a) from 0 to 90 parts by weight of a thermoplastic polymer other than polystyrene and incompatible with the polyphenylenether resin, and(b) from 1 to 90 parts by weight of a polymeric compatibility-promoting agent comprising one or more blocks of vinylacromatic monomeric units compatible with the polyphenylenether resin, and one or more blocks of monomeric units of the same nature as the thermoplastic polymer (a), or compatible with that polymer.
摘要翻译：基于多苯基树脂的热塑性组合物具有改进的机械，耐热和耐溶剂性特征，包括：对于100重量份的聚苯基树脂：（a）0至90重量份的除聚苯乙烯以外的热塑性聚合物，所述多苯基树脂和（b）1至90重量份的包含与所述多苯基树脂相容的一个或多个乙烯基芳族单体单元的嵌段的聚合物相容性促进剂，以及一种或多种与热塑性聚合物（a），或与该聚合物相容。

7. 发明授权

US6114461A Process for the preparation of vinylaromatic copolymers reinforced with rubber 失效
标题翻译：用橡胶制备乙烯基芳族共聚物的方法
公开(公告)号：US6114461A
公开(公告)日：2000-09-05
申请号：US805077
申请日：1997-02-21
申请人： Davide Preti , Anna Grazia Rossi , Roberto Nocci , Nicola Vecchini
发明人： Davide Preti , Anna Grazia Rossi , Roberto Nocci , Nicola Vecchini
IPC分类号： C08F279/00 , C08F279/02 , C08F279/04 , C08F285/00 , C08F287/00 , C08F297/04 , C08L51/04 , C08L55/02 , C08F255/00 , C08F255/02 , C08F255/08
CPC分类号： C08F297/04 , C08F279/02 , C08F287/00 , C08L51/04 , C08L55/02
摘要： Process for the preparation of vinylaromatic copolymers reinforced with rubber which comprises:a) dissolving a dienic rubber (i) and/or a linear block elastomer, vinylaromatic monomer-1,3 conjugated diene (ii), in a mixture comprising at least one vinylaromatic monomer and a pair of solvents consisting of a polar solvent and a nonpolar solvent;b) polymerizing the solution thus obtained, possibly in the presence of an initiator.
摘要翻译：用于制备用橡胶增强的乙烯基芳族共聚物的方法，其包括：a）将二烯橡胶（i）和/或线性嵌段弹性体乙烯基芳族单体-1,3-共轭二烯（ii）溶解在包含至少一种乙烯基芳族化合物单体和一种由极性溶剂和非极性溶剂组成的溶剂; b）聚合所得到的溶液，可能在引发剂的存在下。

8. 发明授权

US5807928A Process for the preparation of ABS resins 失效
标题翻译：制备ABS树脂的方法
公开(公告)号：US5807928A
公开(公告)日：1998-09-15
申请号：US852076
申请日：1997-05-06
申请人： Davide Preti , Anna Grazia Rossi , Roberto Nocci , Nicola Vecchini
发明人： Davide Preti , Anna Grazia Rossi , Roberto Nocci , Nicola Vecchini
IPC分类号： C08F2/00 , C08F2/44 , C08F279/04 , C08F287/00 , C08F297/04 , C08L55/02 , C08G63/48
CPC分类号： C08F287/00 , C08F279/04
摘要： Process for the preparation of ABS which comprises: a) preparing a solution consisting of a diblock linear rubber of the type S-B dissolved in a mixture of monomers comprising styrene and acrylonitrile; b) feeding to the solution of step (a) at least one preformed ABS resin having an average volumetric diameter of the rubber particles contained in the polymeric matrix of more than 1.5 .mu.; c) dissolving the preformed ABS in the solution of step (a); d) feeding in continuous the solution thus obtained to a polymerization reactor for ABS resins; e) polymerizing the final solution to produce an ABS with a multimodal morphology.
摘要翻译：制备ABS的方法，其包括：a）制备溶解在包含苯乙烯和丙烯腈的单体混合物中的S-B型二嵌段线性橡胶组成的溶液; b）向步骤（a）的溶液中加入至少一种具有超过1.5μm的聚合物基质中包含的橡胶颗粒的平均体积直径的预先形成的ABS树脂; c）将预成型的ABS溶解在步骤（a）的溶液中; d）将如此得到的溶液连续供给到用于ABS树脂的聚合反应器中; e）聚合最终溶液以产生具有多峰形态的ABS。

