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1. 发明授权

US5569553A Battery design for achieving end-of-life indication during electrical discharge 失效
标题翻译：电池设计，用于在放电期间达到寿命终止指示
公开(公告)号：US5569553A
公开(公告)日：1996-10-29
申请号：US400975
申请日：1995-03-08
申请人： Sally A. Smesko , Esther S. Takeuchi , Steven J. Ebel
发明人： Sally A. Smesko , Esther S. Takeuchi , Steven J. Ebel
IPC分类号： H01M4/62 , H01M6/10 , H01M6/16 , H01M6/50 , H01M10/05 , H01M10/48
CPC分类号： H01M10/05 , H01M10/48 , H01M6/16 , H01M6/5055 , H01M4/625 , H01M6/10
摘要： A cell construction that makes use of unbalanced electrode components or portions comprising one of the electrodes of an electrochemical cell to provide an end-of-life indication, is described. The unbalanced electrode components can have dissimilar physical dimensions or dissimilar percent loading of electrode active material. This renders the one dissimilar electrode component having the lesser physical dimension, i.e., lesser surface area or thickness, or lesser quantity of electrode active material electrochemically unreactive prior to the other electrode component during the course of cell discharge. Upon the early exhaustion or unreactiveness of the one dissimilar electrode component, the total cell interelectrode working capacity is reduced by a predetermined factor. The remaining functional electrode component provides the cell with sufficient capacity for electrical discharge at a predetermined lower energy level.
摘要翻译：描述了使用不平衡电极部件或包括电化学电池的电极之一的部分来提供寿命终止指示的电池结构。不平衡的电极组件可以具有不同的物理尺寸或不同的电极活性材料的百分比负载。这使得在电池放电过程中，在另一个电极部件之前，电极活性材料具有较小的物理尺寸，即较小的表面积或厚度，或较少量的电化学活性物质的不相似电极组分。在一个不同电极部件的早期耗尽或不活动的情况下，总细胞电极间工作容量减小预定因子。剩余的功能电极组件为电池提供足够的容量以在预定的较低能量水平进行放电。

2. 发明授权

US5667916A Mixed cathode formulation for achieving end-of-life indication 失效
标题翻译：用于实现寿命终止指示的混合阴极配方
公开(公告)号：US5667916A
公开(公告)日：1997-09-16
申请号：US644452
申请日：1996-05-10
申请人： Steven J. Ebel , Sally Ann Smesko , Esther S. Takeuchi
发明人： Steven J. Ebel , Sally Ann Smesko , Esther S. Takeuchi
IPC分类号： H01M4/36 , H01M4/48 , H01M4/58 , H01M6/50 , H01M4/02
CPC分类号： H01M4/364 , H01M4/36 , H01M6/5055 , H01M4/483 , H01M4/5835
摘要： Battery-powered implantable medical devices require a suitable method for indicating end-of-service of the power source so that there is ample time for elective replacement of the device and/or power source. The present invention utilizes mixed cathode materials preferably comprising a major portion of a fluorinated carbon and a minor portion of a metal-containing material. This mixed cathode formulation is characterized by two, discretely different operating voltages, the second of which may be used as an end-of-life indicator.
摘要翻译：电池供电的植入式医疗设备需要适当的方法来指示电源的服务终点，以便有足够的时间来选择性地更换设备和/或电源。本发明利用混合阴极材料，优选地包含主要部分的氟化碳和少部分含金属的材料。该混合阴极配方的特征在于两个离散地不同的工作电压，其中第二个可以用作寿命终止指示器。

