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    • 6. 发明申请
    • INSECTICIDAL COMPOUNDS
    • 杀虫剂化合物
    • WO2012163959A1
    • 2012-12-06
    • PCT/EP2012/060125
    • 2012-05-30
    • SYNGENTA PARTICIPATIONS AGCASSAYRE, Jérôme, YvesRENOLD, PeterEL QACEMI, MyriemPITTERNA, ThomasTOUEG, Julie, Clementine
    • CASSAYRE, Jérôme, YvesRENOLD, PeterEL QACEMI, MyriemPITTERNA, ThomasTOUEG, Julie, Clementine
    • C07D261/02C07D327/02A01N43/80
    • A01N43/80C07D261/02C07D327/02C07D411/12C07D413/12C07D413/14
    • The present invention provides compounds of formula (I): wherein A 1 , A 2 , A 3 and A 4 are independently of one another C-H, C-R 5 , or nitrogen; B 1 --B 2 --B 3 --B 4 is -CH 2 -C=N-CH 2 -, -CH 2 -N-CH 2 -CH 2 -, -CH 2 -C=CH-0- or -CH=C-CH 2 -0-; G 1 is oxygen or sulfur; L is a single bond or C 1 -C 8 alkylene; R 1 is hydrogen, C 1 -C 8 alkyl, C 1 -C 8 alkylcarbonyl-, C 1 -C 8 alkoxy, C 2 -C 8 alkenyl, C 2 -C 8 alkynyl, C 1 -C 8 alkoxy- C 1 -C 8 alkyl, aryl or aryl substituted by one to three R 6 , or R 1 is heterocyclyl or heterocyclyl substituted by one to three R 6 or C 1 -C 8 alkoxycarbonyl-; R 2 is hydrogen, C 1 -C 8 haloalkyl or C 1 -C 8 alkyl; R 3 is C 1 -C 8 haloalkyl; R 4 is aryl or aryl substituted by one to three R 6 , or R 4 is heterocyclyl or heterocyclyl substituted by one to three R 6 ; Y 1 is CR 7 R 8 , C=O or C=S; Y 2 , Y 3 and Y 4 are independently CR 7 R 8 , C=0, C=S, N-R 9 , O, S, SO or SO 2 ; wherein at least two adjacent ring atoms in the ring formed by Y 1 , Y 2 , Y 3 and Y 4 are heteroatoms; each R 7 and R 8 is independently hydrogen, halogen, C 1 -C 8 alkyl, or C 1 -C 8 haloalkyl; and R 5 , R 6 , R 7 , R 8 and R 9 are as defined in the claims. The invention also relates to processes and intermediates for preparing these compounds, to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising these compounds and to methods of using these compounds to control insect, acarine, nematode and mollusc pests.
    • 本发明提供式(I)化合物:其中A1,A2,A3和A4彼此独立地为C-H,C-R5或氮; B1-B2-B3-B4是-CH2-C = N-CH2-,-CH2-N-CH2-CH2-,-CH2-C = CH-O-或-CH = C-CH2- ; G1是氧或硫; L是单键或C1-C8亚烷基; R 1是氢,C 1 -C 8烷基,C 1 -C 8烷基羰基 - ,C 1 -C 8烷氧基,C 2 -C 8链烯基,C 2 -C 8炔基,C 1 -C 8烷氧基-C 1 -C 8烷基,被1至3个R 6取代的芳基或芳基,或者R 1是杂环基或杂环基取代 一至三个R6或C1-C8烷氧基羰基 - ; R2是氢,C1-C8卤代烷基或C1-C8烷基; R3是C1-C8卤代烷基; R4是被一至三个R6取代的芳基或芳基,或R4是被一至三个R6取代的杂环基或杂环基; Y1是CR7R8,C = O或C = S; Y2,Y3和Y4独立地为CR7R8,C = 0,C = S,N-R9,O,S,SO或SO2; 其中由Y1,Y2,Y3和Y4形成的环中至少两个相邻的环原子是杂原子; 每个R 7和R 8独立地是氢,卤素,C 1 -C 8烷基或C 1 -C 8卤代烷基; 且R 5,R 6,R 7,R 8和R 9如权利要求中所定义。 本发明还涉及制备这些化合物的方法和中间体,包含这些化合物的杀虫,杀螨,杀线虫和杀软体动物的组合物,以及使用这些化合物来控制昆虫,螨虫,线虫和软体动物害虫的方法。