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    • 3. 发明申请
    • PHOTOCATALYST MATERIAL AND PHOTOCATALYST DEVICE
    • 光电材料和光电子器件
    • US20130105306A1
    • 2013-05-02
    • US13806950
    • 2011-06-24
    • Saki SonodaOsamu KawasakiJunichi KatoMutsuo Takenaga
    • Saki SonodaOsamu KawasakiJunichi KatoMutsuo Takenaga
    • C25B11/04
    • H01G9/205B01J27/24B01J35/004C01B3/042C01B13/0207C25B1/003C25B1/04C25B11/0478Y02E60/364Y02E60/368Y02E70/10
    • A photocatalyst material and a photocatalyst device capable of generating hydrogen from water by radiation of sunlight at high efficiency. The photocatalyst material according to the present invention includes a nitride-based compound semiconductor obtained by replacement of part of Ga and/or Al by a 3d-transition metal. The nitride-based compound semiconductor has one or more impurity bands. A light absorption coefficient of the nitride-based compound semiconductor is 1,000 cm−1 or more in an entire wavelength region of 1,500 nm or less and 300 nm or more. Further, the photocatalyst material satisfies the following conditions: the energy level of the bottom of the conduction band is more negative than the redox potential of H+/H2; the energy level of the top of the valence band is more positive than the redox potential of O2/H2O; and there is no or little degradation of a material even when the material is irradiated with light underwater.
    • 一种光催化剂材料和能够以高效率的阳光照射从水中产生氢的光催化剂装置。 根据本发明的光催化剂材料包括通过用3d-过渡金属置换部分Ga和/或Al而获得的氮化物基化合物半导体。 氮化物系化合物半导体具有一个以上的杂质带。 氮化物系化合物半导体的光吸收系数在1500nm以下且300nm以上的整个波长范围内为1000cm -1以上。 此外,光催化剂材料满足以下条件:导带底部的能级比H + / H2的氧化还原电位更负; 价带顶部的能级比O2 / H2O的氧化还原电位更正; 即使当材料在水下被照射时,材料也没有或几乎没有劣化。