3. 发明授权

US5415959A Woven synthetic halogenated polymer fibers as separator material for electrochemical cells 失效
标题翻译：合成卤化聚合物纤维作为电化学电池的隔离材料
公开(公告)号：US5415959A
公开(公告)日：1995-05-16
申请号：US145782
申请日：1993-10-29
申请人： Michael F. Pyszczek , Christine A. Frysz , Steven J. Ebel , Esther S. Takeuchi
发明人： Michael F. Pyszczek , Christine A. Frysz , Steven J. Ebel , Esther S. Takeuchi
IPC分类号： H01M2/16 , H01M6/14 , H01M6/16 , H01M2/14
CPC分类号： H01M2/162
摘要： A fabric separator woven from synthetic halogenated polymeric fibers for use in an electrochemical cell comprising a Group IA, IIA and IIIB metal anode and a depolarizer/catholyte or a solid cathode/electrolyte system, is described. The separator is resistant to the highly oxidizing components present in the cell, is tear resistant and has a reduced thickness to minimize the diminishing effect of the separator on the volumetric amount of active components in the cell. The separator can be used by itself or as a laminate with a microporous film, preferably made of a fluoropolymeric fiber.
摘要翻译：描述了用于包含IA，IIA和IIIB族金属阳极的电化学电池和消偏振器/阴极电解液或固体阴极/电解质系统的由合成卤化聚合物纤维编织的织物隔离物。分离器对电池中存在的高度氧化成分具有抗性，具有抗撕裂性并且具有减小的厚度以最小化隔膜对电池中活性组分的体积量的减小的影响。隔膜可以单独使用或作为具有微孔膜的层压体使用，优选由含氟聚合纤维制成。

4. 发明授权

US4964877A Non-aqueous lithium battery 失效
标题翻译：非水锂电池
公开(公告)号：US4964877A
公开(公告)日：1990-10-23
申请号：US323281
申请日：1989-03-14
申请人： Pamela P. Keister , Ralph T. Mead , Barry C. Muffoletto , Esther S. Takeuchi , Steven J. Ebel , Michael A. Zelinsky , John M. Greenwood
发明人： Pamela P. Keister , Ralph T. Mead , Barry C. Muffoletto , Esther S. Takeuchi , Steven J. Ebel , Michael A. Zelinsky , John M. Greenwood
IPC分类号： A61N1/378 , H01M2/02 , H01M2/06 , H01M2/12 , H01M2/26 , H01M4/12 , H01M4/48 , H01M6/10 , H01M6/16 , H01M10/04
CPC分类号： H01M4/54 , A61N1/378 , H01M10/0413 , H01M10/0454 , H01M2/06 , H01M2/263 , H01M2/266 , H01M4/12 , H01M4/483 , H01M6/10 , H01M6/103 , H01M6/16 , H01M2/0217 , H01M2/12 , Y10T29/49108 , Y10T29/4911
摘要： A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure in the casing comprising a plurality of plates in spaced apart relation, a lithium anode comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum salt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag.sub.x V.sub.2 O.sub.y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted.
摘要翻译：一种用于输送高电流脉冲的固体阴极液体有机电解质锂电池，包括壳体，壳体中的阴极结构，包括间隔开的多个板，锂阳极，其包括插入在阴极板之间的多个阳极部分，包括在壳体中的锂盐和有机溶剂的组合的水性液体有机电解质可操作地接触阳极和阴极，提供给阳极的电连接和提供给阴极的电连接。根据本发明的一个方面，阴极包括作为活性材料Ag x V 2 O y，其中x在约0.5至约2.0的范围内，y在约4.5至约6.0的范围内，这有利地具有高体积容量和高速率能力，本发明的电池提供高容量的结果，在各种放电水平下显示出良好的电流脉冲特性，并且具有倾斜的放电，从而能够预测寿命的终止。

