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    • 1. 发明授权
    • Process for the synthesis of flyash based Zeolite-A
    • 用于合成基于飞灰的沸石-A的方法
    • US5965105A
    • 1999-10-12
    • US96821
    • 1998-06-12
    • Sadhana RayaluNitin Kumar LabhasetwarPurushottam Khanna
    • Sadhana RayaluNitin Kumar LabhasetwarPurushottam Khanna
    • C01B39/14
    • C01B39/14Y10S423/24
    • The present invention relates to a process for synthesis of flyash based Zeolite-A, said process comprising grinding and mixing of flyash and caustic soda in a ratio of 1:1.2 and optionally adding sodium aluminate or aluminium hydroxide to obtain a fine homogeneous fusion mixture; heating the said mixture in an inert vessel at about 500-600.degree. C. for about 1-2 hrs. to obtain a fused mass; cooling, milling, and mixing the said fused mass in distilled water for about 8-10 hrs. with simultaneous optional additon of sodium aluminate or alum solution, in the present or absence of NaC1 followed by optional addition of zeolite-A seeding to obtain amorphous alumino -silicate slurry; subjecting the said slurry to hydrothermal crystallisation at about 90-110.degree. C. for 2 to 4 hrs. to obtain Zeolite-A crystals; and washing the said crystals with water and then subjecting the washed crystals to oven drying at about 50-60.degree. C. to obtain the FAZ-A crystals.
    • 本发明涉及一种合成基于飞灰的沸石-A的方法,所述方法包括以1:1.2的比例研磨和混合飞灰和苛性钠,并任选地加入铝酸钠或氢氧化铝以获得细均匀的熔融混合物; 在约500-600℃下在惰性容器中加热所述混合物约1-2小时。 得到熔融体; 冷却,研磨和将所述熔融物质在蒸馏水中混合约8-10小时。 在本发明或不存在NaCl的情况下同时选择性地添加铝酸钠或明矾溶液,然后任选加入沸石-A接种以获得无定形硅铝酸盐浆料; 将所述浆料在约90-110℃下进行水热结晶2至4小时。 得到沸石A晶体; 并用水洗涤所述晶体,然后将洗涤的晶体在约50-60℃下烘箱干燥,得到FAZ-A晶体。