9. 发明授权

US4925899A Bimodal star-block copolymers, showing excellent optical properties and resilience, and process for their manufacture 失效
标题翻译：双峰星形嵌段共聚物，显示出优异的光学性能和弹性，以及其制造方法
公开(公告)号：US4925899A
公开(公告)日：1990-05-15
申请号：US214831
申请日：1988-07-01
申请人： Gabriele Rendina , Roberto Nocci , Andrea Callaioli , Francesco Corrado
发明人： Gabriele Rendina , Roberto Nocci , Andrea Callaioli , Francesco Corrado
IPC分类号： C08F257/00 , C08F297/02 , C08F297/04 , C08G81/02
CPC分类号： C08G81/022 , C08F297/044
摘要： Bimodal star-block copolymers are disclosed containing from 60 to 90% by weight of an aromatic vinyl monomer and from 40 to 10% by weight of a conjugated diene, said copolymers having the general formula:(S--S.sub.1 --B/S.sub.2 --B.sub.1).sub.m --X--(B.sub.1 --S.sub.2 /B--S.sub.1).sub.nwherein X is a polyfunctional radical, m and n are integers (being m.ltoreq.n) the sum of which is between 3 and 20 and equal to the functionality degree of the radical X, S and S.sub.1 are polymer blocks of an aromatic vinyl monomer, B.sub.1 is an elastomeric copolymer of conjugated dienic units, containing up to 20% of all the dienic units of the copolymer, and B/S.sub.2 and S.sub.2 /B are blocks of copolymers of aromatic vinyl monomer and conjugated diene of the random and/or tapered type.
摘要翻译：公开了双峰型星形嵌段共聚物，其包含60至90重量％的芳族乙烯基单体和40至10重量％的共轭二烯，所述共聚物具有以下通式：（S-S1-B / S2-B1 ）mX-（B1-S2 / B-S1）n其中X是多官能基团，m和n是整数（m = n），其总和在3和20之间，并且等于基团X，S和S1是芳族乙烯基单体的聚合物嵌段，B1是共轭二烯单元的弹性共聚物，其含有共聚物中所有二烯单元的多达20％，B / S2和S2 / B是芳族乙烯基单体和随机和/或锥形类型的共轭二烯的共聚物。

10. 发明授权

US4762893A Block copolymers of olefines with vinyl aromatic monomers 失效
标题翻译：烯烃与乙烯基芳族单体的嵌段共聚物
公开(公告)号：US4762893A
公开(公告)日：1988-08-09
申请号：US812376
申请日：1985-12-23
申请人： Roberto Nocci , Giancarlo Attalla , Luciano Del Giudice , Robert E. Cohen , Floriana Bertinotti
发明人： Roberto Nocci , Giancarlo Attalla , Luciano Del Giudice , Robert E. Cohen , Floriana Bertinotti
IPC分类号： C08F297/00 , C08F4/64 , C08F210/00 , C08F210/06 , C08F212/06 , C08F297/06
CPC分类号： C08F297/06
摘要： Block copolymers of ethylene and/or alpha-olefins, in particular propylene, with vinyl aromatic monomers, comprising at least two polymeric blocks, one of which being a polyolefinic block and the other having a stereoregular structure and being formed by vinyl aromatic monomer units.
摘要翻译：乙烯和/或α-烯烃，特别是丙烯与乙烯基芳族单体的嵌段共聚物，其包含至少两个聚合物嵌段，其中一个是聚烯烃嵌段，另一个具有立构规整结构并由乙烯基芳族单体单元形成。

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