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    • 1. 发明申请
    • Method of Diffusing a Catalyst for Electrochemical Oxygen Reduction
    • 扩散电催化氧化还原催化剂的方法
    • US20080058201A1
    • 2008-03-06
    • US11837008
    • 2007-08-10
    • John GordonHachiya ToshinoriShekar BalagopalSai Bhavaraju
    • John GordonHachiya ToshinoriShekar BalagopalSai Bhavaraju
    • B01J21/18B01J23/02B01J23/04B01J23/10B01J23/745B01J23/75B01J23/755
    • C25B11/0463C23C18/1216C23C18/1254C23C18/127C23C18/1275H01M4/8875H01M4/9016H01M4/96H01M8/08Y10S502/525Y10S516/901
    • An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated. The amount of premixed metal oxide is chosen in conjunction with the amount of metal salts to provide the desired molar ratio after heating and calcining of the aqueous solution.
    • 改进的气体扩散电极,其由分散在炭黑和疏水性粘合剂聚合物的混合物中的钙钛矿型氧化物组成。 用于电化学还原氧的改进的催化剂包括具有α和β位点的钙钛矿型化合物,并且在β位具有更大的阳离子摩尔比。 特别好的还原催化剂是钕钙锰矿。 将电催化剂用碳分散在电极的反应层中的改进方法提高了电极的性能和氧还原过程。 这是通过在金属盐的水溶液加热至凝胶然后加入炭然后煅烧之前将炭黑加入到水溶液中而提供的。 任选地,一定量的所需氧化物催化剂可以在将碳添加到待加热的金属盐的水溶液中之前与碳的一部分预混合。 联合金属盐的量选择预混合金属氧化物的量,以便在加热和煅烧水溶液之后提供所需的摩尔比。
    • 6. 发明申请
    • Gas Diffusion Electrode For Electrochemical Oxygen Reduction
    • 用于电化学氧还原的气体扩散电极
    • US20080057379A1
    • 2008-03-06
    • US11837032
    • 2007-08-10
    • John GordonHachiya ToshinoriShekar BalagopalSai Bhavaraju
    • John GordonHachiya ToshinoriShekar BalagopalSai Bhavaraju
    • H01M4/90C25B11/06
    • C25B11/0463C23C18/1216C23C18/1254C23C18/127C23C18/1275H01M4/8875H01M4/9016H01M4/96H01M8/08Y10S502/525Y10S516/901
    • An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated. The amount of premixed metal oxide is chosen in conjunction with the amount of metal salts to provide the desired molar ratio after heating and calcining of the aqueous solution.
    • 改进的气体扩散电极,其由分散在炭黑和疏水性粘合剂聚合物的混合物中的钙钛矿型氧化物组成。 用于电化学还原氧的改进的催化剂包括具有α和β位点的钙钛矿型化合物,并且在β位具有更大的阳离子摩尔比。 特别好的还原催化剂是钕钙锰矿。 将电催化剂用碳分散在电极的反应层中的改进方法提高了电极的性能和氧还原过程。 这是通过在金属盐的水溶液加热至凝胶然后加入炭然后煅烧之前将炭黑加入到水溶液中而提供的。 任选地,一定量的所需氧化物催化剂可以在将碳添加到待加热的金属盐的水溶液中之前与碳的一部分预混合。 联合金属盐的量选择预混合金属氧化物的量,以便在加热和煅烧水溶液之后提供所需的摩尔比。
    • 7. 发明授权
    • Electrochemical production of hydrogen
    • 电化学生产氢
    • US09297084B2
    • 2016-03-29
    • US13349269
    • 2012-01-12
    • Ashok V. JoshiSai Bhavaraju
    • Ashok V. JoshiSai Bhavaraju
    • C25B1/04C25B1/10C25B1/20C25B1/24C25B15/08C25B9/08
    • C25B1/10C25B1/04C25B1/20C25B1/24C25B9/08C25B9/10C25B13/04C25B15/08Y02E60/366Y02P20/134
    • Electrochemical systems and methods for producing hydrogen. Generally, the systems and methods involve providing an electrochemical cell that includes an anolyte compartment holding an anode in contact with an anolyte, wherein the anolyte includes an oxidizable substance having a higher standard oxidation potential than water. The cell further comprises a catholyte compartment holding a cathode in contact with a catholyte that includes a substance that reduces to form hydrogen. Additionally, the cell includes an alkali cation conductive membrane that separates the anolyte compartment from the catholyte compartment. As an electrical potential passes between the anode and cathode, the reducible substance reduces to form hydrogen and the oxidizable substance oxidizes to form an oxidized product.
    • 电化学系统和生产氢的方法。 通常,所述系统和方法包括提供一种电化学电池,其包括阳极电解液室,其阳极与阳极电解液接触,其中所述阳极电解质包括具有比水更高的标准氧化电位的可氧化物质。 电池进一步包括阴极电解室,其阴极与阴极电解液接触,阴极电解液包括减少形成氢的物质。 此外,电池包括将阳极电解液室与阴极电解液隔室分离的碱性阳离子导电膜。 当电极通过阳极和阴极之间时,可还原物质减少形成氢气,可氧化物质氧化形成氧化产物。
    • 8. 发明授权
    • Dialkyl and diaryl ether production from metal alcoholate
    • 二烷基和二芳基醚由金属醇化物生产
    • US08916731B2
    • 2014-12-23
    • US12834679
    • 2010-07-12
    • Justin PendletonSai Bhavaraju
    • Justin PendletonSai Bhavaraju
    • C07C41/09C07C29/70C07C41/01C07C37/66
    • C07C41/01C07C29/70C07C37/66C07C31/30C07C39/235C07C43/257C07C43/03
    • A dialkyl or diaryl ether is produced by reacting carbon dioxide with a metal alcoholate having the formula, M(RO)x, where “M” is a Group 1, Group 2, or Group 3 metal; “x” is the valence of the metal M; “R” is a C1 to C6 lower alkyl or aryl, wherein the reaction produces a dialkyl or diaryl ether having a formula, R—O—R, and a metal carbonate having a formula M2CO3 where M is a Group 1 metal, MCO3 where M is a Group 2 metal, and M2(CO3)3 where M is a Group 3 metal. The metal carbonate may be removed by conventional means, such as filtration. The dialkyl or diaryl ether may be recovered and used as a fuel, fuel additive, propellant, or building block for other fuels or petrochemicals. In some cases the metal alcoholate is in an alcohol solution and the alcohol and metal carbonate are recycled to regenerate the metal alcoholate. A specific example of dimethyl ether production is disclosed.
    • 通过使二氧化碳与具有式M(RO)x的金属醇化物反应制备二烷基或二芳基醚,其中“M”为第1族,第2族或第3族金属; “x”是金属M的化合价; “R”是C1至C6低级烷基或芳基,其中该反应产生具有式R-O-R的二烷基或二芳基醚和具有式M2CO3的金属碳酸盐,其中M是第1族金属,MCO3, M是2族金属,M2(CO3)3,其中M是第3族金属。 金属碳酸盐可以通过常规方法如过滤除去。 可以回收二烷基醚或二芳基醚,并将其用作燃料,燃料添加剂,推进剂或其它燃料或石化产品的结构单元。 在一些情况下,金属醇化物在醇溶液中,并且将醇和金属碳酸盐再循环以再生金属醇化物。 公开了二甲醚生产的具体实例。