5. 发明授权

US5114811A High energy density non-aqueous electrolyte lithium cell operational over a wide temperature range 失效
标题翻译：高能量密度非水溶性电解质锂电池工作在宽温度范围内
公开(公告)号：US5114811A
公开(公告)日：1992-05-19
申请号：US475410
申请日：1990-02-05
申请人： Steven J. Ebel , Michael F. Pyszczyk , Christine A. Frysz , Michael A. Zelinsky
发明人： Steven J. Ebel , Michael F. Pyszczyk , Christine A. Frysz , Michael A. Zelinsky
IPC分类号： H01M2/16 , H01M4/66 , H01M6/16
CPC分类号： H01M6/16 , H01M2/1613 , H01M4/661 , H01M4/663 , H01M4/669 , H01M2300/0025
摘要： An electrochemical cell is provided having a metallic anode comprising a lithium-aluminum alloy, a solid cathode of electronically conductive material and an ionic conductive non-aqueous electrolyte solution operatively associated and in direct contact with the anode and cathode. The metallic anode comprises a lithium-aluminum alloy wherein aluminum comprises from about 0% to about 50% by weight of the alloy. The solid cathode comprises a fluorinated carbon such as poly carbon monofluoride, a metal oxide or a metal oxide bronze. The non-aqueous electrolyte solution comprises a first component consisting of a high boiling aprotic solvent or combinations thereof, and a second component consisting of at least one lithium salt. The electrochemical cell demonstrates an energy density of about 0.6WH/CC and exhibits consistent performance predictability over an operational range of from about -20.degree. C. to about 180.degree. C.

6. 发明授权

US4830940A Non-agueous lithium battery 失效
标题翻译：非电动锂电池
公开(公告)号：US4830940A
公开(公告)日：1989-05-16
申请号：US818879
申请日：1986-01-14
申请人： Pamela P. Keister , Ralph T. Mead , Barry C. Muffoletto , Ester S. Takeuchi , Steven J. Ebel , Michael A. Zelinsky , John M. Greenwood
发明人： Pamela P. Keister , Ralph T. Mead , Barry C. Muffoletto , Ester S. Takeuchi , Steven J. Ebel , Michael A. Zelinsky , John M. Greenwood
IPC分类号： A61N1/378 , H01M2/02 , H01M2/06 , H01M2/12 , H01M2/26 , H01M4/12 , H01M4/48 , H01M6/10 , H01M6/16 , H01M10/04
CPC分类号： H01M4/54 , A61N1/378 , H01M10/0413 , H01M10/0454 , H01M2/06 , H01M2/263 , H01M2/266 , H01M4/12 , H01M4/483 , H01M6/10 , H01M6/103 , H01M6/16 , A61N1/3758 , H01M2/0217 , H01M2/12
摘要： A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure inthe casing comprising a plurality of plates in spaced apart relation, a lithium anond comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum dalt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag.sub.x V.sub.2 O.sub.y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted. In accordance with another aspect of the present invention, the anode comprises a continuous elongated lithium element enclosed within a separator and folded into a plurality of sections interposed between the cathode plates, each of which individually is enclosed within separator material thereby enhancing the reliability of the cell. The cell of the present invention finds advantageous use as a power source for an implantable cardiac defibrillator.
摘要翻译：一种用于输送高电流脉冲的固体阴极液体有机电解质锂电池，包括壳体，壳体中的阴极结构，包括间隔开的多个板，包含插入在阴极板之间的多个阳极部分的锂阳极，包含硅酸盐和有机溶剂的组合的含水液体有机电解质在壳体中可操作地接触阳极和阴极，提供给阳极的电连接和提供给阴极的电连接。根据本发明的一个方面，阴极包括作为活性材料Ag x V 2 O y，其中x在约0.5至约2.0的范围内，y在约4.5至约6.0的范围内，这有利地具有高体积容量和高速率能力，本发明的电池提供高容量的结果，在各种放电水平下显示出良好的电流脉冲特性，并且具有倾斜的放电，从而能够预测寿命的终止。根据本发明的另一方面，阳极包括一个连续细长的锂元素，其包围在隔板内并折叠成插入在阴极板之间的多个部分，每个部分分别被封闭在隔板材料内，从而提高了可靠性细胞。本发明的细胞作为可植入心脏除颤器的动力源有优势的使用。

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